Silicone fine particles, method for preparing the same, and thermoplastic resin composition using the same
One aspect of the invention relates to a method of preparing silicone fine particles which comprises preparing a mixture comprising an organotrialkoxysilane and an organochlorosilane to give a concentration of the organochlorosilane in the mixture of about 100 to about 2,000 ppm; mixing the mixture with water to prepare a sol solution; and maintaining a pH value of the sol solution within a range of about 8 to about 11. Another aspect of the invention relates to a thermoplastic resin composition which employs the silicone fine particles as a diffuser.
1. A method of preparing polyorganosilsesquioxane fine particles, comprising the steps of:
(a) preparing a mixture comprising an organotrialkoxysilane and an organochlorosilane to give a concentration of the organochlorosilane in the mixture of about 100 to about 2,000 ppm;
(b) mixing the mixture with water by means of a high-efficiency mixer selected from the group consisting of a homo-mixer, a homogenizer, a microfluidizer, a flat impeller having a width that is at least 50% of an inner diameter of a reactor, stirring equipment having a plurality of baffle plates oriented in a longitudinal direction of a reactor and combinations thereof to prepare a sol solution; and
(c) maintaining a pH value of the sol solution within a range of about 8 to about 11.
2. The method of claim 1 , wherein said organotrialkoxysilane is represented by the following chemical Formula (I):
R 1 Si(OR 2 ) 3 (I)
wherein R 1 represents an alkyl group having 1 to 6 carbon atoms, vinyl group, or aryl group, and R 2 is an alkyl group having 1 to 5 carbon atoms.
3. The method of claim 2 , wherein said sol solution comprises said organotrialkoxysilane in an amount of about 5 to about 50% by weight based on the total weight of the sol solution.
4. The method of claim 1 , wherein said organochlorosilane is represented by the following chemical Formula (II):
R 1 Si(OR 2 ) 3-x Cl x (II)
wherein R 1 represents an alkyl group having 1 to 6 carbon atoms, vinyl group, or aryl group, R 2 is an alkyl group having 1 to 5 carbon atoms, and x is 1 to 3.
5. The method of claim 1 , wherein said organochlorosilane is organotrichlorosilane.
6. The method of claim 1 , further comprising the steps of filtering said sol solution, washing and drying after step (c) to thereby obtain fine particles having an average particle diameter of about 0.1 to about 10 μm.
7. The method of claim 1 , wherein the step of mixing the mixture with water comprises mixing the mixture with water using a homo-mixer.
8. The method of claim 1 , wherein the step of mixing the mixture with water comprises mixing the mixture with water using a microfluidizer.
9. The method of claim 1 , wherein the step of mixing the mixture with water comprises mixing the mixture with water using a homo-mixer and a microfluidizer.
10. The method of claim 1 , wherein the step of mixing the mixture with water comprises mixing the mixture with water using a flat impeller having a width that is at least 50% of an inner diameter of a reactor.
11. The method of claim 1 , further comprising the steps of filtering said sol solution, washing and drying after step (c) to thereby obtain fine particles having an average particle diameter of about 2.5 to about 3.5 μm.