Method for manufacturing group III nitride semiconductor layer, method for manufacturing group III nitride semiconductor light-emitting device, and group III nitride semiconductor light-emitting device, and lamp
A method for manufacturing a Group III nitride semiconductor layer according to the present invention includes a sputtering step of disposing a substrate and a target containing a Group III element in a chamber, introducing a gas for formation of a plasma in the chamber and forming a Group III nitride semiconductor layer added with Si as a dopant on the substrate by a reactive sputtering method, wherein a Si hydride is added in the gas for formation of a plasma.
1. A method for manufacturing a Group III nitride semiconductor light-emitting device, which comprises:
a step of forming an n-type semiconductor layer by a method for manufacturing a Group III nitride semiconductor layer; and
a lamination step of sequentially laminating a laminated semiconductor layer comprising the n-type semiconductor layer, a light-emitting layer and a p-type semiconductor layer on a substrate, wherein
the method for manufacturing a Group III nitride semiconductor layer comprises:
a sputtering step of disposing a substrate and a target containing a Group III element in a chamber, introducing a gas for formation of a plasma in the chamber, and
forming a Group III nitride semiconductor layer in which Si has been added as a dopant, on the substrate by a reactive sputtering method, wherein
a Si hydride is added in the gas for formation of a plasma; and
the sputtering step comprises:
a first plasma generation step of adding the Si hydride in a gas for formation of a first plasma, which contains no nitrogen element, introducing the gas in the chamber and sputtering the target, thereby generating a first plasma containing sputtering particles comprised of at least a Group III element, and
a second plasma generation step of introducing a gas for formation of a second plasma, which contains at least a nitrogen element, in the chamber and generating a second plasma containing at least the nitrogen element, wherein
the Group III nitride semiconductor layer is formed by performing the first plasma generation step and the second plasma generation step repeatedly and alternately.