Method for the production of water absorbent polymer particles by polymerizing drops of a monomer solution
A process for preparing water-absorbing polymer beads by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, the initiator being added to the monomer solution from 0.5 to 60 seconds before the droplets are generated.
1. A process for preparing water-absorbing polymer beads by polymerizing droplets of a monomer solution comprising
a) at least one ethylenically unsaturated monomer,
b) at least one crosslinker,
c) at least one initiator,
d) water,
in a gas phase surrounding the droplets, which have a mean diameter of at least 200 μm, which comprises adding the initiator c) to the monomer solution from 0.5 to 30 seconds before the droplets are generated.
2. The process according to claim 1 , wherein the initiator is added upstream of a static mixer.
3. The process according to claim 1 , wherein an oxygen content of the monomer solution is at least 1 ppm by weight.
4. The process according to claim 1 , wherein the monomer solution comprises less than 160 ppm by weight, based on the ethylenically unsaturated monomer a), of a polymerization inhibitor.
5. The process according to claim 4 , wherein the polymerization inhibitor is hydroquinone monomethyl ether.
6. The process according to claim 1 , wherein the monomer a) has at least one acid group.
7. The process according to claim 6 , wherein the acid groups of the monomer a) have been at least partly neutralized.
8. The process according to claim 1 , wherein the monomer a) is acrylic acid to an extent of at least 50 mol %.
9. The process according to claim 1 , wherein the resulting polymer beads are dried and/or postcrosslinked in at least one further process step.
10. The process according to claim 1 , wherein the droplets of the monomer are monodisperse.
11. The process according to claim 10 , wherein the monodisperse droplets are formed by means of a dropletizer plate.
12. The process according to claim 1 , wherein the droplets of the monomer solution are polymerized in a laminar gas flow.
13. The process according to claim 1 , wherein the droplets have a mean diameter of at least 200 μm to 600 μm.
14. The process according to claim 1 , wherein the initiator c) is added to the monomer solution from 0.5 to 15 seconds before the droplets are generated.