Method for obtaining a surface of titanium-based metal implant to be inserted into bone tissue
View Patent ↗The invention relates to a method for obtaining a surface of a titanium-based metal implant intended to be inserted into bone tissue, comprising: (a) projecting particles of aluminum oxide under pressure on the external area of the implant; (b) chemically treating the sandblasted external area of the implant with an acid composition comprising sulfuric acid and hydrofluoric acid; and (c) thermally treating the sandblasted external area of the implant by heating at a temperature of 200-450° C. for 15-120 min. The invention likewise defines a metal implant having said surface. The surface thus obtained has good micrometer-scale roughness with a suitable morphology, as well as a composition which is virtually free of impurities and a thickness which is approximately three times the thickness of conventional surfaces, which characteristics provide it with very good osseointegration properties.
1. A method for obtaining a treated surface of a titanium-based metal implant intended to be inserted into bone tissue, comprising:
(a) projecting particles of aluminium oxide under pressure on an external area of the implant to form a sandblasted external area;
(b) cleaning the sandblasted external area with a pressurized air, to provide a cleaned sandblasted external area;
(c) chemically treating the cleaned sandblasted external area of the implant with an acid composition comprising sulfuric acid and hydrofluoric acid to form a sandblasted and chemically treated external area; and
(d) thermally treating the sandblasted and chemically treated external area of the implant by heating at a temperature of 200-450° C. for 15-120 minutes to form a titanium oxide surface coating layer;
wherein the acid treatment step, step (c) results in additional pitting of the cleaned, sandblasted external area.
2. The method according to claim 1 , wherein the projection of the particles of aluminium oxide on the external area of step (a) is performed at a pressure of 1-6 atm.
3. The method according to claim 2 , wherein the projection of the particles of aluminium oxide on the external area of step (a) is performed at a pressure of 3 atm.
4. The method according to claim 1 , wherein the particles of aluminium oxide used in step (a) have a particle size of 10-100 μm.
5. The method according to claim 4 , wherein the particles of aluminium oxide used in step (a) have a particle size of 25 μm.
6. The method according to claim 1 , wherein the acid composition used in step (c) comprises 15-50% (v/v) sulfuric acid and 0.01-1% (v/v) hydrofluoric acid.
7. The method according to claim 6 , wherein the acid composition used in step (c) comprises 28.8% (v/v) sulfuric acid and 0.024% (v/v) hydrofluoric acid.
8. The method according to claim 1 , wherein the chemical treatment of step (c) is performed at a temperature of 50-110° C. for 4-60 minutes.
9. The method according to claim 8 , wherein the chemical treatment of step (c) is performed at a temperature of 75° C. for 12 minutes.
10. The method according to claim 1 , wherein the thermal treatment of step (d) is performed at a temperature of 285° C. for 60 minutes.