IP Library Granted Patent US 8,338,552
Granted Patent B2
US 8,338,552 · App. 12/947,598 · Granted Dec 25, 2012

Co-polymer films for sensors

Assignee: California Institute of Technology
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Quick Facts
Patent No.
US 8,338,552
App. No.
12/947,598
Granted
Dec 25, 2012
Kind
B2
Abstract

Embodiments include a sensor comprising a co-polymer, the co-polymer comprising a first monomer and a second monomer. For some embodiments, the first monomer is poly-4-vinyl pyridine, and the second monomer is poly-4-vinyl pyridinium propylamine chloride. For some embodiments, the first monomer is polystyrene and the second monomer is poly-2-vinyl pyridinium propylamine chloride. For some embodiments, the first monomer is poly-4-vinyl pyridine, and the second monomer is poly-4-vinyl pyridinium benzylamine chloride. Other embodiments are described and claimed.

Claims (23)

1. An SO 2 gas sensor comprising an SO 2 sorbing co-polymer, the co-polymer comprising:

a first monomer selected from monomers belonging to the polystyrene family; and

a second monomer selected from the group consisting of monomers belonging to the pyridinium alkyl amine halide family and monomers belonging to the aryl pyridinium alkyl amine halide family.

2. The gas sensor as set forth in claim 1 , further comprising:

a substrate, wherein the co-polymer is formed on the substrate as a film.

3. An SO 2 gas sensor comprising an SO 2 sorbing co-polymer, the co-polymer comprising:

a first monomer selected from the group consisting of monomers belonging to the pyridine family and monomers belonging to the polystyrene family; and

a second monomer selected from the group consisting of monomers belonging to the pyridinium alkyl amine halide family and monomers belonging to the aryl pyridinium alkyl amine halide family;

the first monomer comprising poly-4-vinyl pyridine, and the second monomer comprising poly-4-vinyl pyridinium propylamine chloride.

4. The gas sensor as set forth in claim 3 , wherein the first monomer is at a relative molar concentration in a range of 0.2 to 0.8, and the second monomer is at a relative molar concentration in the range of 0.2 to 0.8.

5. The gas sensor as set forth in claim 3 , wherein the co-polymer is such that there is one part of the first monomer to four parts of the second monomer, or one part of the first monomer to one part of the second monomer.

6. An SO 2 gas sensor comprising an SO 2 sorbing co-polymer, the co-polymer comprising:

a first monomer selected from the group consisting of monomers belonging to the pyridine family and monomers belonging to the polystyrene family; and

a second monomer selected from the group consisting of monomers belonging to the pyridinium alkyl amine halide family and monomers belonging to the aryl pyridinium alkyl amine halide family;

the first monomer comprising polystyrene, and the second monomer comprising poly-2-vinyl pyridinium propylamine chloride.

7. The gas sensor as set forth in claim 6 , wherein the first monomer is at a relative molar concentration in a range of 0.2 to 0.8, and the second monomer is at a relative molar concentration in the range of 0.2 to 0.8.

8. The gas sensor as set forth in claim 6 , wherein the co-polymer is such that the first and second monomers are at relative molar concentrations of 0.3 and 0.7, respectively.

9. An SO 2 gas sensor comprising an SO 2 sorbing co-polymer, the co-polymer comprising:

a first monomer selected from the group consisting of monomers belonging to the pyridine family and monomers belonging to the polystyrene family; and

a second monomer selected from the group consisting of monomers belonging to the pyridinium alkyl amine halide family and monomers belonging to the aryl pyridinium alkyl amine halide family;

the first monomer comprising poly-4-vinyl pyridine, and the second monomer comprising poly-4-vinyl pyridinium benzylamine chloride.

10. The gas sensor as set forth in claim 9 , wherein the first monomer is at a relative molar concentration in a range of 0.2 to 0.8, and the second monomer is at a relative molar concentration in the range of 0.2 to 0.8.

11. The gas sensor as set forth in claim 9 , wherein the co-polymer is such that there is one part of the first monomer to one part of the second monomer.

Assignments (2)
CONFIRMATORY LICENSE Recorded Feb 17, 2011
From: CALIFORNIA INSTITUTE OF TECHNOLOGY
To: NASA
Reel/Frame 025815/0867 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 14, 2010
From: RYAN, MARGARET A; KISOR, ADAM; HOMER, MARGIE L; YEN, SHIAO-PIN S; SHEVADE, ABHIJIT V; JEWELL, APRIL D; MANATT, KENNETH S; TAYLOR, CHARLES; BLANCO, MARIO; GODDARD, WILLIAM A
To: CALIFORNIA INSTITUTE OF TECHNOLOGY
Reel/Frame 025493/0001 →
Continuity (3)
Division 11820472 · Jun 19, 2007
Provisional Application 60814730 · Jun 19, 2006
Related Publication 20110060114A1 · Mar 10, 2011