Addition reaction-curable silicone pressure-sensitive adhesive composition and pressure-sensitive adhesive tape
Provided is an addition reaction-curable silicone pressure-sensitive adhesive composition, including: (A) a specific diorganopolysiloxane consisting of (A1) a linear diorganopolysiloxane having two or more alkenyl groups, and (A2) a linear diorganopolysiloxane having SiOH groups at the terminals and containing no alkenyl groups, (B) a specific organopolysiloxane containing M units, Q units and SiOH group-containing siloxane units, (C) an organohydrogenpolysiloxane containing three or more SiH groups, (D) an addition reaction retarder, (E) a platinum group metal-based catalyst, and (F) a specific organopolysiloxane containing T units and D units. A cured product layer formed from a cured product of this composition can be peeled from a release film with minimal peeling force, and exhibits excellent adhesion to silicone rubbers. The composition is ideal for use within a pressure-sensitive adhesive tape including a substrate and an aforementioned cured product layer laminated to at least one surface of the substrate.
1. An addition reaction-curable silicone pressure-sensitive adhesive composition, comprising:
(A) a diorganopolysiloxane consisting of:
(A1) a linear diorganopolysiloxane having two or more alkenyl groups within each molecule, and
(A2) a linear diorganopolysiloxane having SiOH groups at terminals and containing no alkenyl groups, wherein
a mass ratio of (A1)/(A2) is within a range from 100/0 to 10/90,
in an amount of 20 to 80 parts by mass,
(B) an organopolysiloxane comprising R 3 3 SiO 0.5 units, SiO 2 units, and siloxane units having a hydroxyl group bonded to a silicon atom, wherein
R 3 represents a monovalent hydrocarbon group of 1 to 10 carbon atoms,
a molar ratio of R 3 3 SiO 0.5 units/SiO 2 units is within a range from 0.5 to 0.9, and
a hydroxyl group content is within a range from 0.1 to 5.0% by mass,
in an amount of 80 to 20 parts by mass (provided that a combined total of component (A) and component (B) is 100 parts by mass),
(C) an organohydrogenpolysiloxane comprising three or more SiH groups within each molecule, in an amount such that a molar ratio of SiH groups within component (C) relative to alkenyl groups within the composition is within a range from 0.5 to 20,
(D) an addition reaction retarder, in an amount within a range from 0 to 8.0 parts by mass per 100 parts by mass of a combination of component (A) and component (B),
(E) a platinum group metal-based catalyst, in an amount sufficient to provide a mass of the platinum group metal equivalent to 1 to 5,000 ppm relative to a combined mass of component (A) and component (B), and
(F) an organopolysiloxane comprising R 3 1 SiO 1.5 units and R 3 2 SiO 1 units, wherein R 3 is as defined above, and a molar ratio of R 3 1 SiO 1.5 units/R 3 2 SiO 1 units is within a range from 100/0 to 30/70,
in an amount within a range from 1 to 30 parts by mass per 100 parts by mass of a combination of component (A) and component (B).
2. The composition according to claim 1 , wherein the mass ratio of (A1)/(A2) within component (A) is within a range from 90/10 to 10/90.
3. The composition according to claim 1 , wherein
the component (A1) is a linear diorganopolysiloxane represented by formula (1-1) shown below:
X a R 1 3-a SiO—[XR 1 SiO] b —[R 1 2 SiO] c —SiX a R 1 3-a (1-1)
wherein R 1 represents identical or different monovalent hydrocarbon groups of 1 to 10 carbon atoms that contain no aliphatic unsaturated bonds, X represents identical or different alkenyl groups of 2 to 10 carbon atoms, a represents 0, 1 or 3, b represents an integer of 0 or greater, and c represents an integer of 0 or greater, provided that 2a+b≧2 and 500≦b+c≦20,000,
a linear diorganopolysiloxane represented by formula (1-2) shown below:
(HO)R 1 2 (HO)R 1 2 SiO—[XR 1 SiO] b+2 —[R 1 2 SiO] c —Si(OH)R 1 2 (1-2)
wherein R 1 , X, b and c are as defined above, or
a combination thereof.
4. The composition according to claim 1 , wherein
the component (A2) is a linear diorganopolysiloxane represented by formula (2) shown below:
R 2 2 (HO)SiO-(R 2 2 SiO) d —SiR 2 2 (OH) (2)
wherein R 2 represents identical or different monovalent hydrocarbon groups of 1 to 10 carbon atoms that contain no aliphatic unsaturated bonds, and d represents an integer that satisfies 500≦d≦20,000.
5. The composition according to claim 1 , wherein
the component (C) is an organohydrogenpolysiloxane represented by formula (3) shown below:
H e R 4 3-e SiO—[HR 4 SiO] f —[R 4 2 SiO] g SiH e R 4 3-e (3)
wherein R 4 represents identical or different monovalent hydrocarbon groups of 1 to 10 carbon atoms that contain no aliphatic unsaturated bonds, e represents 0 or 1, f represents an integer of 1 or greater, and g represents an integer of 0 or greater, provided that 2e+f≧3 and 1≦f+g≦1,000.
6. The composition according to claim 1 , wherein a molecular weight of component (F) is not less than 2,000.
7. The composition according to claim 1 , wherein the molar ratio of R 3 1 SiO 1.5 units/R 3 2 SiO 1 units within component (F), wherein R 3 is as defined above, is within a range from 100/0 to 50/50.
8. A pressure-sensitive adhesive tape, comprising a substrate, and a cured product layer consisting of a cured product of the composition defined in claim 1 laminated to at least one surface of the substrate.
9. The pressure-sensitive adhesive tape according to claim 8 , further comprising a release film consisting of a substrate at least one surface of which is coated with a silicone-based release agent containing a fluorine-containing substituent, wherein the release film is laminated to the cured product layer so that a surface of the release film that is coated with the release agent contacts the cured product layer.