Grafting functionalized pearlescent or metallic pigment onto polyester polymers for special effect images
Pigment particles with at least one metal oxide surface additive, wherein the at least one metal oxide surface additive is a metal oxide particle covalently bonded with at least one polycondensation polymer, wherein the pigment particle is a pearlescent or metallic pigment.
1. A pigment particle comprising
a pearlescent or metallic pigment base particle having at least one surface additive on a surface of the pearlescent or metallic pigment base particle;
wherein the at least one surface additive is a metal oxide particle coated with and covalently bonded to at least one polycondensation polymer.
2. The pigment particle according to claim 1 , wherein the pearlescent or metallic pigment base particle has an average size of from about 5 to about 50 microns.
3. The pigment particle according to claim 1 , wherein the polycondensation polymer is a polyester.
4. The pigment particle according to claim 3 , wherein the polyester has an acid value of from about 13 mg/eq. KOH to about 40 mg/eq. KOH.
5. The pigment particle according to claim 3 , wherein the covalent bond is between a functional group on a surface of the metal oxide particle and a functional group of the polyester.
6. The pigment particle according to claim 5 , wherein the functional group of the polyester is selected from the group consisting of amine, hydroxyl, epoxide, and carboxylic acid.
7. The pigment particle according to claim 3 , wherein the covalent bond is between an amine functional group on the surface of the metal oxide particle and an epoxide functional group of the polyester, or the covalent bond is between an epoxide functional group on the surface of the metal oxide particle and a carboxylic acid functional group of the polyester.
8. The pigment particle according to claim 3 , wherein the polyester is a linear amorphous polyester resin or a branched amorphous polyester resin.
9. The pigment particle according to claim 3 , wherein the polyester is selected from the group consisting of poly(1,2-propylene-diethylene)terephthalate, polyethylene-terephthalate, polypropylene-terephthalate, polybutylene-terephthalate, polypentylene-terephthalate, polyhexalene-terephthalate, polyheptadene-terephthalate, polyoctalene-terephthalate, polyethylene-sebacate, polypropylene-sebacate, polybutylene-sebacate, polyethylene-adipate, polypropylene-adipate, polybutylene-adipate, polypentylene-adipate, polyhexalene-adipate polyheptadene-adipate, polyoctalene-adipate, polyethylene-glutarate, polypropylene-glutarate, polybutylene-glutarate, polypentylene-glutarate, polyhexalene-glutarate, polyheptadene-glutarate, polyoctalene-glutarate, polyethylene-pimelate, polypropylene-pimelate, polybutylene-pimelate, polypentylene-pimelate, polyhexalene-pimelate, polyheptadene-pimelate, poly(propoxylated bisphenol co-fumarate), poly(ethoxylated bisphenol co-fumarate), poly(butyloxylated bisphenol co-fumarate), poly(co-propoxylated bisphenol co-ethoxylated bisphenol co-fumarate), poly(1,2-propylene fumarate), poly(propoxylated bisphenol co-maleate), poly(ethoxylated bisphenol co-maleate), poly(butyloxylated bisphenol co-maleate), poly(co-propoxylated bisphenol co-ethoxylated bisphenol co-maleate), poly(1,2-propylene maleate), poly(propoxylated bisphenol co-itaconate), poly(ethoxylated bisphenol co-itaconate), poly(butyloxylated bisphenol co-itaconate), poly(co-propoxylated bisphenol co-ethoxylated bisphenol co-itaconate), poly(1,2-propylene itaconate), and mixtures thereof.
10. The pigment particle according to claim 1 , wherein the metal oxide particle has an average size of from about 3 nm to about 700 nm.
11. The pigment particle according to claim 1 , wherein the metal oxide particle is selected from the group consisting of silicon dioxide, titanium dioxide and mixtures thereof.
12. The pigment particle according to claim 1 , wherein the metal oxide particle has an average size of from about 10 nm to about 50 nm.
13. The pigment particle according to claim 1 , further comprising carrier particles.
14. The pigment particle according to claim 1 , wherein the pigment particle is mixed with clear toner particles, and wherein the amount of clear toner particles mixed with the pigment particles is from about 20 to about 80 weight percent of the mixture.
15. A developer comprising:
a pigment particle comprising a pearlescent or metallic pigment base particle having at least one surface additive on a surface of the pearlescent or metallic pigment base particle;
wherein the at least one surface additive is a metal oxide particle coated with and covalently bonded to at least one polycondensation polymer.
16. The developer according to claim 15 , further comprising a carrier.
17. The developer according to claim 16 , wherein the carrier includes a carrier core selected from the group consisting of granular zircon, granular silicon, glass, steel, nickel, ferrites, magnetites, iron ferrites, silicon dioxide.
18. A method of making a pigment particle comprising:
with a pearlescent or metallic pigment base particle having at least one surface additive on a surface of the pearlescent or metallic pigment base particle, the at least one surface additive being a metal oxide particle, functionalizing a surface of the metal oxide particle on the pearlescent or metallic pigment base particle to form a functionalized group on the surface of the metal oxide particle; and
covalently bonding a polycondensation polymer with the functionalized group of the metal oxide particle.
19. The method according to claim 18 , wherein the metal oxide particle is a nano-sized metal oxide particle.
20. The method according to claim 18 , wherein the polycondensation polymer is a polyester.
21. The method according to claim 18 , wherein the metal oxide particle is selected from the group consisting of silicon dioxide, titanium dioxide and mixtures thereof.
22. The method according to claim 18 , further comprising, prior to the covalently bonding, functionalizing the polycondensation polymer to include a functional group for covalently bonding with the functional group of the metal oxide particle.