Membrane reactor for H
A system for the selective removal of CO 2 , H 2 S, and H 2 from a gaseous fluid mixture comprising CO 2 , H 2 S, and H 2 , which system includes a first membrane section having a nonporous metal oxide membrane, a second membrane section having a CO 2 -selective membrane, and a third membrane section having an H 2 -selective membrane. Each membrane section has a feed side and a permeate side and the membrane sections are arranged in series whereby the gaseous fluid mixture contacts the feed side, in sequence, of the first membrane section, the second membrane section and the third membrane section, resulting first in the separation or removal of H 2 S, second in the separation or removal of CO 2 , and third in the separation or removal of H 2 . The process can be used to process synthesis gas generated from the gasification or reforming of carbonaceous materials for hydrogen production and carbon dioxide capture.
1. A system for selective removal of CO 2 , H 2 S, and H 2 from a fluid mixture comprising said CO 2 , H 2 S, and H 2 , the system comprising:
an H 2 S-selective nonporous metal oxide membrane;
a CO 2 -selective membrane;
an H 2 -selective membrane;
each said membrane having a feed side, a permeate side, a fluid inlet end, and a fluid outlet end; and
said membranes touching end-to-end whereby said fluid mixture flows into said inlet ends, in sequence, and contacts said feed side, in sequence, of said H 2 S-selective membrane, said CO 2 -selective membrane and said H 2 -selective membrane.
2. A system in accordance with claim 1 , wherein said H 2 S-selective nonporous metal oxide membrane comprises a metal selected from the group consisting of Ca, Mg, Ba, Sr, Cd, Mn, Fe, Zn, Co, Ni, and combinations thereof.
3. A system in accordance with claim 1 , wherein said CO 2 -selective membrane is a nonporous metal carbonate membrane.
4. A system in accordance with claim 3 , wherein said nonporous metal carbonate membrane comprises a metal selected from the group consisting of Ca, Mg, Ba, Sr, Cd, Mn, Fe, Zn, Co, Ni, and combinations thereof.
5. A system in accordance with claim 1 , wherein said membranes are disposed within a single reactor vessel.
6. A system in accordance with claim 4 , wherein said nonporous metal carbonate membrane is one of disposed on a surface of a porous substrate and disposed within an interior of said porous substrate.
7. A system in accordance with claim 6 , wherein substantially all pores of said porous substrate have pore sizes “less than 1000 nm in diameter”.
8. A system in accordance with claim 7 , wherein said pore sizes are less than 20 nm in diameter or equal to about 20 nm in diameter.
9. A system in accordance with claim 1 , wherein each said membrane has a tubular shape.