Coating composition for marking substrates
Composition, which comprises a latent activator and a colour former, a process for the preparation of these compositions, substrates coated with these compositions and a process for their preparation, a process for preparing marked substrates using these compositions and marked substrates obtainable by the latter process.
1. A composition comprising a latent activator and a colour former,
wherein the latent activator is an ester derivative of an organic sulfuric acid selected from the group consisting of 4-styrene sulfonic acid, p-toluenesulfonic acid, benzene sulfonic acid, xylene sulfonic acid, phenol sulfonic acid, methane sulfonic acid, trifluormethane sulfonic acid, poly(4-styrene sulfonic acid) and copolymers comprising 4-styrene sulfonic acid units, and
wherein the colour former is selected from the group consisting of phthalides, fluorans, triarylmethanes, benzoxazines, quinazolines, spiropyrans, thiazines and oxazines and mixtures thereof.
2. The composition of claim 1 , wherein the composition also comprises a solvent.
3. The composition of claim 1 , wherein the composition also comprises a polymeric binder.
4. A process for preparing the composition of claim 1 , which comprises the step of mixing a latent activator and a colour former.
5. A substrate coated with the coating composition of claim 1 .
6. A process for preparing a coated substrate, which comprises the step of coating a substrate with the composition of claim 1 .
7. A process for preparing a marked substrate, which comprises the steps of i) coating a substrate with the composition of claim 1 , and ii) exposing those parts of the coated substrate, where a marking is intended, to energy in order to generate a marking.
8. The process of claim 7 , wherein the energy is selected from the group consisting of UV, IR, visible and microwave irradiation.
9. A marked substrate, which is obtained by the process of claim 6 .
10. The composition of claim 3 , wherein the polymeric binder is acrylic polymer, styrene polymer and hydrogenated products thereof, vinyl polymer and derivatives thereof, polyolefin and hydrogenated or epoxidized products thereof, aldehyde polymer, epoxide polymer, polyamide, polyester, polyurethane, sulfone-based polymer and natural polymers and derivatives thereof, or mixtures thereof.
11. The composition of claim 1 further comprising a char forming compound, wherein the char forming compound is selected from the group consisting of glucose, mannose, galactose, arabinose, fructose, ribose, erythrose, xylose, maltose, cellobiose, lactose, saccharose, cellulose, starch, gum arabic, dextrin, cyclodextrin, meso-erythritol, sorbitol, mannitol, and pentaerythritol.
12. The composition of claim 1 , wherein the latent activator is present in an amount of 1 to 50% by weight and the colour former is present in an amount of 0.1 to 50% by weight.
13. The composition of claim 3 , wherein the polymeric binder is present in an amount of 1 to 80% by weight.
14. The composition of claim 1 , wherein the colour former is 3,3-bis(p-dimethylaminophenyl)-6-dimethylaminophthalide, 3,3-bis(1-octyl-2-methylindol-3-yl)phthalide, or 3-diethylamino-7-(ethoxycarbonyl)-fluoran.