Purification process for organic electronics material
View Patent ↗Objects of the present invention are to provide a purification process that enables Pd contained in an organic electronics material to be removed effectively, to provide an electroluminescent device middle layer material purified by the process, and to provide an electroluminescent device employing the middle layer material. The present invention relates to a process for purifying an organic electronics material, the process involving treating, with a phosphorus-containing material, an organic electronics material that contains Pd as an impurity so as to remove the Pd.
1. A method of making an electroluminescent device, comprising:
a purification step of treating, with a material modified by a phosphorus atom-containing compound, an organic electronics material that contains Pd as an impurity so as to remove Pd; and
a step of making a middle layer of an electroluminescent device using the organic electronics material which is purified at the purification step,
wherein the phosphorous atom-containing compound is any one of a phosphine (R 3 P), a phosphate ((RO) 3 PO),a phosphite ((RO) 3 P) and derivatives thereof, where R independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, an aryl group, or an aralkyl group;
wherein the material is any one of silica gel, alumina, zirconia, titania, crosslinked polystyrene, polymethacrylate and styrene-divinylbenzene copolymer.
2. The method of making an electroluminescent device according to claim 1 ,
wherein the phosphine is any one of hydrogen phosphide PH 3 , a primary phosphine RPH 2 , a secondary phosphine R 2 PH, and a tertiary phosphine R 3 P, where R independently represents a substituted or unsubstituted alkyl group, aryl group, or aralkyl group.