Process for producing glass substrate and glass substrate
Provided are a process for producing a glass substrate usable for low-temperature p-SiTFT substrates directly in accordance with a down draw method, and the glass substrate obtained by the process. The process for producing a glass substrate includes a forming step of forming a molten glass into a ribbon shape in accordance with a down draw method, an annealing step of annealing the glass ribbon, and a cutting step of cutting the glass ribbon to give a glass substrate, in which, in the annealing step, an average cooling rate from the annealing point to the (annealing point −50° C.) is lower than an average cooling rate from the (annealing point +100° C.) to the annealing point.
1. A process for producing a glass substrate, comprising:
a forming step of forming a molten glass into a ribbon shape in accordance with a down draw method,
an annealing step of annealing said glass ribbon, and
a cutting step of cutting said glass ribbon to give a glass substrate,
wherein the annealing step comprises a first annealing stage of cooling the glass ribbon from (annealing point +100° C.) to the annealing point and a second annealing stage of cooling the glass ribbon from the annealing point to (annealing point −50° C.),
wherein an average cooling rate in the second annealing stage is 10° C./min or more lower than an average cooling rate in the first annealing stage.
2. The process for producing a glass substrate according to claim 1 , wherein the average cooling rate of the first annealing stage is 30° C./min or higher.
3. A process for producing a glass substrate, comprising:
a forming step of forming a molten glass into a ribbon shape in accordance with a down draw method,
an annealing step of annealing said glass ribbon, and
a cutting step of cutting said glass ribbon to give a glass substrate, wherein the annealing step includes;
a first annealing stage of cooling the glass to the annealing point, wherein the first annealing stage is defined as from (annealing point +100° C.) to the annealing point,
a second annealing stage of cooling the glass down from the annealing point to Tx, wherein Tx is a temperature falling between the (annealing point −50° C.) and the (annealing point −200° C.), and
a third annealing stage of cooling the glass down to (Tx −250° C.), and
an average cooling rate in the second annealing stage is 10° C./min or more lower than an average cooling rate in the first annealing stage.
4. The process for producing a glass substrate according to claim 3 , wherein the average cooling rate in the first annealing stage is 30° C./min or higher.
5. The process for producing a glass substrate according to claim 3 , wherein an average cooling rate in the third annealing stage is higher than the average cooling rate in the second annealing stage.
6. The process for producing a glass substrate according to claim 3 , wherein the average cooling rate in the third annealing stage, which is defined as an average cooling rate from Tx to (Tx −250° C.), is 50° C./min or higher.
7. The process for producing a glass substrate according to claim 1 or 3 , wherein the molten glass is formed such that said glass ribbon has an effective width of 500 mm or more.
8. The process for producing a glass substrate according to claim 1 or 3 , wherein the down draw method is an overflow down draw method.
9. The process for producing a glass substrate according to claim 1 or 3 , wherein a glass having a liquidus viscosity of 10 4.5 dPa·s or more is used.
10. The process for producing a glass substrate according to claim 1 or 3 , wherein a glass having a strain point of not lower than 600° C. is used.
11. The process for producing a glass substrate according to claim 1 or 3 , wherein a glass containing, in terms of percentage by mass, from 50 to 70% of SiO 2 , from 10 to 25% of Al 2 O 3 , from 3 to 15% of B 2 O 3 , from 0 to 10% of MgO, from 0 to 15% of CaO, from 0 to 15% of SrO, from 0 to 15% of BaO and from 0 to 5% of Na 2 O is used.
12. The process for producing a glass substrate according to claim 1 or 3 , which is a production process for a glass substrate to be used in a flat panel display.
13. The process for producing a glass substrate according to claim 12 , wherein the flat panel display is a display in which a low-temperature p-SiTFT is formed on the substrate.