Skin-covered propylene resin foamed molded article
The present invention pertains to a skin-covered foamed molded article of expanded propylene resin beads having excellent lightness in weight, mechanical properties and appearance. The present invention provides a skin-covered foamed molded article of propylene resin expanded beads, with the skin covering substantially the entire surface of the molded article of the expanded beads. The skin, within which the molded article of expanded propylene resin beads is placed, is a propylene resin hollow molded body obtained by blow molding. A base resin of which the skin is formed comprises a propylene resin having a partial heat of fusion in a temperature range between 80 and 140° C. of at least 15 J/g and a ratio of the partial heat of fusion to a total heat of fusion (partial heat of fusion/total heat of fusion) of at least 0.2 as measured by heat flux differential scanning calorimetry. The skin has a thickness in the range of 0.3 to 3.5 mm, and the molded article of expanded propylene resin beads has an apparent density in the range of 0.015 to 0.15 g/cm 3 . The skin is fuse-bonded to the molded article of expanded beads, and the expanded beads from which the molded article is formed are fuse-bonded to each other.
1. A skin-covered propylene resin foamed molded article consisting of a propylene resin skin layer of a propylene resin hollow molded body obtained by blow molding, and
a molded article of expanded propylene resin beads placed within the skin layer,
wherein a base resin of which the skin layer is formed comprises:
a mixed resin composed of propylene resin obtained by polymerization using a metallocene polymerization catalyst and another propylene resin having a melt tension in the range of 2 to 30 cN at 230° C.,
the base resin having a partial heat of fusion in a temperature range between 80° C. and 140° C. of 15 to 70 J/g, a ratio of the partial heat of fusion to a total heat of fusion of 0.25 to 0.7, and an endothermic peak whose peak temperature being present in a temperature range of 115° C. to 140° C. as measured by heat flux differential scanning calorimetry, and a melt tension in the range of 2 to 30 cN 230° C.,
the skin layer has a thickness in the range of 0.3 to 2.0 mm,
the molded article of expanded propylene resin beads has an apparent density in the range of 0.015 to 0.15 g/cm 3 ,
the skin layer is fuse-bonded to the molded article of expanded propylene resin beads, and wherein the expanded beads from which the molded article is formed are fuse-bonded to each other.
2. The skin-covered propylene resin foamed molded article according to claim 1 , wherein the base resin has a melt flow rate of 0.1 to 5 g/10 minutes.
3. The skin-covered propylene resin foamed molded article according to claim 1 , wherein the base resin has a ratio of the partial heat of fusion to a total heat of fusion of 0.4 to 0.7.
4. A skin-covered propylene resin foamed molded article consisting of a propylene resin skin layer of a propylene resin hollow molded body obtained by blow molding, and a molded article of expanded propylene resin beads placed within the skin layer,
wherein a base resin of which the skin layer is formed comprises a propylene resin obtained by polymerization using a metallocene polymerization catalyst, having a partial heat of fusion in a temperature range between 80° C. and 140° C. of 15 to 70 J/g, a ratio of the partial heat of fusion to a total heat of fusion of 0.4 to 0.92, and an endothermic peak whose peak temperature being present in a temperature range of 115° C. to 140° C. as measured by heat flux differential scanning calorimetry, and a melt tension in the range of 1 to 30 cN at 230° C.,
the skin layer has a thickness in the range of 0.3 to 2.0 mm,
the molded article of expanded propylene resin beads has an apparent density in the range of 0.015 to 0.15 g/cm 3 ,
the skin layer is fuse-bonded to the molded article of expanded propylene resin beads, and wherein the expanded beads from which the molded article is formed are fuse-bonded to each other.
5. The skin-covered propylene resin foamed molded article according to claim 2 , wherein the base resin of which the skin layer is formed comprises a propylene resin having a melt tension in the range of 2 to 30 cN at 230° C.
6. The skin-covered propylene resin foamed molded article according to claim 4 , wherein the base resin of which the skin layer is formed comprises a propylene resin obtained by polymerization using a metallocene polymerization catalyst, having a partial heat of fusion in a temperature range between 80° C. and 140° C. of 30 to 70 J/g.
7. The skin-covered propylene resin foamed molded article according to claim 4 , wherein the base resin has a melt flow rate of 0.1 to 5 g/10 minutes.
8. The skin-covered propylene resin foamed molded article according to claim 4 , wherein the base resin has a ratio of the partial heat of fusion to a total heat of fusion of 0.4 to 0.7.