Lightly doped silicon carbide wafer and use thereof in high power devices
View Patent ↗A method for manufacturing a silicon carbide single crystal. A silicon carbide single crystal is grown. The crystal has a boron concentration less than 5×10 14 cm −3 , and a concentration of transition metals impurities less than 5×10 14 cm −3 . Intrinsic defects in the crystal are minimised. The intrinsic defects include silicon vacancies or carbon vacancies. The crystal is annealed for a desired time at a temperature above 700° C. in an atmosphere containing any of the gases hydrogen or a mixture of hydrogen and an inert gas, such that the density of intrinsic defects and any associated defects is decreased to a concentration low enough to confer to the crystal a desired carrier life time of at least 50 ns at room temperature.
1. A method for manufacturing a silicon carbide single crystal, the method comprising:
growing a silicon carbide single crystal, wherein:
said crystal has a boron concentration less than 5×10 14 cm −3 , and a concentration of transition metals impurities less than 5×10 14 cm −3 ,
intrinsic defects in the crystal are minimised and
said intrinsic defects comprising silicon vacancies or carbon vacancies
and
annealing, for a desired time, said crystal at a temperature above 700° C. in an atmosphere containing any of the gases:
hydrogen,
a mixture of hydrogen and an inert gas
so that the density of intrinsic defects and any associated defects is decreased to a concentration low enough to confer to the crystal a desired carrier life time of at least 50 ns at room temperature.
2. The method according to claim 1 , further comprising:
slicing and polishing a wafer from said crystal before the step of annealing the crystal.
3. The method according to claim 1 , further comprising:
slicing a wafer from said crystal.
4. The method according to claim 3 , further comprising:
polishing said wafer.
5. The method for growing said single crystal of silicon carbide according to claim 1 , wherein the method further comprising:
introducing a flow of silicon and carbon atoms containing gases into an enclosure,
heating the enclosure containing a seed silicon carbide crystal to a temperature above 1900° C., in such a way that the temperature of the seed crystal remains lower than the temperature at which it would decompose under the partial pressures of the Si and C containing species introduced into the heated enclosure,
maintaining the flows of silicon gas and carbon gas and the temperature above 1900° C. for a sufficient time so that a bulk crystal is grown, and
introducing into the crystal, during the time of its growth, a flow of a dopant to make the crystal either n- or p-type.
6. The method according to claim 5 , further comprising:
cooling down the crystal from the growth temperature to room temperature at a rate sufficiently slow to decrease the concentration of intrinsic levels below the concentration of shallow impurities acting as dopants.
7. The method according to claim 5 , wherein the carbon containing gas comprises a hydrocarbon chosen from the group of methane, ethylene and propane.
8. The method according to claim 5 , wherein the silicon containing gas is chosen from the group of silane, a chlorosilane compound and a methylsilane compound.
9. The method according to claim 1 , wherein said crystal has a boron concentration less than 5×10 13 cm −3 , and a concentration of transition metals impurities less than 5×10 13 cm −3 .