Method and apparatus for regenerating catalyst during oxygenates to olefins reaction
Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.
1. A method of regenerating a molecular sieve catalyst for converting oxygenates into olefins, comprising:
a) in a pretreatment stage, pretreating a molecular sieve catalyst under pretreatment conditions by heating the catalyst at a pretreatment temperature of between 300° C. to 700° C. in an oxygen depleted medium wherein in the pretreatment stage the catalyst is heated at a first pretreatment temperature for a first residence time of between 1 minute to 2 hours followed by increasing the temperature to a second pretreatment temperature and maintaining the second pretreatment temperature for a second residence time of between 1 minute to 2 hours, wherein the first pretreatment temperature is between 300° C. to 400° C. and the second pretreatment temperature is between 400° C. to 700° C., followed by cooling the catalyst to room temperature; and
b) in a regeneration stage, regenerating the cooled catalyst under regeneration conditions by heating the catalyst at a regeneration temperature of between 350° C. to 500° C. in an oxidizing medium for a regeneration residence time of between 1 minute to 2 hours.
2. The method of claim 1 , wherein the pretreatment temperature is increased from the first pretreatment temperature to the second pretreatment temperature at a rate of between 5° C. to 50° C. per minute.
3. The method of claim 1 , wherein the catalyst in the pretreatment stage is heated by combustion of coke on the catalyst.
4. The method of claim 1 , wherein the catalyst in the pretreatment stage is heated by mixing the catalyst in the first stage with catalyst from the regeneration stage.
5. The method of claim 1 , wherein the oxygen depleted medium comprises less than 30% of the stoichiometric amount of oxygen for completely removing coke from the catalyst.
6. The method of claim 1 , wherein the method further comprises the step of controlling the pretreatment and/or regeneration stage conditions to control the amount of coke on the catalyst to between 0.05 to 1.0 wt % of coke on catalyst.
7. The method of claim 1 , wherein the oxidizing medium comprises at least a stoichiometric amount of oxygen for completely removing coke from the catalyst.
8. The method of claim 1 , wherein the method further comprises the step of feeding gaseous pretreatment effluent from the pretreatment stage to the regeneration stage.
9. The method of claim 1 , wherein the catalyst comprises a silicoaluminophosphate molecular sieve.
10. A method for converting oxygenates into olefins by means of molecular sieve catalyst comprising:
a) in a reaction stage, reacting a molecular sieve catalyst with the oxygenates under reaction conditions, the reaction conditions comprising a reaction temperature from 320° C. to 700° C., a pressure of 5 kPaa to 1 MPaa and a weight hourly space velocity of at least 1 hr −1 ;
b) regenerating at least a portion of the catalyst from the reaction stage as defined in claim 1 ; and
c) returning the catalyst following regeneration to the reaction stage.
11. The method of claim 10 , wherein at least a portion of the catalyst is returned to the reaction stage following pretreatment in the pretreatment stage.
12. The method of claim 10 or 11 , comprising polymerizing said olefins in the presence of a polymerization catalyst to form polymers.