IP Library Granted Patent US 8,189,397
Granted Patent B2
US 8,189,397 · App. 12/318,767 · Granted May 29, 2012

Retention in NVM with top or bottom injection

Assignee: Spansion Israel Ltd
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Quick Facts
Patent No.
US 8,189,397
App. No.
12/318,767
Granted
May 29, 2012
Kind
B2
Abstract

Retention of charges in a nonvolatile memory (NVM) cell having a nitride-based injector (such as SiN, SIRN, SiON) for facilitating injection of holes into a charge-storage layer (for NROM, nitride) of a charge-storage stack (for NROM, ONO) may be improved by providing an insulating layer (for NROM, oxide) between the charge-storage layer and the injector has a thickness of at least 3 nm. Top and bottom injectors are disclosed. Methods of operating NVM cells are disclosed. The NVM cell may be NROM, SONOS, or other oxide-nitride technology NVM cells such as SANOS, MANOS, TANOS.

Claims (74)

1. A nonvolatile memory (NVM) cell comprising:

a charge-storage stack comprising a charge-storage layer; a channel and a gate, between which said stack is disposed, wherein said channel or said gate is a hole source; and

an injector disposed between said charge-storage stack and said hole source,

wherein said injector further includes a hole permissive layer and an insulator layer adjacent to said hole source, and wherein said hole permissive layer is composed of a material having a potential barrier for holes which is lower than that of an interface of said charge storage stack.

2. The NVM cell according to claim 1 , wherein said insulator layer adjacent to said hole source is composed of an oxide.

3. The NVM cell according to claim 1 , wherein said insulator layer is at least 3 NM thick.

4. The NVM cell of claim 1 , wherein said injector comprises a layer of material having a valence band energy which is higher than that of a top insulating layer of the charge-storage stack.

5. The NVM cell of claim 1 , wherein said charge storage layer is composed of charge trapping type material.

6. The NVM cell of claim 5 , wherein said charge trapping type material is silicon nitride.

7. The NVM cell of claim 6 , wherein said NVM cell is of a type selected from the group consisting of NROM, SONOS and TONOS.

8. The NVM cell of claim 1 , wherein said charge storage stack includes one or more insulating layers disposed between said charge storage layer and said gate or channel.

9. The NVM cell of claim 8 , wherein said insulating layer comprises oxide and said injector comprises a material selected from the group consisting of nitride (SiN), oxinitride (SiON), and silicon-rich nitride (SiRN).

10. The NVM cell of claim 9 , wherein said injector is disposed between said stack and said gate.

11. The NVM cell of claim 9 , wherein said injector is disposed between said stack and said channel.

12. The NVM cell of claim 1 , wherein said injector comprises a hole permissive layer comprised of gradated hole barrier material having increasing hole-barrier properties moving away from said hole source.

13. The NVM cell of claim 12 , wherein said gradated hole barrier material is comprised of at least two layers of dielectric materials arranged such that a potential barrier height peak for holes is near an interface between the injector and said charge-storage stack.

14. The NVM cell of claim 1 , wherein: said injector comprises at least one layer of a hole permissive material having a potential barrier for holes which is lower than that of an interface of the charge-storage stack; and said at least one layer of hole permissive material comprises: a first layer of material disposed next to said hole source and having a first potential barrier for holes which is lower than that of an insulating layer of said charge-storage stack; and a second layer of material disposed between the first layer of material and said insulating layer of the charge-storage stack and having a second potential barrier for holes which is lower than that of said insulating layer of the charge-storage stack and higher than that of said first layer of material.

15. The NVM cell of claim 14 , wherein: said first layer of material is selected from the group consisting of nitride (SiN) and silicon-rich nitride (SiRN); and said second layer of material comprises oxinitride (SiON).

16. A nonvolatile memory (NVM) cell comprising:

a charge-storage stack comprising a charge-storage layer; a channel and a gate, between which said stack is disposed, wherein said channel or said gate is a hole source; and

an injector disposed between said charge-storage stack and said hole source adjacent to said hole source,

wherein said injector further includes a hole permissive layer and an insulator layer, and wherein said injector comprises a layer of material having a valence band energy which is higher than that of a top insulating layer of the charge-storage stack.

17. The NVM cell according to claim 16 , wherein said hole permissive layer is composed of a material having a potential barrier for holes which is lower than that of an interface of said charge storage stack.

18. The NVM cell according to claim 16 , wherein said insulator layer adjacent to said hole source is composed of an oxide.

19. The NVM cell according to claim 16 , wherein said insulator layer is at least 3 NM thick.

20. The NVM cell of claim 16 , wherein said charge storage layer is composed of charge trapping type material.

21. The NVM cell of claim 20 , wherein said charge trapping type material is silicon nitride.

22. The NVM cell of claim 21 , wherein said NVM cell is of a type selected from the group consisting of NROM, SONOS and TONOS.

23. The NVM cell of claim 16 , wherein said charge storage stack includes one or more insulating layers disposed between said charge storage layer and said gate or channel.

24. The NVM cell of claim 23 , wherein said insulating layer comprises oxide and said injector comprises a material selected from the group consisting of nitride (SiN), oxinitride (SiON), and silicon-rich nitride (SiRN).

25. The NVM cell of claim 24 , wherein said injector is disposed between said stack and said gate.

26. The NVM cell of claim 24 , wherein said injector is disposed between said stack and said channel.

27. The NVM cell of claim 16 , wherein said injector comprises a hole permissive layer comprised of gradated hole barrier material having increasing hole-barrier properties moving away from said hole source.

28. The NVM cell of claim 27 , wherein said gradated hole barrier material is comprised of at least two layers of dielectric materials arranged such that a potential barrier height peak for holes is near an interface between the injector and said charge-storage stack.

29. The NVM cell of claim 16 , wherein: said injector comprises at least one layer of a hole permissive material having a potential barrier for holes which is lower than that of an interface of the charge-storage stack; and said at least one layer of hole permissive material comprises: a first layer of material disposed next to said hole source and having a first potential barrier for holes which is lower than that of an insulating layer of said charge-storage stack; and a second layer of material disposed between the first layer of material and said insulating layer of the charge-storage stack and having a second potential barrier for holes which is lower than that of said insulating layer of the charge-storage stack and higher than that of said first layer of material.

30. The NVM cell of claim 29 , wherein: said first layer of material is selected from the group consisting of nitride (SiN) and silicon-rich nitride (SiRN); and said second layer of material comprises oxinitride (SiON).

31. A nonvolatile memory (NVM) cell comprising:

a charge-storage stack comprising a charge-storage layer; a channel and a gate, between which said stack is disposed, wherein said channel or said gate is a hole source; and

an injector disposed between said charge-storage stack and said hole source,

wherein said injector further includes a hole permissive layer and an insulator layer adjacent to said hole source, and wherein said injector comprises a hole permissive layer comprised of gradated hole barrier material having increasing hole-barrier properties moving away from said hole source.

32. The NVM cell according to claim 31 , wherein said hole permissive layer is composed of a material having a potential barrier for holes which is lower than that of an interface of said charge storage stack.

33. The NVM cell according to claim 31 , wherein said insulator layer adjacent to said hole source is composed of an oxide.

34. The NVM cell according to claim 31 , wherein said insulator layer is at least 3 NM thick.

35. The NVM cell according to claim 31 , wherein said injector comprises a layer of material having a valence band energy which is higher than that of a top insulating layer of the charge-storage stack.

36. The NVM cell of claim 31 , wherein said charge storage layer is composed of charge trapping type material.

37. The NVM cell of claim 36 , wherein said charge trapping type material is silicon nitride.

38. The NVM cell of claim 37 , wherein said NVM cell is of a type selected from the group consisting of NROM, SONOS and TONOS.

39. The NVM cell of claim 31 , wherein said charge storage stack includes one or more insulating layers disposed between said charge storage layer and said gate or channel.

40. The NVM cell of claim 39 , wherein said insulating layer comprises oxide and said injector comprises a material selected from the group consisting of nitride (SiN), oxinitride (SiON), and silicon-rich nitride (SiRN).

41. The NVM cell of claim 40 , wherein said injector is disposed between said stack and said gate.

42. The NVM cell of claim 40 , wherein said injector is disposed between said stack and said channel.

43. The NVM cell of claim 31 , wherein said gradated hole barrier material is comprised of at least two layers of dielectric materials arranged such that a potential barrier height peak for holes is near an interface between the injector and said charge-storage stack.

44. The NVM cell of claim 31 , wherein: said injector comprises at least one layer of a hole permissive material having a potential barrier for holes which is lower than that of an interface of the charge-storage stack; and said at least one layer of hole permissive material comprises: a first layer of material disposed next to said hole source and having a first potential barrier for holes which is lower than that of an insulating layer of said charge-storage stack; and a second layer of material disposed between the first layer of material and said insulating layer of the charge-storage stack and having a second potential barrier for holes which is lower than that of said insulating layer of the charge-storage stack and higher than that of said first layer of material.

45. The NVM cell of claim 44 , wherein: said first layer of material is selected from the group consisting of nitride (SiN) and silicon-rich nitride (SiRN); and said second layer of material comprises oxinitride (SiON).

46. A nonvolatile memory (NVM) cell comprising:

a charge-storage stack comprising a charge-storage layer; a channel and a gate, between which said stack is disposed, wherein said channel or said gate is a hole source; and

an injector disposed between said charge-storage stack and said hole source, wherein said injector further includes a hole permissive layer and an insulator layer adjacent to said hole source, and

wherein said injector comprises at least one layer of a hole permissive material having a potential barrier for holes which is lower than that of an interface of the charge-storage stack; and said at least one layer of hole permissive material comprises:

a first layer of material disposed next to said hole source and having a first potential barrier for holes which is lower than that of an insulating layer of said charge-storage stack; and

a second layer of material disposed between the first layer of material and said insulating layer of the charge-storage stack and having a second potential barrier for holes which is lower than that of said insulating layer of the charge-storage stack and higher than that of said first layer of material.

47. The NVM cell according to claim 46 , wherein said hole permissive layer is composed of a material having a potential barrier for holes which is lower than that of an interface of said charge storage stack.

48. The NVM cell according to claim 46 , wherein said insulator layer adjacent to said hole source is composed of an oxide.

49. The NVM cell according to claim 46 , wherein said insulator layer is at least 3 NM thick.

50. The NVM cell according to claim 46 , wherein said injector comprises a layer of material having a valence band energy which is higher than that of a top insulating layer of the charge-storage stack.

51. The NVM cell of claim 46 , wherein said charge storage layer is composed of charge trapping type material.

52. The NVM cell of claim 51 , wherein said charge trapping type material is silicon nitride.

53. The NVM cell of claim 52 , wherein said NVM cell is of a type selected from the group consisting of NROM, SONOS and TONOS.

54. The NVM cell of claim 46 , wherein said charge storage stack includes one or more insulating layers disposed between said charge storage layer and said gate or channel.

55. The NVM cell of claim 54 , wherein said insulating layer comprises oxide and said injector comprises a material selected from the group consisting of nitride (SiN), oxinitride (SiON), and silicon-rich nitride (SiRN).

56. The NVM cell of claim 55 , wherein said injector is disposed between said stack and said gate.

57. The NVM cell of claim 55 , wherein said injector is disposed between said stack and said channel.

58. The NVM cell of claim 46 , wherein said injector comprises a hole permissive layer comprised of gradated hole barrier material having increasing hole-barrier properties moving away from said hole source.

59. The NVM cell of claim 58 , wherein said gradated hole barrier material is comprised of at least two layers of dielectric materials arranged such that a potential barrier height peak for holes is near an interface between the injector and said charge-storage stack.

60. The NVM cell of claim 46 , wherein: said first layer of material is selected from the group consisting of nitride (SiN) and silicon-rich nitride (SiRN); and said second layer of material comprises oxinitride (SiON).

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Mar 16, 2022
From: MUFG UNION BANK, N.A.
To: CYPRESS SEMICONDUCTOR CORPORATION; SPANSION LLC
Reel/Frame 059410/0438 →
CORRECTIVE ASSIGNMENT TO CORRECT THE FOLLOWING NUMBERS 6272046,7277824,7282374,7286384,7299106,7337032,7460920,7519447 PREVIOUSLY RECORDED ON REEL 039676 FRAME 0237. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST. Recorded Oct 16, 2018
From: CYPRESS SEMICONDUCTOR CORPORATION
To: MORGAN STANLEY SENIOR FUNDING
Reel/Frame 047797/0854 →
SECURITY INTEREST Recorded Aug 15, 2016
From: CYPRESS SEMICONDUCTOR CORPORATION
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039676/0237 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT COLLATERAL Recorded Dec 30, 2014
From: BARCLAYS BANK PLC
To: SPANSION LLC; SPANSION INC.; SPANSION TECHNOLOGY INC.; SPANSION TECHNOLOGY LLC
Reel/Frame 034715/0305 →
CHANGE OF NAME Recorded Dec 26, 2011
From: SAIFUN SEMICONDUCTORS LTD.
To: SPANSION ISRAEL LTD
Reel/Frame 027444/0160 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 19, 2009
From: EITAN, BOAZ; KUSHNIR, MARIA; SHAPPIR, ASSAF
To: SAIFUN SEMICONDUCTORS LTD.
Reel/Frame 022278/0949 →
Continuity (2)
Provisional Application 61006354 · Jan 8, 2008
Related Publication 20090175089A1 · Jul 9, 2009