Blended fluoropolymer coatings for rigid substrates
A fluoropolymer coating composition that may be applied over a primer and/or at least one midcoat in a non-stick coating system. The coating composition may be prepared and applied in the form of a liquid dispersion, and includes at least one fluoropolymer base component, such as polytetrafluoroethylene (PTFE) and, in particular, at least one high molecular weight PTFE (HPTFE). The coating composition additionally includes a blended fluoropolymer composition. The blended fluoropolymer composition is a blend of at least one low molecular weight PTFE (LPTFE) and at least one melt-processible fluoropolymer. After application directly to a substrate or over an underlying coating, the coating demonstrates improved abrasion and scratch resistance, as well as improved release characteristics, as compared to known coatings that include only HPTFE or HPTFE with a small amount of melt processible fluoropolymer.
1. A fluoropolymer coating composition, comprising:
a fluoropolymer base component present in an amount of between 30 wt. % and 96 wt. % based on the total solids weight of all fluoropolymers in said coating composition, said fluoropolymer base component comprising at least one fluoropolymer including high molecular weight polytetrafluoroethylene (HPTFE) having a number average molecular weight (M n ) of at least 500,000; and
a blended fluoropolymer composition present in an amount of between 4 wt. % and 70 wt. % based on the total solids weight of all fluoropolymers in said coating composition, said blended fluoropolymer composition comprising:
at least one low molecular weight polytetrafluoroethylene (LPTFE) having a first melt temperature (T m ) of 335° C. or less; and
at least one melt-processible fluoropolymer (MPF).
2. The coating composition of claim 1 , wherein said fluoropolymer base component is present in an amount of between 60 wt. % and 96 wt. % and said blended fluoropolymer composition is present in an amount of between 4 wt. % and 40 wt. % based on the total solids weight of all fluoropolymers in said coating composition.
3. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 2 wt. % and 15 wt. % and said at least one melt-processible fluoropolymer (MPF) is present in an amount of between 2 wt. % and 15 wt. % based on the total solids weight of all fluoropolymers in said coating composition.
4. The coating composition of claim 1 , wherein said at least one melt-processible fluoropolymer comprises perfluoroalkoxy (PFA) present in an amount between 20 wt. % and 85 wt. %, based on the total solids weight of said fluoropolymers in said blended fluoropolymer composition.
5. The coating composition of claim 4 , wherein said at least one melt-processible fluoropolymer comprises perfluoroalkoxy (PFA) present in an amount between 37 wt. % and 65 wt. %, based on the total solids weight of said fluoropolymers in said blended fluoropolymer composition.
6. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.9 microns (μm) or less.
7. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 330° C. or less.
8. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is obtained via emulsion polymerization and without being subjected to agglomeration, thermal degradation, or irradiation, and has a mean particle size of 1.0 microns (μm) or less.
9. The coating composition of claim 1 , wherein at least one melt-processible fluoropolymer (MPF) has a mean particle size of 1.0 microns (μm) or less.
10. The coating composition of claim 2 , wherein said fluoropolymer base component is present in an amount of between 75 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 25 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
11. The coating composition of claim 10 , wherein said fluoropolymer base component is present in an amount of between 85 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 15 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
12. The coating composition of claim 11 , wherein said fluoropolymer base component is present in an amount of between 90 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 10 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
13. The coating composition of claim 1 , wherein said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said fluoropolymer base component is present in an amount of between 75 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 25 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
14. The coating composition of claim 13 , wherein said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said fluoropolymer base component is present in an amount of between 85 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 15 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
15. The coating composition of claim 14 , wherein said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said fluoropolymer base component is present in an amount of between 90 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 10 wt.% based on the total solids weight of all fluoropolymers in said coating composition.
16. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 40 wt.% and 60 wt.% and said at least one melt-processible fluoropolymer (MPF) is present in an amount of between 40 wt.% and 60 wt.% based on the total solids weight of said at least one LPTFE and said at least one MPF.
17. The coating composition of claim 16 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 45 wt.% and 55 wt.% and said at least one melt-processible fluoropolymer (MPF) is present in an amount of between 45 wt.% and 55 wt.% based on the total solids weight of said at least one LPTFE and said at least one MPF.
18. The coating composition of claim 1 , wherein said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 40 wt.% and 60 wt.% and said PFA is present in an amount of between 40 wt.% and 60 wt.% based on the total solids weight of said at least one LPTFE and said PFA.
19. The coating composition of claim 18 , wherein said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 45 wt.% and 55 wt.% and said PFA is present in an amount of between 45 wt.% and 55 wt.% based on the total solids weight of said at least one LPTFE and said PFA.
20. The coating composition of claim 1 , wherein said at least one melt-processible fluoropolymer comprises perfluoroalkoxy (PFA) present in an amount between 43 wt.% and 63 wt.%, based on the total solids weight of said fluoropolymers in said blended fluoropolymer composition.
21. The coating composition of claim 20 , wherein said at least one melt-processible fluoropolymer comprises perfluoroalkoxy (PFA) present in an amount between 50 wt.% and 60 wt.%, based on the total solids weight of said fluoropolymers in said blended fluoropolymer composition.
22. The coating composition of claim 6 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.75 microns (μm) or less.
23. The coating composition of claim 22 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.5 microns (μm) or less.
24. The coating composition of claim 23 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.2 microns (μm) or less.
25. The coating composition of claim 7 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 329°C. or less.
26. The coating composition of claim 25 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 327°C. or less.
27. The coating composition of claim 26 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 325°C. or less.
28. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is an LPTFE micropowder obtained via emulsion polymerization with or without a subsequent molecular weight reduction step.
29. The coating composition of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is an LPTFE micropowder obtained via suspension polymerization with or without a subsequent molecular weight reduction step.
30. The coating composition of claim 1 , wherein said at least one high molecular weight polytetrafluoroethylene (HPTFE) includes a modifying co-monomer in an amount less than 1 wt.% based on the weight of said high molecular weight polytetrafluoroethylene (HPTFE).
31. The coating composition of claim 30 , wherein said modifying co-monomer is a perfluoroalkylvinyl ether.
32. The coating composition of claim 30 , wherein said modifying co-monomer is perfluoromethylvinyl ether (PMVE).
33. The coating composition of claim 30 , wherein said modifying co-monomer is perfluoroethylvinyl ether (PEVE).
34. The coating composition of claim 30 , wherein said modifying co-monomer is perfluoropropylvinyl ether (PPVE).
35. The coating composition of claim 1 , wherein said coating composition is in the form of an aqueous dispersion.
36. The coating composition of claim 1 , wherein:
said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said fluoropolymer base component is present in an amount of between 85 wt.% and 95 wt.% and said blended fluoropolymer composition is present in an amount of between 5 wt.% and 15 wt.% based on the total solids weight of all fluoropolymers in said coating composition;
said at least one high molecular weight polytetrafluoroethylene (HPTFE) includes a modifying co-monomer in an amount less than 1 wt.% based on the weight of said high molecular weight polytetrafluoroethylene (HPTFE); and
said at least one low molecular weight polytetrafluoroethylene (LPTFE) is obtained via emulsion polymerization and without being subjected to agglomeration, thermal degradation, or irradiation, and has a mean particle size of 1.0 microns (μm) or less.
37. The coating composition of claim 36 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 329°C. or less.
38. The coating composition of claim 36 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.5 microns (μm) or less.
39. The coating composition of claim 1 , wherein:
said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 45 wt.% and 55 wt.% and said PFA is present in an amount of between 45 wt.% and 55 wt.% based on the total solids weight of said at least one LPTFE and said PFA;
said at least one high molecular weight polytetrafluoroethylene (HPTFE) includes a modifying co-monomer in an amount less than 1 wt.% based on the weight of said high molecular weight polytetrafluoroethylene (HPTFE); and
said at least one low molecular weight polytetrafluoroethylene (LPTFE) is obtained via emulsion polymerization and without being subjected to agglomeration, thermal degradation, or irradiation, and has a mean particle size of 1.0 microns (μm) or less.
40. The coating composition of claim 39 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a first melt temperature (T m ) of 329°C. or less.
41. The coating composition of claim 39 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) has a mean particle size of 0.5 microns (μm) or less.
42. The coating composition of claim 36 , wherein said coating composition is in the form of an aqueous dispersion.
43. The coating composition of claim 36 , wherein said modifying co-monomer is perfluoropropylvinyl ether (PPVE).
44. The coating composition of claim 39 , wherein said coating composition is in the form of an aqueous dispersion.
45. The coating composition of claim 39 , wherein said modifying co-monomer is perfluoropropylvinyl ether (PPVE).