All-solid-state cell
View Patent ↗A first paste for a first electrode layer and a second paste for a second electrode layer are printed on a fired solid electrolyte by screen printing, etc. to form electrode patterns for forming the first electrode layer and the second electrode layer. The first and second pastes can be prepared by dissolving a binder in an organic solvent, adding an appropriate amount of the obtained solution to powders of an electrode active substance material and a solid electrolyte material, and kneading the resultant mixture. The first and second pastes are applied to the fired solid electrolyte to form a cell precursor, the cell precursor is placed in a hot press mold subjected to a thermal treatment while pressing from above by a punch, whereby the first and second electrode layer are formed from the first and second pastes.
1. An all-solid-state cell comprising positive and negative electrode portions containing an electrode active substance, an electrolyte portion containing a solid electrolyte, and positive and negative collector portions, wherein
one or both of the positive and negative electrode portions are formed by firing a mixture of the electrode active substance and the solid electrolyte under an applied pressure of at least 500 kg/cm 2 .
2. An all-solid-state cell according to claim 1 , wherein the solid electrolyte comprises an amorphous polyanion material.
3. An all-solid-state cell according to claim 1 , wherein the solid electrolyte comprises an amorphous phosphate material.
4. An all-solid-state cell according to claim 1 , wherein the solid electrolyte is made of a material of Nasicon class of materials after the firing.
5. An all-solid-state cell according to claim 1 , wherein both the solid electrolyte and the electrode active substance are made of materials of Nasicon class of materials after the firing.
6. An all-solid-state cell according to claim 1 , wherein both the solid electrolyte and the electrode active substance are made of materials of Nasicon class of materials after the firing, the solid electrolyte comprises LAGP Li 1+x Al x Ge 2-x (PO 4 ) 3 , wherein x is greater than or equal to 0 and less than or equal to 1, the electrode active substance comprises LVP Li m V 2 (PO 4 ) 3 , wherein m is greater than or equal to 1 and less than or equal to 5, in both the positive and negative electrode portions, and the all-solid-state cell has a symmetrical structure.
7. An all-solid-state cell according to claim 6 , wherein the process of firing the mixture is started under an oxygen-containing atmosphere.
8. An all-solid-state cell according to claim 6 , wherein the process of firing the mixture is carried out under a firing atmosphere with variable oxygen density.
9. An all-solid-state cell according to claim 1 , wherein the solid electrolyte comprises an amorphous polyanion material.
10. An all-solid-state cell according to claim 1 , wherein the solid electrolyte comprises an amorphous phosphate material.
11. An all-solid-state cell according to claim 1 , wherein the mixture is formed into a printing paste.
12. An all-solid-state cell comprising positive and negative electrode portions containing an electrode active substance, an electrolyte portion containing a solid electrolyte, and positive and negative collector portions, wherein
one or both of the positive and negative electrode portions are formed by firing a mixture of the solid electrolyte and the electrode active substance under an applied pressure of at least 500 kg/cm 2 , and
the solid electrolyte and the electrode active substance satisfy the inequality:
Ty>Tz
wherein Ty is a temperature at which the capacity of the electrode active substance is lowered by a reaction between a solid electrolyte material and an electrode active substance material, and Tz is a temperature at which the solid electrolyte material is shrunk by firing.
13. An all-solid-state cell according to claim 12 , wherein Tz is a temperature at which the relative density of the solid electrolyte material is increased to 70% or more of the theoretical density thereof due to the shrinkage by firing.
14. An all-solid-state cell according to claim 12 , wherein the solid electrolyte comprises an amorphous polyanion material.
15. An all-solid-state cell according to claim 12 , wherein the solid electrolyte comprises an amorphous phosphate material.
16. An all-solid-state cell according to claim 12 , wherein the solid electrolyte is made of a material of Nasicon class of materials after the firing.
17. An all-solid-state cell according to claim 12 , wherein both the solid electrolyte and the electrode active substance are made of materials of Nasicon class of materials after the firing.
18. An all-solid-state cell according to claim 12 , wherein both the solid electrolyte and the electrode active substance are made of materials of Nasicon class of materials after the firing, the solid electrolyte comprises LAGP Li 1+x Al x Ge 2-x (PO 4 ) 3 , wherein x is greater than or equal to 0 and less than or equal to 1, the electrode active substance comprises LVP Li m V 2 (PO 4 ) 3 , wherein m is greater than or equal to 1 and less than or equal to 5, in both the positive and negative electrode portions, and the all-solid-state cell has a symmetrical structure.
19. An all-solid-state cell according to claim 18 , wherein the process of firing the mixture is started under an oxygen-containing atmosphere.
20. An all-solid-state cell according to claim 18 , wherein the process of firing the mixture is carried out under a firing atmosphere with variable oxygen density.
21. An all-solid-state cell according to claim 12 , wherein the solid electrolyte comprises an amorphous polyanion material.
22. An all-solid-state cell according to claim 12 , wherein the solid electrolyte comprises an amorphous phosphate material.
23. An all-solid-state cell according to claim 12 , wherein one or both of the positive and negative electrode portions are formed by firing a printing paste containing the mixture.
24. An all-solid-state cell according to claim 1 , wherein each of the electrode portions is formed by firing said mixture under an applied pressure of at least 500 kg/cm 2 and at a temperature of at least 600° C.
25. An all-solid-state cell according to claim 1 , wherein a charge transfer resistance at the interface between said electrode active substance and said electrolyte is less than or equal to 1000 Ω.
26. An all-solid-state cell according to claim 12 , wherein each of the electrode portions is formed by firing said mixture under an applied pressure of at least 500 kg/cm 2 and at a temperature of at least 600° C.
27. An all-solid-state cell according to claim 12 , wherein a charge transfer resistance at the interface between said electrode active substance and said electrolyte is less than or equal to 1000 Ω.