IP Library Granted Patent US 7,951,749
Granted Patent B2
US 7,951,749 · App. 11/820,954 · Granted May 31, 2011

Enhancing hydrogen spillover and storage

Assignee: The Regents of The University of Michigan
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Quick Facts
Patent No.
US 7,951,749
App. No.
11/820,954
Granted
May 31, 2011
Kind
B2
Abstract

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Claims (18)

1. A method for enhancing hydrogen storage, comprising:

doping a hydrogen receptor with metal particles by:

forming a dispersion including the hydrogen receptor; and

adding a solution including a source of the metal particles to the dispersion including the hydrogen receptor, thereby forming a mixture, wherein the hydrogen receptor is chosen from activated carbons and alumina;

exposing the hydrogen receptor to ultrasonication as doping occurs;

drying the mixture to form a composition;

subjecting the composition to a first gas flow at a first temperature;

subjecting the composition to a second gas flow at a second temperature, the second temperature being higher than the first temperature; and

cooling the composition.

2. The method as defined in claim 1 wherein the first gas flow contains helium gas and wherein the second gas flow contains hydrogen gas.

3. The method as defined in claim 1 wherein the metal particles are selected from platinum, palladium, ruthenium, rhodium, nickel, copper, iron, and combinations thereof.

4. A method for enhancing hydrogen storage, comprising:

doping a hydrogen receptor with metal particles, wherein the hydrogen receptor is chosen from activated carbons and alumina;

exposing the hydrogen receptor to ultrasonication as doping occurs; and

then exposing the doped hydrogen receptor to a plasma treatment.

5. The method as defined in claim 4 wherein the plasma treatment is selected from glow discharge plasma, microwave plasma, plasma spraying, and combinations thereof.

6. The method as defined in claim 4 , further comprising forming chemical bridges between respective metal particles and a surface of the hydrogen receptor during the plasma treatment.

7. The method as defined in claim 4 wherein the plasma treatment is accomplished for a predetermined time ranging from about 5 minutes to about 60 minutes at a predetermined temperature up to 1000° C.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 9, 2013
From: UNIVERSITY OF MICHIGAN
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 031447/0515 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2007
From: YANG, RALPH T.; LI, YINGWEI; LACHAWIEC, JR., ANTHONY J.
To: MICHIGAN, UNIVERSITY OF, THE REGENTS OF THE
Reel/Frame 019528/0838 →
Continuity (4)
Continuation In Part 11442898 · May 30, 2006
Provisional Application 60751744 · Dec 19, 2005
Provisional Application 60725337 · Oct 11, 2005
Related Publication 20100019196A1 · Jan 28, 2010