Mixed fiber and stretch nonwoven fabric comprising said mixed fiber and method for manufacture thereof
A fiber mixture according to the invention comprises fibers A comprising a polymer A containing a thermoplastic polyurethane elastomer and fibers B comprising a thermoplastic polymer B other than the thermoplastic polyurethane elastomer, said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 6 or less polar-solvent-insoluble particles per g counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter. An elastic nonwoven fabric comprises the fiber mixture.
1. A spunbonded elastic nonwoven fabric obtained by depositing a fiber mixture into the form of a web, wherein the fiber mixture comprises fibers A comprising a polymer A containing a thermoplastic polyurethane elastomer and fibers B comprising a thermoplastic polymer B other than the thermoplastic polyurethane elastomer, said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter.
2. The spunbonded elastic nonwoven fabric according to claim 1 , wherein the fiber B is an inelastic fiber.
3. The spunbonded elastic nonwoven fabric according to claim 1 , wherein the polymer A contains the thermoplastic polyurethane elastomer in an amount of 50 wt % or more.
4. The spunbonded elastic nonwoven fabric according to claim 1 , wherein on the thermoplastic polyurethane elastomer, a total heat of fusion (a) determined from endothermic peaks within the temperature range of from 90 to 140° C. and a total heat of fusion (b) determined from endothermic peaks within the temperature range of from above 140 to 220° C., which are measured by a differential scanning calorimeter (DSC), satisfy the following relation (1):
a /( a+b )×100≦80 (1).
5. A laminate comprising at least one layer comprising the spunbonded elastic nonwoven fabric of claim 1 .
6. A hygiene material comprising the spunbonded elastic nonwoven fabric of claim 1 .
7. A production method for spunbonded elastic nonwoven fabrics, said method comprising the steps of:
(I) separately melting a polymer A containing a thermoplastic polyurethane elastomer and a thermoplastic polymer B other than the thermoplastic polyurethane elastomer, said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter;
(II) extruding the polymer A and the polymer B simultaneously through a die having respective nozzles for the polymers to spin them and depositing fibers into the form of a web of fiber mixture;
(III) partially fusion bonding the web; and
(IV) stretching the partially fusion bonded web,
wherein the thermoplastic polyurethane elastomer used in the act (I) is produced by a production process comprising:
a step (A); an isocyanate compound, a polyol and a chain extender are mixed and stirred in advance,
a step (B); the mixture is fed to a static mixer or discharged on a belt to be heated to induce polymerization, and
a step (C); filtering the reaction product of the mixture after polymerization.
8. A spunbonded elastic nonwoven fabric obtained by depositing a fiber mixture into the form of a web, partially fusion bonding the deposit and stretching the partially fusion bonded web, wherein the fiber mixture has an average fiber diameter of 30 μm or less and comprises fibers A comprising a polymer A containing a thermoplastic polyurethane elastomer and fibers B comprising a thermoplastic polymer B other than the thermoplastic polyurethane elastomer, said thermoplastic polyurethane elastomer having a starting temperature for solidifying of 65° C. or above as measured by a differential scanning calorimeter (DSC) and containing 3.00×10 6 or less polar-solvent-insoluble particles per gram as counted on a particle size distribution analyzer, which is based on an electrical sensing zone method, equipped with an aperture tube having an orifice of 100 μm in diameter.
9. The spunbonded elastic nonwoven fabric according to claim 8 , wherein the fiber B is an inelastic fiber.
10. The spunbonded elastic nonwoven fabric according to claim 8 , wherein the polymer A contains the thermoplastic polyurethane elastomer in an amount of 50 wt % or more.
11. The spunbonded elastic nonwoven fabric according to claim 8 , wherein on the thermoplastic polyurethane elastomer, a total heat of fusion (a) determined from endothermic peaks within the temperature range of from 90 to 140° C. and a total heat of fusion (b) determined from endothermic peaks within the temperature range of from above 140 to 220° C., which are measured by a differential scanning calorimeter (DSC), satisfy the following relation (1):
a /( a+b )×100≦80 (1).
12. A laminate comprising at least one layer comprising the elastic nonwoven fabric of claim 8 .
13. A hygiene material comprising the spunbonded elastic nonwoven fabric of claim 8 .
14. The production method of claim 7 , wherein the step (C) is a filtering step using a metal mesh or a polymer filter.
15. The spunbonded elastic nonwoven fabric according to claim 1 , wherein the elastic nonwoven fabric is obtained by the production method of claim 7 .
16. The elastic nonwoven fabric according to claim 1 , wherein said elastic nonwoven fabric is obtained by partially fusion bonding the deposit and stretching the partially fusion bonded web.
17. The elastic nonwoven fabric according to claim 1 , wherein the fiber mixture has a fiber diameter of 30 μm or less.
18. The elastic nonwoven fabric according to claim 1 , wherein said elastic nonwoven fabric is obtained by partially fusion bonding the deposit and stretching the partially fusion bonded web, wherein the fiber mixture has a fiber diameter of 30 μm or less.
19. The elastic nonwoven fabric according to claim 1 , wherein the fiber B comprises at least one resin selected from a group of a resin containing polyethylene, a resin containing polypropylene, and a resin containing polyethylene and polypropylene.
20. The elastic nonwoven fabric according to claim 1 , wherein the fiber B comprises at least one resin selected from a group of polyethylene and polypropylene.
21. The spunbonded elastic nonwoven fabric according to claim 1 , wherein the thermoplastic polyurethane elastomer ranges in melt viscosity from 100 to 3,000 Pas as measured at 200° C. and 100 sec −1 shear rate.
22. The production method for spunbonded elastic nonwoven fabrics according to claim 7 , wherein the thermoplastic polyurethane elastomer ranges in melt viscosity from 100 to 3,000 Pa·s as measured at 200° C. and 100 sec −1 shear rate.
23. The spunbonded elastic nonwoven fabric according to claim 8 , wherein the thermoplastic polyurethane elastomer ranges in melt viscosity from 100 to 3,000 Pa·s as measured at 200° C. and 100 sec −1 shear rate.