Method of producing electrode for capacitor
The present invention provides a method of producing an electrode for an electric double layer capacitor, which yields the electrode with an electrode layer having a higher density by calendering treatment. A method of producing an electrode for a capacitor, which comprises at least a current collector and an electrode layer on the current collector, the method comprising the steps of: applying an electrode layer coating material which comprises at least a carbon material, a binder and a solvent, onto the current collector to form an electrode coating layer; drying the electrode coating layer on the current collector to set the amount of the solvent remaining in the electrode coating layer within a range of 5 to 35% by weight of the layer; and subjecting the electrode coating layer after the drying to calendering treatment to yield an electrode layer.
1. A method of producing an electrode for a capacitor, which comprises a current collector, an undercoat layer on the current collector, and an electrode layer on the undercoat layer, the method comprising:
applying an undercoat layer coating material, which comprises at least electrically conductive particles, a binder and a solvent, onto the current collector, and then drying the applied material to set the amount of the solvent remaining in the applied material within a range of 0.1% by weight or less, thereby forming an undercoat layer;
applying an electrode layer coating material, which comprises at least a carbon material, a binder and a solvent, onto the undercoat layer to form an electrode coating layer;
drying the electrode coating layer to set the amount of the solvent remaining in the whole of the layers formed on the current collector within a range of 11 to 35% by weight of the layers; and
subjecting the electrode coating layer after the drying to calendering treatment to yield an electrode layer,
wherein the binder in the undercoat layer coating material and the binder in the electrode layer coating material are the same, and
wherein the drying of the electrode coating layer is performed at a temperature of 90° C. to 180° C. for 0.1 to 100 minutes.
2. The method of producing an electrode for a capacitor according to claim 1 , wherein the calendering treatment is conducted at a pressure of 4,900 to 24,500 N/cm (0.5 to 2.5 t/cm).
3. The method of producing an electrode for a capacitor according to claim 1 , wherein the electrode layer has a thickness of 50 to 200 μm.
4. The method of producing an electrode for a capacitor according to claim 1 , wherein the undercoat has a thickness of 0.2 to 10 μm.
5. The method of producing an electrode for a capacitor according to claim 1 , wherein the undercoat electrically conductive particles are carbon black particles, and an average particle diameter of the carbon black particles is from 25 to 50 nm, and the BET specific surface area is 50 m 2 /g or greater.
6. The method of producing an electrode for a capacitor according to claim 1 , wherein the undercoat electrically conductive particles are graphite particles, and the average particle diameter of the graphite particles is from 4 to 6 μm, and the BET specific surface area is 10 m 2 /g or greater.
7. The method of producing an electrode for a capacitor according to claim 1 , wherein the binder in the undercoat layer is at least one binder selected from the group consisting of polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyethylene (PE), polypropylene (PP), and fluororubber.
8. The method of producing an electrode for a capacitor according to claim 1 , wherein an amount of the binder in the undercoat layer is from 50 to 70 wt. % of the dried undercoat layer.
9. The method of producing an electrode for a capacitor according to claim 1 , wherein the solvent of the undercoat layer is at least one organic solvent selected from the group consisting of saturated hydrocarbons; aromatic hydrocarbons; alcohols; ketones; esters; ethers; amides; and halogenated hydrocarbons.
10. The method of producing an electrode for a capacitor according to claim 1 , wherein an average particle diameter of the carbon material in the electrode layer is from 3 to 20 μm, and the BET specific surface area is 1,500 m 2 /g or greater.
11. The method of producing an electrode for a capacitor according to claim 1 , wherein an amount of the binder in the electrode layer is from 5 to 20 wt. % of the dried electrode layer.
12. The method of producing an electrode for a capacitor according to claim 1 , wherein an electrode layer density is 0.640 g/cm 3 or greater.
13. The method of producing an electrode for a capacitor according to claim 1 , wherein the undercoat layer is dried at 50-150° C. before applying the electrode layer.
14. The method of producing an electrode for a capacitor according to claim 1 , wherein the drying of the electrode coating layer is performed for 0.5 to 100 minutes.
15. The method of producing an electrode for a capacitor according to claim 1 , wherein the drying of the electrode coating layer is performed for 3 to 100 minutes.