Method for forming barrier metal layer of bit line in semiconductor memory device
A semiconductor memory device includes a titanium layer and a titanium nitride layer formed on a substrate, a thin layer formed on the titanium nitride layer, and a metal layer formed on the thin layer, wherein the thin layer increases a grain size of the metal layer.
1. A method for fabricating a semiconductor memory device, comprising:
sequentially forming a titanium layer and a titanium nitride layer over a substrate;
forming a thin layer on the titanium nitride layer; and
forming a metal layer on the thin layer, wherein forming the thin layer increases a grain size of the metal layer;
wherein forming the thin layer comprises forming an amorphous layer by performing an atomic layer deposition (ALD) method and the amorphous layer has a thickness ranging from approximately 50 Å to approximately 200 Å and the amorphous layer remains as an amorphous layer in the semiconductor memory device.
2. The method of claim 1 , wherein forming the metal layer comprises forming a tungsten layer, and forming the amorphous layer comprises forming a tungsten silicide layer.
3. The method of claim 1 , wherein forming the amorphous layer comprises forming the amorphous layer from a material selected from a group consisting of tantalum silicide (TaSi x ), titanium silicide (TiSi x ), molybdenum silicide (MoSi x ), hafnium silicide (HfSi x ), zirconium silicide (ZrSi x ), cobalt silicide (CoSi x ), chrome silicide (CrSi x ), nickel silicide (NiSi x ), tungsten silicon nitride (W—Si—N), tantalum silicon nitride (Ta—Si—N), titanium silicon nitride (Ti—Si—N), molybdenum silicon nitride (Mo—Si—N), hafnium silicon nitride (Hf—Si—N), and zirconium silicon nitride (Zr—Si—N).
4. The method of claim 1 , wherein forming the metal layer comprises forming the metal layer from a material selected from a group consisting of tantalum (Ta), titanium (Ti), molybdenum (Mo), hafnium (HO, cobalt (Co), chrome (Cr), nickel (Ni), platinum (Pt), and ruthenium (Ru).
5. The method of claim 1 , further comprising forming an amorphous tungsten nitride (WN) layer between the amorphous layer and the metal layer.