Dielectric composition and ceramic electronic component manufactured therefrom
Provided are a dielectric composition and a ceramic electronic component including the same. The dielectric composition includes (a) barium titanate having a specific surface area of 2.5 m2/g to 6.0 m2/g; (b) a mixture containing at least one or more materials selected from the group consisting of any one oxide of Mg, Ca, Sr, Ba and Zr, and any one carbonate thereof; (c) oxide containing at least one or more materials selected from the group consisting of Sc, Y, La, Ac, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; (d) oxide containing at least one or more material selected from the group consisting of Cr, Mn, Fe, Co, and Ni; (e) oxide containing at least one or more material selected from the group consisting of V, Nb, and Ta; and (f) oxide containing at least one or more material selected from the group consisting of Si and Al. The dielectric composition can satisfy X8R characteristic, can be sintered at a low temperature, and can obtain high reliability.
1. A dielectric composition comprising:
(a) barium titanate having a specific surface area of 2.5 m 2 /g to 6.0 m 2 /g;
(b) a mixture containing at least one or more materials selected from the group consisting of any one oxide of Ca, Sr, Ba and Zr, and any one carbonate thereof;
(c) oxide containing at least one or more materials selected from the group consisting of Sc, Y, La, Ac, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Tm, Yb, and Lu;
(d) oxide containing at least one or more material selected from the group consisting of Cr, Fe, Co, and Ni;
(e) oxide containing at least one or more material selected from the group consisting of Nb and Ta; and
(f) oxide containing at least one or more material selected from the group consisting of Si and Al,
wherein a value of [((total number of moles of the (b) component)−(number of moles of the Zr oxide))/(number of moles of the (f) component)] is in a range of 1 to 1.5, and wherein a value of [(number of moles of the (c) component)/(number of moles of the (f) component)] is in a range of 1.5 to 3.
2. The dielectric composition according to claim 1 ,
wherein the barium titanate is expressed as Ba m TiO 3 , where 0.995≦m<0.999.
3. The dielectric composition according to claim 1 ,
wherein a specific surface area of a mixture containing the (b) component, the (c) component, the (d) component, the (e) component, and the (f) component is in a range of 5.0 m 2 /g to 100 m 2 /g.
4. The dielectric composition according to claim 1 , further comprising:
(g) Li oxide, wherein the content of the (g) component is 0.01 mol to 0.6 mol relative to 100 mol of the (a) component.
5. The dielectric composition according to claim 4 ,
wherein a specific surface area of a mixture containing the (b) component, the (c) component, the (d) component, the (e) component, the (f) component, and the (g) component is in a range of 5.0 m 2 /g to 100 m 2 /g.
6. The dielectric composition according to claim 1 ,
wherein the (b) component and the (e) component have a single oxide form.
7. A dielectric composition comprising:
(a) barium titanate having a specific surface area of 2.5 m 2 /g to 6.0 m 2 /g;
(b) a mixture containing at least one or more materials selected from the group consisting of any one oxide of Ca, Sr, Ba and Zr, and any one carbonate thereof;
(c) oxide containing at least one or more materials selected from the group consisting of Sc, Y, La, Ac, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Tm, Yb, and Lu;
(d) oxide containing at least one or more material selected from the group consisting of Cr, Fe, Co, and Ni;
(e) oxide containing at least one or more material selected from the group consisting of Nb and Ta; and
(f) oxide containing at least one or more material selected from the group consisting of Si and Al,
wherein a value of [((total number of moles of the (b) component)−(number of moles of the Zr oxide))/(number of moles of the (f) component)] is in a range of 1 to 1.5, and
wherein a value of [(number of moles of the (c) component)/(number of moles of the (f) component)] is in a range of 1.5 to 3,
wherein the content of the (b) component is 3 mol to 10 mol relative to 100 mol of the (a) component;
the content of the (c) component is 3.2 mol to 9 mol relative to 100 mol of the (a) component;
the content of the (d) component is 0.01 mol to 1 mol relative to 100 mol of the (a) component;
the content of the (e) component is 0.01 mol to 1 mol relative to 100 mol of the (a) component; and
the content of the (f) component is 1.5 mol to 5 mol relative to 100 mol of the (a) component.