Method for manufacturing semiconductor device
View Patent ↗An object is to suppress discharge due to static electricity generated by peeling, when an element formation layer including a semiconductor element is peeled from a substrate. Over the substrate, the release layer and the element formation layer are formed. The support base material which can be peeled later is fixed to the upper surface of the element formation layer. The element formation layer is transformed through the support base material, and peeling is generated at an interface between the element formation layer and the release layer. Peeling is performed while the liquid is being supplied so that the element formation layer and the release layer which appear sequentially by peeling are wetted with the liquid such as pure water. Electric charge generated on the surfaces of the element formation layer and the release layer can be diffused by the liquid, and discharge by peeling electrification can be eliminated.
1. A method for manufacturing a semiconductor device, comprising:
forming a metal film over a substrate;
forming a silicon oxide film over the metal film;
forming a base insulating layer over the silicon oxide film;
forming a circuit including a thin film transistor over the base insulating layer; and
peeling the circuit from the substrate by applying a mechanical external force,
wherein the circuit is peeled while a surface which is exposed by peeling the circuit is wetted with water,
wherein discharge due to peeling electrification in the step of peeling is preventable by wetting the surface with the water, and
wherein the liquid spreads to wet a surface which is exposed as the peeling of the circuit proceeds.
2. The method for manufacturing the semiconductor device according to claim 1 , wherein the metal film comprises at least one metal element selected from tungsten, molybdenum, titanium, tantalum, niobium, nickel, cobalt, zirconium, zinc, ruthenium, rhodium, palladium, osmium and iridium.
3. The method for manufacturing the semiconductor device according to claim 1 , wherein a surface of the metal film is oxidized.
4. The method for manufacturing the semiconductor device according to claim 1 , wherein the peeling step is performed while the substrate is immersed in the water.
5. A method for manufacturing a semiconductor device, comprising:
forming a release layer over a substrate;
forming an element formation layer including a semiconductor element over the release layer;
generating peeling at an interface between the release layer and the element formation layer;
supplying liquid to a portion where the peeling is generated; and
after the supplying step, further peeling the element formation layer from the substrate by applying a mechanical external force while a surface which is exposed by the peeling is wetted with the liquid,
wherein discharge due to peeling electrification in the step of further peeling is preventable by wetting the surface with the liquid, and
wherein the liquid spreads to wet a surface which is exposed as the peeling of the element formation layer proceeds.
6. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is pure water.
7. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is an aqueous solution of salt, carbon dioxide, or hydrogen chloride.
8. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid comprises water and volatile liquid.
9. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is an organic solvent.
10. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is supplied by dropping.
11. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is supplied by pouring.
12. The method for manufacturing the semiconductor device according to claim 5 , wherein the liquid is supplied by immersing the substrate in the liquid.
13. The method for manufacturing the semiconductor device according to claim 5 , wherein the further peeling step is performed while the substrate is immersed in the liquid.
14. The method for manufacturing the semiconductor device according to claim 5 , wherein the release layer comprises metal.
15. A method for manufacturing a semiconductor device, comprising:
forming a release layer over a substrate;
forming an element formation layer including a semiconductor element over the release layer;
generating peeling at an interface between the release layer and the substrate;
supplying liquid to a portion where the peeling is generated; and
after the supplying step, further peeling the element formation layer from the substrate by applying a mechanical external force while a surface which is exposed by the peeling is wetted with liquid,
wherein discharge due to peeling electrification in the step of further peeling is preventable by wetting the surface with the liquid, and
wherein the liquid spreads to wet a surface which is exposed as the peeling of the element formation layer proceeds.
16. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is pure water.
17. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is an aqueous solution of salt, carbon dioxide, or hydrogen chloride.
18. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid comprises water and volatile liquid.
19. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is an organic solvent.
20. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is supplied by dropping.
21. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is supplied by pouring.
22. The method for manufacturing the semiconductor device according to claim 15 , wherein the liquid is supplied by immersing the substrate in the liquid.
23. The method for manufacturing the semiconductor device according to claim 15 , wherein the further peeling step is performed while the substrate is immersed in the liquid.
24. The method for manufacturing the semiconductor device according to claim 15 , wherein the release layer comprises metal.
25. A method for manufacturing a semiconductor device, comprising:
forming a release layer over a substrate;
forming an element formation layer including a semiconductor element over the release layer;
generating peeling inside the release layer;
supplying liquid to a portion where the peeling is generated; and
after the supplying step, further peeling the element formation layer from the substrate by applying a mechanical external force while a surface which is exposed by the peeling is wetted with liquid,
wherein discharge due to peeling electrification in the step of further peeling is preventable by wetting the surface with the liquid, and
wherein the liquid spreads to wet a surface which is exposed as the peeling of the element formation layer proceeds.
26. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is pure water.
27. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is an aqueous solution of salt, carbon dioxide, or hydrogen chloride.
28. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid comprises water and volatile liquid.
29. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is an organic solvent.
30. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is supplied by dropping.
31. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is supplied by pouring.
32. The method for manufacturing the semiconductor device according to claim 25 , wherein the liquid is supplied by immersing the substrate in the liquid.
33. The method for manufacturing the semiconductor device according to claim 25 , wherein the further peeling step is performed while the substrate is immersed in the liquid.
34. The method for manufacturing the semiconductor device according to claim 25 , wherein the release layer comprises metal.
35. A method for manufacturing a semiconductor device, comprising:
forming a release layer over a substrate;
forming an element formation layer including a semiconductor element over the release layer;
forming a groove in the element formation layer;
generating a gap between the release layer and the element formation layer;
supplying liquid to the gap; and
after the supplying step, peeling the element formation layer from the substrate by applying a mechanical external force while a surface which is exposed by the peeling is wetted with the liquid,
wherein discharge due to peeling electrification in the step of peeling is preventable by wetting the surface with the liquid, and
wherein the liquid spreads to wet a surface which is exposed as the peeling of the element formation layer proceeds.
36. The method for manufacturing the semiconductor device according to claim 35 , wherein the liquid is pure water.
37. The method for manufacturing the semiconductor device according to claim 35 , wherein the liquid is an aqueous solution of salt, carbon dioxide, or hydrogen chloride.
38. The method for manufacturing the semiconductor device according to claim 35 , wherein the liquid comprises water and volatile liquid.
39. The method for manufacturing the semiconductor device according to claim 35 , wherein the liquid is an organic solvent.
40. The method for manufacturing the semiconductor device according to claim 35 , wherein the groove is formed by irradiation with a laser beam.