IP Library Granted Patent US 8,148,264
Granted Patent B2
US 8,148,264 · App. 12/711,992 · Granted Apr 3, 2012

Methods for fabrication of high aspect ratio micropillars and nanopillars

Assignee: California Institue of Technology
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Quick Facts
Patent No.
US 8,148,264
App. No.
12/711,992
Granted
Apr 3, 2012
Kind
B2
Abstract

Methods for fabrication of high aspect ratio micropillars and nanopillars are described. Use of alumina as an etch mask for the fabrication methods is also described. The resulting micropillars and nanopillars are analyzed and a characterization of the etch mask is provided.

Claims (22)

1. A method for fabricating high aspect ratio pillars comprising:

providing a substrate;

coating the substrate by a resist;

defining the high aspect ratio pillars by patterning and exposing the resist;

developing the resist to remove portions of the resist on the substrate, to expose portions of the substrate;

depositing an etch mask on the resist and the exposed portions of the substrate;

placing the resist in a chemical bath to dissolve the resist and the etch mask on the resist, such that the etch mask on the substrate remain undissolved;

etching sections of the substrate exposed as a consequence of dissolving the resist and the etch mask on the resist, the etching being performed with an SF 6 /O 2 cryogenic etch to fabricate high aspect ratio micropillars and a Pseudo Bosch etch to fabricate high aspect ratio nanopillars; and

removing a remainder of the etch mask to form the high aspect ratio pillars.

2. The method of claim 1 , wherein the substrate is a silicon substrate.

3. The method of claim 2 , wherein the etch mask is an alumina etch mask.

4. The method of claim 3 , wherein the alumina is sputtered on the substrate.

5. The method of claim 4 , wherein a 99.995% aluminum target is used to produce the etch mask and a 5:1 mixture of argon to oxygen is used as a process gas to sputter the alumina.

6. The method of claim 5 , wherein the alumina is sputtered using a 400 watts DC power.

7. The method of claim 3 , wherein the etching is a plasma etching.

8. The method of claim 3 , wherein a remainder of the alumina etch mask is removed using either buffered hydrofluoric acid or ammonium hydroxide mixed with hydrogen peroxide.

9. The method of claim 1 , wherein a 10 to 1 ratio of SF 6 to O 2 is employed for the SF 6 /O 2 cryogenic etch.

10. The method of claim 1 , wherein an ICP power of 900 W combined with a RIE power of 3 to 9 is employed to fabricate micropillars and an ICP power of 1200 W combined with a RIE power of 20 W is used to generate nanopillars.

11. The method of claim 1 , wherein the high aspect ratio pillars are micropillars of diameters ranging from 5 to 50 micron with aspect ratios greater than 25.

12. The method of claim 11 , wherein the micropillars are controllably placed at a distance of 5 micron or more from one another.

13. The method of claim 1 , wherein the high aspect ratio pillars are nanopillars of diameters ranging from 30 to 50 nm with aspect ratios greater than 25.

14. The method of claim 13 , wherein the nanopillars are controllably placed at a distance of 50 nm or more from one another.

Assignments (2)
CONFIRMATORY LICENSE Recorded Jun 22, 2010
From: CALIFORNIA INSTITUTE OF TECHNOLOGY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 024570/0950 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2010
From: HENRY, MICHAEL D.; HOMYK, ANDREW P.; SCHERER, AXEL; WALAVALKAR, SAMEER
To: CALIFORNIA INSTITUTE OF TECHNOLOGY
Reel/Frame 024383/0892 →
Continuity (4)
Provisional Application 61208528 · Feb 25, 2009
Provisional Application 61164289 · Mar 27, 2009
Provisional Application 61220980 · Jun 26, 2009
Related Publication 20100213579A1 · Aug 26, 2010