Evaluation of the corrosion inhibiting activity of a coating
The corrosion inhibiting activity of a coating is determined from the effect of corrosion inhibiting species released by the coating on the oxygen reduction current for a cathode placed very close to the coating. A rotating disk electrode or pumped solution flow is used to sweep the corrosion inhibiting species from the coating surface to the cathode. The oxygen reduction current is measured under conditions of oxygen diffusion control.
1. An apparatus for evaluating the corrosion inhibiting activity of a coating, comprising:
a non-corroding rotating disk cathode comprising an oxygen reduction catalyst;
an anode;
an electrolytic solution;
a means for applying a voltage between said cathode and said anode, wherein said cathode, said anode and the coating are in electrical contact with said electrolytic solution, and said cathode is positioned a predetermined distance of less than 1.0 mm from the coating surface; and
a means for detecting corrosion inhibiting species released from said coating into said solution.
2. The apparatus of claim 1 , further comprising a reference electrode in electrical contact with said electrolytic solution.
3. The apparatus of claim 2 , wherein said means for applying a voltage between said cathode and said anode includes a potentiostat.
4. An apparatus for evaluating the corrosion inhibiting activity of a coating, comprising:
a non-corroding rotating disk cathode comprising an oxygen reduction catalyst;
an anode;
a reference electrode;
an electrolytic solution;
a potentiostat for applying a potential to said cathode relative to said reference electrode, wherein said cathode, said anode and the coating are in electrical contact with said electrolytic solution, and said cathode is positioned a predetermined distance of less than 1.0 mm from the coating surface; and
a means for detecting corrosion inhibiting species released from said coating into said solution.
5. The apparatus of claim 1 , wherein said means for detecting corrosion inhibiting species released from said coating into said solution comprises a means for monitoring the oxygen reduction current at said cathode.
6. The apparatus of claim 5 , further comprising a reference electrode in electrical contact with said electrolytic solution, wherein said means for monitoring the oxygen reduction current at said cathode comprises applying a potential to said cathode relative to said reference electrode such that diffusion limited oxygen reduction occurs at said cathode and corrosion inhibiting species released from said coating are transported to said cathode surface and suppress said oxygen reduction current.
7. The apparatus of claim 4 , wherein said means for detecting corrosion inhibiting species released from said coating into said solution comprises a means for monitoring the oxygen reduction current at said cathode.
8. The apparatus of claim 7 , wherein said means for monitoring the oxygen reduction current at said cathode comprises applying a potential to said cathode relative to said reference electrode such that diffusion limited oxygen reduction occurs at said cathode and corrosion inhibiting species released from said coating are transported to said cathode surface and suppress said oxygen reduction current.