IP Library Granted Patent US 8,022,142
Granted Patent B2
US 8,022,142 · App. 12/335,252 · Granted Sep 20, 2011

Thermoplastic olefin compositions

Assignee: ExxonMobil Chemical Patents Inc.
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Quick Facts
Patent No.
US 8,022,142
App. No.
12/335,252
Granted
Sep 20, 2011
Kind
B2
Abstract

An in-reactor polymer blend including (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.

Claims (27)

1. An in-reactor polymer blend comprising (a) a propylene-containing first polymer; and (b) a propylene-containing second polymer having a different crystallinity from the first polymer, wherein the polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, and an elongation at break of at least 300%.

2. The blend of claim 1 , wherein the propylene-containing first polymer has a weight average molecular weight ranging from about 20,000 g/mol to about 150,000 g/mol and has a higher crystallinity than the propylene-containing second polymer.

3. The blend of claim 1 , having a melting temperature, Tm, of at least 140° C.

4. The blend of claim 1 , having a melt flow rate of at least 100 dg/min.

5. The blend of claim 1 , having a complex viscosity at 190° C. of less than or equal to 4000 Pa·s.

6. The blend of claim 1 , wherein the ratio of the complex viscosity of the blend at a frequency of 100 rad/s to its zero shear viscosity is 0.25 or greater when measured at 190° C.

7. The polymer blend of claim 1 , wherein said first polymer comprises a propylene homopolymer.

8. The polymer blend of claim 1 , wherein said second polymer is a copolymer of propylene with ethylene.

9. The polymer blend of claim 1 , further comprising (c) a branched block product having peaks in the 44 to 45 ppm range in the 13 C-NMR spectrum.

10. An in-reactor polymer blend comprising (a) a propylene-containing first polymer; and (b) a propylene-containing second polymer having a different crystallinity from the first polymer, wherein the polymer blend has a melting temperature, Tm, of at least 135° C., a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%, and (c) a branched block product having peaks in the 44 to 45 ppm range in the 13 C-NMR spectrum.

11. The blend of claim 10 , having a melting temperature, Tm, of at least 140° C.

12. The blend of claim 10 , having a melt flow rate of at least 100 dg/min.

13. The blend of claim 10 , having a complex viscosity at 190° C. of less than or equal to 4000 Pa·s.

14. The blend of claim 10 , wherein the ratio of the complex viscosity of the blend at a frequency of 100 rad/s to its zero shear viscosity is 0.25 or greater when measured at 190° C.

15. The polymer blend of claim 10 , wherein said first polymer comprises a propylene homopolymer.

16. The polymer blend of claim 10 , wherein said second polymer is a copolymer of propylene with ethylene.

17. The polymer blend of claim 10 , wherein the propylene-containing first polymer has a weight average molecular weight ranging from about 20,000 g/mol to about 150,000 g/mol and has a higher crystallinity than the propylene-containing second polymer.

18. A process for producing a polymer blend, the process comprising:

(i) polymerizing at least one first monomer composition comprising propylene in a first polymerization zone under conditions sufficient to produce a propylene containing a first polymer comprising at least 50% vinyl chain ends; and

(ii) contacting at least part of said first polymer with a second monomer composition comprising propylene in a second polymerization zone separate from said first polymerization zone under conditions sufficient to polymerize said second monomer to produce a second polymer different in crystallinity from said first polymer by at least 5%.

19. The process of claim 18 , wherein the conditions employed in said polymerizing (i) comprise a first temperature and the conditions employed in said contacting (ii) include a second temperature higher than said first temperature.

20. The process of claim 18 , wherein the propylene-containing polymer having the higher crystallinity has a weight averaged molecular weight range from about 20,000 g/mol to about 150,000 g/mol.

21. The process of claim 18 , wherein the temperature in the polymerization zone making the polymer having the higher crystallinity is between about 90° C. and about 180° C.

22. The process of claim 18 , wherein the monomer concentration in said contacting (ii) is less than 5 mole/liter.

23. The process of claim 18 , wherein contacting (ii) includes producing a branched block product having peaks in the 44 to 45 ppm range in the 13 C-NMR spectrum.

24. A component molded from the in-reactor polymer blend of claim 1 .

25. A component molded from the in-reactor polymer blend of claim 10 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 15, 2008
From: JIANG, PEIJUN; DEKMEZIAN, ARMENAG H.; SQUIRE, KEVIN R.; DE GRACIA, CARLOS U.; JOLIBOIS, KEITH E.; GARCIA-FRANCO, CESAR A.; THACKSTON, RONALD R.
To: EXXONMOBIL CHEMICAL PATENTS INC.
Reel/Frame 021981/0305 →
Continuity (1)
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