Method for forming conductive film, thin-film transistor, panel with thin-film transistor, and method for manufacturing thin-film transistor
A conductive film having high adhesion and low specific resistance is formed. A target containing copper as a main component is sputtered in vacuum ambience while an oxygen gas introduced, and then, a conductive film containing copper as a main component and additive metals, such as Ti or Zr, is formed. Such a conductive film has high adhesion to a silicon layer and a glass substrate and is hardly peeled off from the substrate. Furthermore, the specific resistance is low and the contact resistance to a transparent conductive film is also low. Thus, no deterioration in the electric characteristics occurs even when the conductive film is used for an electrode film. Accordingly, the conductive film formed by the present invention suited for TFT, and electrode films and barrier films of semiconductor elements, in particular.
1. A method for forming a conductive film of which forming a conductive film including copper as a main component and additive metal on a surface of an object to be film formed in vacuum ambience by a sputtering method, the method comprising the step of
sputtering a target containing copper as a main component and at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, into the vacuum ambience, such that a ratio of a partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, thereby making the conductive film include the additive metal therein.
2. The method for forming a conductive film according to claim 1 , wherein
the conductive film is formed on at least one of a surface of a silicon layer and a surface of a glass substrate by using the object to be film formed where at least one of the silicon layer and the glass substrate is exposed at least a part of a surface of the object.
3. The method for forming a conductive film according to claim 1 , wherein Ti is selected as the additive metal and oxygen gas is used as the oxidation gas, and
the oxygen gas is introduced such that the conductive film contains at least 0.1 atom % Ti.
4. The method for forming a conductive film according to claim 1 , wherein Zr is selected as the additive metal and oxygen gas is used as the oxidation gas, and
the oxygen gas is introduced such that the conductive film includes at least 0.1 atom % Zr.
5. The method for forming a conductive film according to claim 1 , wherein
the object to be film formed, of which a transparent conductive film is exposed to at least a part of a surface thereof is used, and
wherein the conductive film is formed on a surface of the transparent conductive film.
6. A method for manufacturing a thin-film transistor having a conductive film being in contact with a silicon layer, the method comprising the step of:
sputtering a target in a vacuum ambience so as to form the conductive film, the target containing copper as a main component and containing at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, such that a ratio of partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, into the vacuum ambience.
7. A method for manufacturing a thin-film transistor having a conductive film being in contact with a transparent conductive film, the method comprising the step of:
sputtering a target in a vacuum ambience so as to form the conductive film, the target containing copper as a main component and containing at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, such that a ratio of partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, into the vacuum ambience.
8. A method for manufacturing a thin-film transistor having a conductive film being in contact with a glass substrate, the method comprising the step of:
sputtering a target in a vacuum ambience to form the conductive film, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, such that a ratio of partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, into the vacuum ambience, and
wherein the target contains copper as a main component and contains at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd.
9. A method for manufacturing a thin-film transistor having a conductive film being in contact with a silicon layer and a transparent conductive film, the method comprising the step of:
sputtering a target in a vacuum ambience to form the conductive film, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, such that a ratio of partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, into the vacuum ambience, and
wherein the target contains copper as a main component and contains at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd.
10. A method for manufacturing a thin-film transistor having a silicon layer containing silicon as a main component, a first conductive film being in contact with the silicon layer, a copper film containing copper as a main component and formed on a surface of the first conductive film, and a second conductive film formed on a surface of the copper film, the second conductive film being in contact with a transparent conductive film, the method comprising the step of:
sputtering a target in a vacuum ambience so as to form the first and second conductive films, while supplying an oxidation gas that has oxygen atoms in its chemical structure, for reaction with the additive metal, such that a ratio of partial pressure of the oxidation gas to a total pressure of the vacuum ambience is at least 0.1% and at most 20%, into the vacuum ambience, and
wherein the target contains copper as a main component and contains at least any one type of additive metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Os, Co, Ni, Bi, Ag, Zn, Sn, B, C, Al, Si, La, Ce, Pr, and Nd.