Photosensitive resin composition, light-shielding color filter and production process therefor, and image sensor
A photosensitive resin composition is provided that includes at least (A) titanium black, (B) a polymerizable compound, (C) a photopolymerization initiator (D) a resin, and (E) an organic solvent, the photopolymerization initiator (C) using in combination two or more types of photopolymerization initiators including at least one type of oxime-based photopolymerization initiator. There are also provided a light-shielding color filter having a pattern formed by using the photosensitive resin composition, a process for producing a light-shielding color filter that includes a step of coating a substrate with the photosensitive resin composition, a step of imagewise exposing, and a step of developing to form a pattern, and an image sensor having the light-shielding color filter.
1. A photosensitive resin composition comprising at least:
(A) titanium black;
(B) a polymerizable compound;
(C) a photopolymerization initiator;
(D) a resin; and
(E) an organic solvent,
the photopolymerization initiator (C) comprising in combination two or more types of oxime-based photopolymerization initiators including at least 2-(O-benzoyloxime)-1-[4-(phenylthio)phenyl]-1,2-octanedione and 1-(O-acetyloxime)-1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]ethanone.
2. The photosensitive resin composition according to claim 1 , wherein the photopolymerization initiator (C) comprises in combination 2-(O-benzoyloxime)-1-[4-(phenylthio)phenyl]-1,2-octanedione and 1-(O-acetyloxime)-1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]ethanone at a molar ratio of 1/9 to 9/1.
3. The photosensitive resin composition according to claim 1 , wherein the titanium black (A) has a content of 10 to 60 wt % of the total solids content of the photosensitive resin composition.
4. The photosensitive resin composition according to claim 1 , wherein the photopolymerization initiator (C) has a total content of 1 to 30 wt % of the total solids content of the photosensitive resin composition.
5. A light-shielding color filter comprising a pattern formed by using the photosenitive resin composition according to claim 1 .
6. An image sensor comprising the light-shielding color filter according to claim 5 .
7. A process for producing a light-shielding color filter, the process comprising:
a step of coating a substrate with the photosensitive resin composition according to claim 1 ;
a step of imagewise exposing; and
a step of developing to form a pattern.