Shale hydration inhibition agent(s) and method of use
View Patent ↗A water-based drilling fluid and method of using same are presented in this disclosure, which fluid is used in drilling wells through a formation containing a shale that swells in the presence of water. The drilling fluid comprises an aqueous based continuous phase; a weighting material; and a shale hydration inhibition agent (SHIA) selected from the group consisting of propylamine derivatives, hydrogenated poly(propyleneimine) dendrimers (HPPID), and polyamine twin dendrimers (PTD). In some embodiments, the SHIA of this disclosure is not hydrolyzed at a temperature in the range of from about 100° F. to about 500° F. The drilling fluid may further comprise a fluid loss control agent, an encapsulating agent, other additives, and combinations thereof. A method of reducing shale swelling during wellbore drilling is also described. The method comprises circulating in the subterranean well a water-based drilling fluid comprising an aqueous based continuous phase, a weighting material, and a SHIA.
1. A water-based drilling fluid for use in drilling wells through a formation containing a shale which swells in the presence of water, the drilling fluid comprising:
an aqueous based continuous phase;
a weighting material; and
a shale hydration inhibition agent (SHIA) selected from the group consisting of
(a) propylamine derivatives having the formula:
R—Y—(CH 2 ) n —NH 2
wherein n=3; Y═O or N; R=one or more —CH 3 groups or a morpholino group;
(b) hydrogenated poly(propyleneimine) dendrimers (HPPID) having a core with the formula N(-A-N*)3 and branches with the formula —H 2 or -(AN*H 2 ) 2
wherein A=(CH 2 ) 3 and N* is the growth point where two additional branches are attached; and
(c) polyamine twin dendrimers (PTD) having a core with the formula
H 2 N—(CH 2 ) x —NH 2
wherein 2≦x≦6, and branches B with the formula —(CH 2 —CH 2 —CH 2 —NH 2 ), wherein the core and the branches are arranged as:
(B) 2 n . . . —(B) 8 —(B) 4 —(B) 2 —[H 2 N—(CH 2 ) x —NH 2 ]—(B) 2 —(B) 4 —(B) 8 — . . . (B) 2 n
wherein n is the dendrimer growth generation number and n<10;
wherein the SHIA is present in a sufficient amount to reduce shale swelling.
2. The propylamine derivative of claim 1 is 3-methoxypropylamine (MOPA), having the formula:
CH 3 —O—(CH 2 ) 3 —NH 2
wherein R═CH 3 and Y═O.
3. The propylamine derivative of claim 1 is dimethylaminopropylamine (DMAPA), having the formula:
(CH 3 ) 2 —N—(CH 2 ) 3 —NH 2
wherein R═(CH 3 ) 2 and Y═N.
4. The propylamine derivative of claim 1 is N-aminopropylmorpholine (APM), having the formula:
wherein R=a cyclic morpholino group and Y═N.
5. The HPPID of claim 1 is a first generation HPPID having the formula:
N-(A-NH 2 ) 3 ;
wherein A=(CH 2 ) 3 .
6. The HPPID of claim 1 is a second generation HPPID having the formula:
N-[A-N(A-NH 2 ) 2 ] 3 ;
wherein A=(CH 2 ) 3 .
7. The HPPID of claim 1 is a third generation HPPID having the formula:
N-{A-N-[A-N(A-NH 2 ) 2 ] 2 } 3 ;
wherein A=(CH 2 ) 3 .
8. The HPPID of claim 1 has a molecular weight of from about 150 to about 5800.
9. The core of the PTD according to claim 1 is selected from the group consisting of ethylene diamine, propylene diamine, and hexamethylene diamine.
10. The PTD of claim 1 has a molecular weight of from about 250 to about 7500.
11. The method of claim 1 , wherein said SHIA is not hydrolyzed at a temperature in the range of from about 100° F. to about 500° F.
12. The drilling fluid of claim 1 , wherein said aqueous based continuous phase is selected from the group consisting of fresh water, sea water, brine, mixtures of water and water soluble organic compounds, and combinations thereof.
13. The drilling fluid of claim 1 , wherein said weighting material is selected from the group consisting of barite, hematite, iron oxide, calcium carbonate, magnesium carbonate, organic and inorganic salts, and combinations thereof.
14. The drilling fluid of claim 1 further comprises a fluid loss control agent.
15. The drilling fluid of claim 1 further comprises an encapsulating agent, selected from the group consisting of synthetic materials, organic materials, inorganic materials, bio-polymers, and combinations thereof.
16. A method of reducing shale swelling encountered during the drilling of a subterranean well, the method comprising:
circulating in the subterranean well a water-based drilling fluid comprising an aqueous based continuous phase, a weighting material, and a SHIA selected from the group consisting of
(a) propylamine derivatives having the formula:
R—Y—(CH 2 ) n —NH 2
wherein n=3; Y═O or N; R=one or more —CH 3 groups or a morpholino group;
(b) hydrogenated poly(propyleneimine) dendrimers (HPPID) having a core with the formula N(-A-N*) 3 and branches with the formula —H 2 or -(AN*H 2 ) 2
wherein A=(CH 2 ) 3 and N* is the growth point where two additional branches are attached; and
(c) polyamine twin dendrimers (PTD) having a core with the formula
H 2 N—(CH 2 ) x —NH 2
wherein 2≦x≦6, and branches B with the formula —(CH 2 —CH 2 —CH 2 —NH 2 ), wherein the core and the branches are arranged as:
(B) 2 n . . . —(B) 8 —(B) 4 —(B) 2 —[H 2 N—(CH 2 ) x —NH 2 ]—(B) 2 —(B) 4 —(B) 8 — . . . (B) 2 n
wherein n is the dendrimer growth generation number and n<10;
wherein the SHIA is present in a sufficient amount to reduce shale swelling.
17. The method of claim 16 further comprising treating said SHIA prior to introducing SHIA to a drilling fluid with a mineral acid or an organic acid.
18. The method of claim 17 , wherein said acid is selected from the group consisting of hydrochloric acid (HCl), sulfuric acid (H 2 SO 4 ), nitric acid (HNO 3 ), phosphoric acid (H 3 PO 4 ), carbonic acid, formic acid, acetic acid, propionic acid, benzoic acid, and combinations thereof.
19. The method of claim 16 further comprising adjusting the pH of said SHIA prior to introducing the SHIA to a drilling fluid to be in the range of from about 6.0 to about 10.0.
20. The method of claim 16 further comprising adjusting the pH of a drilling fluid prior to introducing SHIA to the drilling fluid to be in the range of from about 6.5 to about 12.0.