Elastomeric nonwovens
A nonwoven fabric and disposable articles comprising the same are provided. The nonwoven fabric can include one or more facing layers thermally bonded to one or more inner layers. The facing layers are inelastic or partially elastic nonwoven webs comprising one or more propylene-based polymers. The facing layer has a permanent set above 30%. The inner layers are elastic nonwoven webs comprising one or more propylene-based polymers and one or more slip agents. The inner layer has a permanent set below 28%, and the one or more propylene-based polymers have (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences, and (iii) a heat of fusion less than 45 J/g.
1. A nonwoven fabric, comprising:
(a) one or more facing layers that are each inelastic nonwoven webs having a permanent set above 30%, the one or more facing layers each comprising:
from about 5 to about 40 wt % polypropylene, and
from about 60 to about 95 wt % of a propylene-based polymer,
wherein the one or more facing layers are devoid of slip agents; and
(b) one or more inner layers that are elastic nonwoven webs having a permanent set below 28%, the one or more inner layers comprising:
one or more propylene-based polymers, and
from about 0.2 to about 10 wt. % of one or more slip agents,
wherein:
the propylene-based polymer has: (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences, and (iii) a heat of fusion less than 45 J/g; and
the one or more facing layers are thermally bonded to one or more inner layers; and
the nonwoven fabric has an elongation greater than 150%.
2. The nonwoven fabric of claim 1 , wherein the facing layer has a permanent set above 50% and the inner layer has a permanent set below 27%.
3. The nonwoven fabric of claim 1 , wherein each facing layer is either spunbonded or meltblown.
4. The nonwoven fabric of claim 1 , wherein the one or more facing layers comprises at least one layer that is spunbonded and at least one layer that is meltblown.
5. The nonwoven fabric of claim 1 , wherein the one or more inner layers comprises at least one layer that is spunbonded and at least one layer that is meltblown.
6. The nonwoven fabric of claim 1 , wherein the one or more facing layers each comprise from about 80% to about 95% by weight of the propylene-based polymer.
7. A nonwoven fabric comprising:
(a) an inelastic nonwoven facing layer or layers comprising:
from about 5 to about 40 wt % polypropylene and from about 60 to about 95 wt % of a propylene-based polymer,
wherein the inelastic layer has a permanent set above 30% and wherein the facing layers are devoid of slip agents; and
(b) an elastic nonwoven layer or layers thermally bonded to the inelastic facing layer comprising:
a slip additive,
a hydrocarbon resin,
a thermoplastic resin having a melt flow rate greater than 400 g/10 min, and
a propylene-based polymer
wherein the elastic layer has a permanent set below 28%; and
wherein the propylene-based polymer has 60 wt % or more units derived from propylene, isotactically arranged propylene derived sequences, and a heat of fusion less than 45 J/g; and
wherein the nonwoven fabric has an elongation greater than 150%.
8. The nonwoven fabric of claim 7 , wherein the polypropylene has a melt flow rate above 20 g/10 min.
9. The nonwoven fabric of claim 7 , wherein the inelastic nonwoven facing layer is fabricated using a spunbond or meltblown process.
10. The nonwoven fabric of claim 7 , wherein the propylene-based polymer has a melt flow rate above 10 g/10 min.
11. The nonwoven fabric of claim 7 , wherein the slip additive is selected from the group consisting of behenamide, erucamide, N-(2-hdriethyl) erucamide, Lauramide, N,N′-ethylene-bis-oleamide, N,N′-ethylene bisstearmide, oleamide, oleyl palmitamide, stearyl erucamide, tallow amide, and mixtures thereof.
12. The nonwoven fabric of claim 7 , wherein the hydrocarbon resin is selected from the group consisting of aliphatic hydrocarbon resins, at least partially hydrogenated aliphatic hydrocarbon resins, aliphatic/aromatic hydrocarbon resins, at least partially hydrogenated aliphatic aromatic hydrocarbon resins, cycloaliphatic hydrocarbon resins, at least partially hydrogenated cycloaliphatic resins, aromatic hydrocarbon resins, at least partially hydrogenated aromatic hydrocarbon resins, at least partially hydrogenated aromatic hydrocarbon resins, polyterpene resins, terpene-phenol resins, rosins, rosin esters, hydrogenated rosins, hydrogenated rosin esters, and mixtures thereof.
13. The nonwoven fabric of claim 7 , wherein the thermoplastic resin is selected from the group of polypropylene homopolymer, propylene copolymers, polypropylene random copolymers, polypropylene impact copolymers, polyethylene, ethylene alpha olefin copolymers and mixtures thereof.
14. A nonwoven fabric, comprising:
(a) one or more facing layers that are inelastic nonwoven webs comprising:
from about 5 to about 40 wt % polypropylene, and
from about 60 to about 95 wt % of a polypropylene-based polymer, and
(b) one or more inner layers that are elastic nonwoven webs comprising:
one or more propylene-based polymers and
one or more slip agents, and
wherein:
the facing layers are thermally bonded to inner layers;
the facing layers are devoid of slip agents;
the facing layers and inner layers have a difference in permanent set of at least 5%;
the propylene-based polymer has 60 wt % or more units derived from propylene, isotactically arranged propylene derived sequences, and a heat of fusion less than 45 J/g; and
the nonwoven fabric has an elongation greater than 150%.
15. The nonwoven fabric of claim 14 , wherein each facing layer is either spunbonded or meltblown.
16. The nonwoven fabric of claim 14 , wherein the one or more facing layers comprise at least one layer that is spunbonded and at least one layer that is meltblown.
17. The nonwoven fabric of claim 14 , wherein the one or more inner layers comprise at least one layer that is spunbonded and at least one layer that is meltblown.
18. The nonwoven fabric of claim 14 , wherein the one or more facing layers each comprise from about 80% to about 95% by weight of the propylene-based polymers.
19. The nonwoven fabric of claim 14 , wherein the difference in permanent set is about 15% or more.
20. The nonwoven fabric of claim 14 , wherein the difference in permanent set is about 22% or more.
21. A disposable article comprising the nonwoven fabric of claim 1 .
22. A disposable article comprising the nonwoven fabric of claim 7 .
23. A disposable article comprising the nonwoven fabric of claim 14 .
24. The nonwoven fabric of claim 7 , where the thermoplastic resin is polypropylene homopolymer.
25. The nonwoven fabric of claim 1 , where the inner layers comprise propylene-based polymers and polypropylene.
26. The facing layer of claim 4 , where the meltblown fabric includes a filament having a fiber diameter from 1 to 5 microns.