Zinc oxide thin film, transparent conductive film and display device using the same
A zinc oxide thin film having desired crystallinity is fabricated. The present invention provides a zinc oxide thin film which laminated on a substrate, and which is a crystalline thin film of a wurtzite form. The c-axis of the crystalline thin film is oriented in a direction substantially perpendicular to the substrate. A zinc surface of being one polar surface of the crystalline thin film in the c-axis direction is formed in the uppermost layer. In addition, the invention also provides a zinc oxide thin film which is laminated on a substrate, and which is a crystalline thin film of a wurtzite form. The zinc oxide thin film is formed on a metal thin film layer by a thin film fabricating technique.
1. A zinc oxide thin film laminated on a substrate, comprising:
a first metal thin film layer on which the zinc oxide thin film is formed by a thin film fabricating technique,
wherein the zinc oxide thin film is a crystalline thin film of a wurtzite form, and
a second metal thin film layer different from the zinc oxide thin film laminated directly on the crystalline thin film,
wherein the second metal thin film layer is metal zinc.
2. The zinc oxide thin film according to claim 1 , wherein the second metal thin film layer is a transparent electrode film.
3. The zinc oxide thin film according to claim 1 , wherein the film thickness of the first metal thin film layer is from 1 nm to 20 nm.
4. The zinc oxide thin film according to claim 1 , wherein the first metal thin film layer has a positive ionic polar substituent group on the upper surface.
5. The zinc oxide thin film according to claim 1 , wherein the film thickness of the second metal thin film layer is from 1 nm to 20 nm.
6. A zinc oxide thin film laminated on an amorphous substrate comprising:
a metal thin film layer, which is formed on the amorphous substrate;
a zinc oxide thin film, which is formed on the metal thin film layer; and
a second metal thin film layer, which is formed on the zinc oxide thin film, wherein the second metal thin film layer is different from the zinc oxide thin film,
wherein the zinc oxide thin film is a crystalline thin film of a wurtzite form, the c-axis of the zinc oxide thin film is oriented in a direction substantially perpendicular to the amorphous substrate, a zinc surface is formed in an uppermost layer of the zinc oxide thin film, and the zinc surface is a polar surface of the zinc oxide thin film in the c-axis direction.
7. The zinc oxide thin film according to claim 6 , wherein the a-axis direction of the crystalline thin film is oriented in one direction within the surface of the zinc oxide thin film.