Heat-sealable propylene-based polymer composition, heat-sealable film, and uses thereof
The present invention is directed to a heat-sealable propylene-based polymer composition comprising a propylene polymer composition including a propylene polymer component and propylene/ethylene random copolymer component; an ethylene/α-olefin random copolymer; and a soft propylene polymer composition. The present invention also provides a heat-sealable film using the composition and a packaging bag comprising the film. The heat-sealable film of the present invention has high heat-seal strength, with little decrease in heat-seal strength even after heat treatment. The heat-sealable film also has excellent blocking resistance, rigidity and low-temperature impact resistance.
1. A heat-sealable propylene-based polymer composition comprising: a propylene polymer composition (A) comprising a propylene polymer component (a1) and a propylene/ethylene random copolymer component (a2) having a propylene unit content of 63 to 77% by mol and an ethylene unit content of 23 to 37% by mol,
an ethylene/α-olefin random copolymer (B), and
a soft propylene polymer composition (D) comprising a propylene polymer (d1) and a propylene/ethylene/α-olefin random copolymer (d2) which has an ethylene content of 2 to 30% by mol and an α-olefin content of 2 to 30% by mol and whose melting point, as measured by a differential scanning calorimeter (DSC), is not observed,
wherein:
(1) a mass ratio of the propylene polymer component (a1) to the propylene/ethylene random copolymer component (a2) in the propylene polymer composition (A) is in the range of 60:40 to 97:3, and the propylene/ethylene random copolymer component (a2) has an intrinsic viscosity [η] of 1 to 7 dl/g,
(2) the ethylene/α-olefin random copolymer (B) has a density of 0.865 to 0.910 g/cm 3 ,
(3) a mass ratio of the propylene polymer (d1) to the propylene/ethylene/α-olefin random copolymer (d2) in the soft propylene polymer composition (D) is in the range of 5:95 to 70:30, and
containing the propylene polymer composition (A) in an amount of 50 to 90% by mass, the ethylene/α-olefin random copolymer (B) in an amount of 3 to 25% by mass and the soft propylene polymer composition (D) in an amount of 0.5 to 40% by mass ((A)+(B)+(D) =100% by mass).
2. The heat-sealable propylene-based polymer composition as claimed in claim 1 , wherein the ethylene/α-olefin random copolymer (B) is an ethylene/1-butene random copolymer having a melting point (Tm) in the range of 30 to 110° C.
3. A heat-sealable film formed from the heat-sealable propylene-based polymer composition of claim 2 .
4. The heat-sealable film as claimed in claim 3 , which is a film for packaging an article to be heated/sterilized.
5. A package comprising an article to be heated/sterilized that is packaged by heat-sealing the heat-sealable film of claim 4 .
6. A heat-sealable laminated film having a base layer laminated on one surface of the heat-sealable film of claim 3 .
7. The heat-sealable laminated film as claimed in claim 6 , which is a film for packaging an article to be heated/sterilized.
8. A package comprising an article to be heated/sterilized that is packaged by heat-sealing the heat-sealable laminated film of claim 7 .
9. The heat-sealable propylene-based polymer composition as claimed in claim 1 , wherein the propylene polymer component (a1) contained in the propylene polymer composition (A) is a propylene homopolymer or a copolymer of propylene and an α-olefin of not more than 10% by mass.
10. The heat-sealable propylene-based polymer composition as claimed in claim 1 , wherein the ethylene/cc-olefin random copolymer (B) is a random copolymer of ethylene and an α-olefin of 4 to 10 carbon atoms.
11. The heat-sealable propylene-based polymer composition as claimed in claim 1 , wherein the propylene polymer (d1) contained in the soft propylene polymer composition (D) is a homopolypropylene or a propylene/α-olefin copolymer having a melting point of 110 to 165° C.