Use of cationic polycondensation products as additives for fixing colours and/or inhibiting the running of colours, for washing products and washing aftertreatment products
The invention relates to the use of cationic polycondensation products as additives for fixing colors and/or inhibiting the running of colors, for washing products and washing aftertreatment products. Said cationic polycondensation products can be produced by the condensation of (A1) non-cyclic amines obtained by the reaction of (A1 a) mono(N,N-dialkylaminoalkyl)amines with (A1 b) bifunctional compounds selected from the group containing urea, thiourea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids, and aliphatic and aromatic diisocyanates, in a molar ratio 1.2:1 to 2.1:1, or (A2) mixtures of non-cyclic amines (A1) and cyclic amines (A3) in a molar ratio 10:1 to 1:10 with (B) bifunctional compounds selected from the group containing alkylene dihalogenides, dihalogen alkyl ethers, halomethyl oxiranes, and bisepoxides, in a molar ratio (B) to (A1) or (B) to (A2) from 0.6:1 to 1.3:1.
1. A cationic polycondensation product obtained by condensation of
(A2) at least one mixture of
(A1) at least one noncyclic amine prepared by reaction of
(A1a) at least one mono(N,N-dialkylaminoalkyl)amine
with
(A1b) at least one bifunctional compound selected from the group consisting of urea, thiourea, a dialkyl carbonate, an aliphatic and aromatic dicarboxylic acid, and an aliphatic and aromatic diisocyanate, in a molar ratio from 1.2:1 to 2.1:1,
and
(A3) at least one cyclic amine,
in a molar ratio from 10:1 to 1:10
with
(B) at least one bifunctional compound selected from the group consisting of an alkylene dihalide, dihaloalkyl ether, halomethyloxirane, and a bisepoxide,
in a molar ratio (B) to (A2) from 0.6:1 to 1.3:1.
2. The cationic polycondensation product according to claim 1 , wherein the component (A3) is at least one cyclic amine selected from the group consisting of imidazole, an alkyl derivative of imidazole, piperazine, an alkyl derivative of piperazine, pyrazine and pyrimidine.
3. A laundry detergent comprising the cationic polycondensation product according to claim 1 as a dye-fixing and/or dye transfer-inhibiting additive.
4. A solid laundry detergent formulation comprising
(a) from 0.05 to 20% by weight of at least one cationic polycondensation product according to claim 1 ,
(b) from 0.5 to 40% by weight of at least one nonionic, anionic and cationic surfactant,
(c) from 0.5 to 50% by weight of at least one inorganic builder,
(d) from 0 to 10% by weight of at least one organic cobuilder and
(e) from 0.1 to 60% by weight of at least one customary ingredient selected from the group consisting of a standardizer, enzyme, perfume, complexing agent, corrosion inhibitor, bleache, bleach activator, bleach catalyst, further dye protection additive and dye transfer inhibitor, graying inhibitor, soil-release polyester, fiber protection additive, silicone, dye, bactericide and preservative, dissolution improver, disintegrant, and water,
wherein the sum of the components (a) to (e) adds up to 100% by weight.
5. A liquid laundry detergent formulation comprising
(a) from 0.05 to 20% by weight of at least one cationic polycondensation product according to claim 1 ,
(b) from 0.5 to 40% by weight of at least one nonionic, anionic and cationic surfactant,
(c) from 0 to 20% by weight of at least one inorganic builder,
(d) from 0 to 10% by weight of at least one organic cobuilder and
(e) from 0.1 to 60% by weight of at least one customary ingredient selected from the group consisting of soda, an enzyme, perfume, a complexing agent, corrosion inhibitor, bleach, bleach activator, bleach catalyst, further dye protection additive and a dye transfer inhibitor, graying inhibitor, soil-release polyester, fiber protection additive, silicone, dye, bactericide and preservative, organic solvent, solubilizer, hydrotrope, thickener, and an alkanolamine, and
(f) from 0 to 99.35% by weight of water.
6. A laundry aftertreatment composition comprising the cationic polycondensation product according to claim 1 as a dye-fixing and/or dye transfer-inhibiting additive.
7. A laundry aftertreatment composition comprising
(a) from 0.05 to 20% by weight of at least one cationic polycondensation product according to claim 1 ,
(b) from 0.1 to 40% by weight of at least one cationic surfactant,
(c) from 0 to 30% by weight of at least one nonionic surfactant,
(d) from 0.1 to 30% by weight of at least one customary ingredient selected from the group consisting of silicone, another lubricant, a wetting agent, film-forming polymer, fragrance and dye, stabilizer, fiber protection additive, further dye protection additive and dye transfer inhibitor, complexing agent, viscosity modifier, soil-release additive, solubilizer, hydrotrope, corrosion protection additive, bactericide, and a preservative, and
(e) from 0 to 99.75% by weight of water.
8. A cationic polycondensation product obtained by condensation of
(A2) at least one mixture of
(A1) at least one noncyclic amine prepared by reaction of
(A1a) at least one mono(N,N-dialkylaminoalkyl)amine
with
(A1b) at least one bifunctional compound selected from the group consisting of an aliphatic and aromatic dicarboxylic acid, and an aliphatic and aromatic diisocyanate,
in a molar ratio from 1.2:1 to 2.1:1,
and
(A3) at least one cyclic amine,
in a molar ratio of 10:1 to 1:10
with
(B) at least one bifunctional compound selected from the group consisting of an alkylene dihalide, dihaloalkyl ether, halomethyloxirane, and a bisepoxide, in a molar ratio of (B) to (A2) of 0.6:1 to 1.3:1.
9. A laundry detergent comprising the cationic polycondensation product according to claim 8 as a dye-fixing and/or dye transfer-inhibiting additive.
10. A solid liquid laundry detergent formulation comprising
(a) from 0.05 to 20% by weight of at least one cationic polycondensation product according to claim 9 ,
(b) from 0.5 to 40% by weight of at least one nonionic, anionic and cationic surfactant,
(c) from 0.5 to 50% by weight of at least one inorganic builder,
(d) from 0 to 10% by weight of at least one organic cobuilder, and
(e) from 0.1 to 60% by weight of at least one customary ingredient selected from the group consisting of a standardizer, enzymes, perfume, complexing agent, corrosion inhibitor, bleach, bleach activator, bleach catalyst, further dye protection additive and dye transfer inhibitor, graying inhibitor, soil-release polyester, fiber protection additive, silicones, dye, bactericide and preservative, dissolution improver, disintegrant, and water,
wherein the sum of components (a) to (e) adds up to 100% by weight.
11. A liquid laundry detergent formulation comprising
(a) from 0.05 to 20% by weight the cationic polycondensation product according to claim 8 ,
(b) from 0.5 to 40% by weight of at least one nonionic, anionic and cationic surfactant,
(c) from 0 to 20% by weight of at least one inorganic builder,
(d) from 0 to 10% by weight of at least one organic cobuilder, and
(e) from 0.1 to 60% by weight of at least one customary ingredient selected from the group consisting of soda, an enzyme, perfume, a complexing agent, corrosion inhibitor, bleache, bleach activator, bleach catalyst, further dye protection additive and dye transfer inhibitor, graying inhibitor, soil-release polyester, fiber protection additive, silicones, dye, bactericide and preservative, organic solvent, solubilizer, hydrotrope, thickener, and an alkanolamine, and
(f) from 0 to 99.35% by weight of water.
12. A laundry aftertreatment composition comprising the cationic polycondensation product according to claim 8 as a dye-fixing and/or dye transfer-inhibiting additive.
13. A laundry aftertreatment composition comprising
(a) from 0.05 to 20% by weight of at least one cationic polycondensation product according to claim 8 ,
(b) from 0.1 to 40% by weight of at least one cationic surfactant,
(c) from 0 to 30% by weight of at least one nonionic surfactant,
(d) from 0.1 to 30% by weight of at least one customary ingredient selected from the group consisting of silicone, another lubricant, a wetting agent, film-forming polymer, fragrances and dye, stabilizer, fiber protection additive, further dye protection additive and dye transfer inhibitor, complexing agent, viscosity modifier, soil-release additive, solubilizer, hydrotrope, corrosion protection additive, bactericide, and a preservative, and
(e) from 0 to 99.75% by weight of water.