Method of obtaining bulk single crystals by seeded growth

1. A process for obtaining a larger area substrate of mono-crystalline gallium-containing nitride by making selective crystallization of gallium containing nitride on a smaller elementary seed under a crystallization temperature and/or pressure from a supercritical ammonia-containing solution made by dissolution of gallium-containing feedstock in a supercritical ammonia-containing solvent with alkali metal ions, comprising:

providing two or more elementary seeds,

placing the elementary seeds in at least one holder for ensuring a precise arrangement of the elementary seeds with respect to each other; and

making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed.

2. The process according to claim 1 , wherein the step of providing two or more elementary seeds includes using the elementary seeds having fast-growing growing faces and merging faces significantly tilted off the slow-growing crystalline plane.

3. The process according to claim 1 , wherein said step of making selective crystallization on the two or more separate elementary seeds includes limiting a process straight growth at an initial stage and evoking merging by lateral growth.

4. The process according to claim 1 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out lateral growth on the compound seed.

5. The process according to claim 1 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out straight growth on the compound seed.

6. The process according to claim 1 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out free growth on the compound seed.

7. The process according to claim 1 , wherein said step of placing the elementary seeds in at least one holder includes ensuring an adjacent orientation of their merging faces with respect to each other.

8. The process according to claim 1 , wherein said step of placing the elementary seeds in at least one holder includes covering and/or exposing selected faces of the seed, so that crystalline growth on these faces is essentially disabled/enabled.

9. The process according to claim 1 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining gallium-containing nitride single crystals.

10. The process according to claim 9 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining the single crystals grown by crystallization from the supercritical ammonia-containing solution.

11. The process according to the claim 9 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining the single crystals grown by crystallization from melt.

12. The process according to the claim 9 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes growing elementary seeds in the direction parallel to the c crystalline axis.

13. The process according to the claim 9 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes growing the elementary seeds in a direction perpendicular to the c crystalline axis and using fast-growing growing faces.

14. The process according to the claim 12 , wherein said step of providing two or more elementary seeds includes using polyhedrons with appropriately formed growing and/or merging faces.

15. The process according to the claim 14 , wherein said step of providing two or more elementary seeds includes placing the two or more the elementary seeds so as to form a flat plate in one plane.

16. The process according to the claim 14 , wherein said step of providing two or more elementary seeds includes polishing the growing and/or merging faces of the elementary seeds.

17. A process for obtaining a larger area substrate of mono-crystalline gallium-containing nitride by making selective crystallization of gallium containing nitride on a smaller elementary seed under a crystallization temperature and/or pressure from a supercritical ammonia-containing solution made by dissolution of gallium-containing feedstock in a supercritical ammonia-containing solvent with alkali metal ions, comprising:

providing two or more elementary seeds,

placing the elementary seeds in at least one holder for ensuring a precise arrangement of the elementary seeds with respect to each other; and

making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed,

wherein said step of placing the elementary seeds in at least one holder includes using the holder having at least two side walls to cover the elementary seeds.

18. The process according to claim 17 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having a shape which contacts opposite sides of the elementary seeds.

19. The process according to claim 17 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having a gap to grow the elementary seeds.

20. The process according to claim 1 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having at least three side walls to cover the elementary seeds.

21. A process for obtaining a larger area substrate of mono-crystalline gallium-containing nitride by making selective crystallization of gallium containing nitride, comprising the steps of:

providing at least two elementary seeds in a high pressure autoclave, and

making selective crystallization on the at least two elementary seeds to get a merged larger compound seed, the selective crystallization being done under a crystallization temperature and/or pressure from a supercritical ammonia-containing solution made by dissolution of gallium-containing feedstock in a supercritical ammonia-containing solvent with alkali metal ions.

22. The process according to claim 21 , wherein the step of providing two or more elementary seeds includes using the elementary seeds having fast-growing growing faces and merging faces significantly tilted off the slow-growing crystalline plane.

23. The process according to claim 21 , wherein said step of making selective crystallization on the two or more separate elementary seeds includes limiting a process straight growth at an initial stage and evoking merging by lateral growth.

24. The process according to claim 21 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out lateral growth on the compound seed.

25. The process according to claim 1 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out straight growth on the compound seed.

26. The process according to claim 21 , wherein said step of providing two or more elementary seeds includes forming a compound seed, and carrying out free growth on the compound seed.

27. The process according to claim 21 , wherein said step of placing the elementary seeds in at least one holder includes ensuring an adjacent orientation of their merging faces with respect to each other.

28. The process according to claim 21 , wherein said step of placing the elementary seeds in at least one holder includes covering and/or exposing selected faces of the seed, so that crystalline growth on these faces is essentially disabled/enabled.

29. The process according to claim 21 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining gallium-containing nitride single crystals.

30. The process according to claim 29 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining the single crystals grown by crystallization from the supercritical ammonia-containing solution.

31. The process according to the claim 29 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes obtaining the single crystals grown by crystallization from melt.

32. The process according to the claim 29 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes growing elementary seeds in the direction parallel to the c crystalline axis.

33. The process according to the claim 29 , wherein said step of making selective crystallization on the two or more separate elementary seeds to get a merged larger compound seed includes growing the elementary seeds in a direction perpendicular to the c crystalline axis and using fast-growing growing faces.

34. The process according to the claim 33 , wherein said step of providing two or more elementary seeds includes using polyhedrons with appropriately formed growing and/or merging faces.

35. The process according to the claim 34 , wherein said step of providing two or more elementary seeds includes placing the two or more the elementary seeds so as to form a flat plate in one plane.

36. The process according to the claim 34 , wherein said step of providing two or more elementary seeds includes polishing the growing and/or merging faces of the elementary seeds.

37. The process according to claim 21 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having at least two side walls to cover the elementary seeds.

38. The process according to claim 37 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having a shape which contacts opposite sides of the elementary seeds.

39. The process according to claim 37 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having a gap to grow the elementary seeds.

40. The process according to claim 21 , wherein said step of placing the elementary seeds in at least one holder includes using the holder having at least three side walls to cover the elementary seeds.