Cup-type polypropylene container and method of molding the same
A cup-type polypropylene container obtained by compression-molding a polypropylene and having at least a body portion and a bottom portion, wherein the body portion has a thickness of not larger than 1.0 mm and a value K 1 relating to peak intensity ratio and/or a value K 2 relating to diffraction intensity ratio as defined herein. The cup-type polypropylene container features improved falling strength in the body portion and at the open end such as flange, improved pressure strength and excellent mechanical strength in the body portion. Also disclosed is a method of molding the cup-type polypropylene container.
1. A cup-type polypropylene container obtained by compression-molding a polypropylene and having at least a body portion and a bottom portion, wherein the body portion has a thickness of not larger than 1.0 mm and a value K 1 in the body portion represented by the following formula,
K 1 =P 1 /P 2
wherein P 1 and P 2 are, respectively, a peak intensity at a diffraction angle 2 θ=14.5° and a peak intensity at a diffraction angle 2 θ=17.2° in the peak intensity distribution in the x-direction of a Debye ring obtained by measuring the diffraction intensity while defining the circumferential direction of a test piece cut out from the body portion of the container to be x, the direction of height thereof to be y, and by causing x-ray to fall perpendicularly to the xy-plane of the test piece,
lying in a range of 0.5 to 1.0 and a value K 2 represented by the following formula,
K 2 =Hβ 1 /( Hβ 1 +Hα 1 +Hα 2 +Hα 3 )
wherein Hβ 1 , Hα 1 , Hα 2 and Hα 3 are values obtained by subtracting the diffraction intensity of an amorphous portion from a peak intensity at a diffraction angle 2 θ=16.3° , and from a peak intensity at a diffraction angle 2 θ=14.5° , and from a peak intensity at a diffraction angle of 17.2° and from a peak intensity at a diffraction angle of 18.8° in the peak intensity distribution in the x-direction of a Debye ring obtained by measuring the diffraction intensity while defining the circumferential direction of a test piece cut out from the body portion of the container to be x, the direction of height thereof to be y, and by causing x-ray to fall perpendicularly to the xy-plane of the test piece,
which is larger than 0 in at least part of the body portion.
2. The cup-type polypropylene container according to claim 1 , wherein a flange portion is formed, the flange portion having a value K 1 of 0.5 to 1.5.
3. The cup-type polypropylene container according to claim 1 , wherein at least the bottom portion and the body portion of the container have a multi-layer structure.
4. The cup-type polypropylene container according to claim 3 , wherein the multi-layer structure includes at least inner and outer layers of the polypropylene and an intermediate layer of other thermoplastic resin, the inner and outer layers completely covering the intermediate layer preventing the intermediate layer from being exposed to the surface of the container.
5. The cup-type polypropylene container according to claim 4 , wherein the intermediate layer comprises an ethylene/vinyl alcohol copolymer having an ethylene copolymerization ratio of less than 32 mol %.
6. A method of molding a cup-type polypropylene container by at least introducing a molten resin mass of a polypropylene into a lower metal mold and compressing the molten resin mass by an upper metal mold and the lower metal mold, wherein a portion that becomes an open end or a part thereof is defined by the metal mold after the molten resin mass is introduced into the lower metal mold but before the upper metal mold or the lower metal mold is moved, and the compression molding is effected at the time of moving the upper metal mold or the lower metal mold while varying the thickness of the portions that form the bottom portion and the body portion of the container.
7. The method according to claim 6 , wherein the molten resin mass is the one having a multi-layer structure extruded by a die head having a multi-layer structure.
8. The method according to claim 6 , wherein the cup-type polypropylene container is one obtained by compression-molding a polypropylene and having at least a body portion and a bottom portion, wherein the body portion has a thickness of not larger than 1.0 mm and a value K 1 in the body portion represented by the following formula,
K 1 =P 1 /P 2
wherein P 1 and P 2 are, respectively, a peak intensity at a diffraction angle 2 θ=14.5° and a peak intensity at a diffraction angle 2 θ=17.2° in the peak intensity distribution in the x-direction of a Debye ring obtained by measuring the diffraction intensity while defining the circumferential direction of a test piece cut out from the body portion of the container to be x, the direction of height thereof to be y, and by causing x-ray to fall perpendicularly to the xy-plane of the test piece,
lying in a range of 0.5 to 1.0 and a value K 2 represented by the following formula,
K 2 =Hβ 1 /(Hβ 1 +Hα l +Hα 2 Hα 3 )
wherein Hβ 1 , Hα 1 , Hα 2 and Hα 3 are values obtained by subtracting the diffraction intensity of an amorphous portion from a peak intensity at a diffraction angle 2 θ=16.3° , and from a peak intensity at a diffraction angle 2 θ=14.5° , and from a peak intensity at a diffraction angle of 17.2° and from a peak intensity at a diffraction angle of 18.8° in the peak intensity distribution in the x-direction of a Debye ring obtained by measuring the diffraction intensity while defining the circumferential direction of a test piece cut out from the body portion of the container to be x, the direction of height thereof to be y, and by causing x-ray to fall perpendicularly to the xy-plane of the test piece,
which is larger than 0 in at least part of the body portion.