Packaging material for flat electrochemical cell
View Patent ↗In a packaging material for electrochemical cell, a thermally adhesive resin layer is configured of a resin having a propylene based elastomer resin in a propylene based resin. This propylene based elastomer resin is a copolymer composed of a constitutional unit derived from propylene and a constitutional unit derived from an α-olefin having from 2 to 20 carbon atoms; when the total sum of the constitutional unit derived from propylene and the constitutional unit derived from an α-olefin is defined as 100% by mole, contains 50% by mole or more of the constitutional unit derived from propylene; and is satisfied with (a) a Shore A hardness (ASTM D2240) of from 65 to 90, (b) a melting point of from 130 to 170° C., (c) a density (ASTM D1505) of from 860 to 875 kg/m 3 and (d) a glass transition temperature as measured by DSC of from −25° C. to −35° C.
1. A packaging material for a flat electrochemical cell comprising at least a base material layer, a metal foil layer having a chemical conversion treated layer on at least one surface thereof, an acid-modified polyolefin layer and a thermally adhesive resin layer laminated in this order, wherein
the acid-modified polyolefin layer is a resin layer constituted of an acid-modified polyolefin based resin, the thermally adhesive resin layer has a resin layer constituted of a propylene based resin,
a propylene based elastomer resin is mixed in at least one of the acid-modified polyolefin based resin and the propylene based resin,
the propylene based elastomer resin has a network structure in which islands constituting a crystal area are communication with each other, thereby covering a whole of an amorphous area; and
the propylene based elastomer resin is a copolymer composed of a constitutional unit derived from propylene and a constitutional unit derived from an α-olefin having from 2 to 20 carbon atoms except propylene; when the total sum of the constitutional unit derived from propylene and the constitutional unit derived from an α-olefin is defined as 100% by mole, contains 50% by mole or more of the constitutional unit derived from propylene; and is satisfied with the following physical properties:
(a) a Shore A hardness (ASTM D2240) is in the range of from 65 to 90,
(b) a melting point is in the range of from 130° C. to 170° C.,
(c) a density (ASTM D1505) is in the range of from 860 to 875 kg/m 3 , and
(d) a glass transition temperature as measured by DSC is in the range of from −25° C. to −35° C.
2. The packaging material for a flat electrochemical cell according to claim 1 , wherein the propylene based elastomer resin is mixed in an amount of 3% by weight or more and not more than 30% by weight relative to the propylene based resin.
3. The packaging material for a flat electrochemical cell according to claim 1 , wherein the metal foil layer is an aluminum foil having a thickness of 80 μm or more and not more than 120 μm.
4. The packaging material for a flat electrochemical cell according to claim 2 , wherein the metal foil layer is an aluminum foil having a thickness of 80 μm or more and not more than 120 μm.
5. The packaging material for a flat electrochemical cell according to claim 1 , wherein the propylene based elastomer resin has a melting point in the range of from 130° C. to 150° C.
6. The packaging material for a flat electrochemical cell according to claim 1 , wherein the propylene based elastomer resin has a density in the range of 860 kg/cm 3 to 872 kg/cm 3 .
7. The packaging material for a flat electrochemical cell according to claim 1 , wherein the propylene based elastomer resin satisfies at least one of
(e) a haze (internal haze) of less than 15%, and
(f) a melt flow rate (MFR as measured at 230° C. under a load of 2.16 kg in conformity with ASTM D1238) in the range of 3 to 15 g/10 min.
8. The packaging material for a flat electrochemical cell according to claim 1 , wherein in (e) the haze is less than 10%, and in (f) the melt flow rate is in the range of 5 to 10 g/10 min.