Methods of making metal oxide nanostructures and methods of controlling morphology of same
View Patent ↗The present invention includes a method of producing a crystalline metal oxide nanostructure. The method comprises providing a metal salt solution and providing a basic solution; placing a porous membrane between the metal salt solution and the basic solution, wherein metal cations of the metal salt solution and hydroxide ions of the basic solution react, thereby producing a crystalline metal oxide nanostructure.
1. A method of producing a crystalline metal oxide nanostructure, the method comprising:
providing a metal salt solution and providing a basic solution;
placing a porous membrane between the metal salt solution and the basic solution, wherein metal cations of the metal salt solution and hydroxide ions of the basic solution react to form metal hydroxides; and
dehydrating the metal hydroxides at about 80 to 700° C., thereby producing a crystalline metal oxide nanostructure;
wherein the crystalline metal oxide nanostructure has the formula M x O y , wherein x is 1, 2, 3, 4 or 5, and y is 1, 2, 3, 4, 7 or 8.
2. A method of claim 1 wherein the metal salt in the metal salt solution is selected from the group consisting of zinc salt, copper salt, iron salt, cobalt salt, nickel salt, magnesium salt, manganese salt, scandium salt, thallium salt, tin salt, aluminum salt, cadmium salt, and chromium salt.
3. A method of claim 1 wherein the metal salt in the metal salt solution is selected from the group consisting of yttrium salt, zirconium salt, vanadium salt, ruthenium salt, tungsten salt, bismuth salt, barium salt, calcium salt, strontium salt, osmium salt, gallium salt, germanium salt, antimony salt, niobium salt, rhenium salt and lead salt.
4. The method of claim 1 wherein the metal oxide nanostructure is single crystalline.
5. The method of claim 1 wherein the metal oxide nanostructure is polycrystalline.
6. The method of claim 1 wherein metal cations and hydroxide ions predominantly nucleate to form metal hydroxides within the confines of the pores of the porous membrane.
7. The method of claim 1 wherein the metal cations and hydroxide ions predominantly nucleate at the walls of the pores of the porous membrane.
8. The method of claim 1 wherein the basic solution has a pH of greater than or equal to 13, the membrane is a polycarbonate membrane, and zinc oxide nanowires are produced.
9. The method of claim 1 wherein the basic solution has a pH of greater than or equal to 13, the membrane is a polycarbonate membrane, and copper oxide nanowires are produced.
10. The method of claim 1 wherein the basic solution has a pH of greater than or equal to 13, the membrane is an alumina membrane, and hematite nanotubes are produced.
11. The method of claim 1 wherein the method further comprises controlling the dimensions and morphology of the nanostructures to form nanowires and/or nanorods, wherein the porous membrane is a homogeneous type membrane; wherein as the pH of the basic solution increases, the length of the nanowires and/or nanorods increases;
wherein as the temperature of the reaction increases, the length of the nanowires and/or nanorods increases.
12. The method of claim 1 , wherein M is selected from the group consisting of Zn, Cu, Fe, Co, Ni, Mg, Mn, Sc, Tl, Sn, Al, Cd and Cr; and wherein the nanostructure is a nanotube, a nanowire or nanorod.
13. The method of claim 12 wherein x is 1 or 2, and y is 1 or 3.
14. The method of claim 1 wherein the crystalline metal oxide nanostructure is a nanoarray comprising a plurality of one-dimensional nanostructures, and wherein M is selected from the group consisting of Zn, Cu, Fe, Co, Ni, Mg, Mn, Sc, Tl, Sn, Al, Cd and Cr.
15. The method of claim 14 , wherein x is 1 or 2, and y is 1 or 3.
16. The method of claim 14 , wherein the nanoarray is at least 50% monodisperse.