Method of preparing positive active material with low carbon content for rechargeable lithium battery

1. A method of preparing a positive active material, comprising:

heating a hydroxide compound that includes nickel and cobalt, or nickel, cobalt, and at least one metal selected from the group consisting of Al, Cr, Fe, Mg, Sr, V, and rare earth elements, or nickel, cobalt, and manganese, or nickel, cobalt, manganese, and at least one metal selected from the group consisting of Al, Cr, Fe, Mg, Sr, V, and rare earth elements to obtain an oxide material;

mixing the oxide material with a lithium-containing compound;

performing a first heat treatment to the resulting mixture; and

performing a second heat treatment to the first heat-treated mixture to obtain a lithium/nickel-based compound,

wherein primary particles of the positive active material have an average particle diameter ranging from 1 μm to 4 μm are agglomerated to form secondary particles of the lithium/nickel-based compound and,

wherein the heat treatment of the hydroxide compound is performed at 700 to 1000° C.

2. The method of claim 1 ,

wherein the average diameter of the secondary particles is between 5 μm to 20 μm.

3. The method of claim 1 , wherein the first heat treatment is performed at 500 to 1000° C.

4. The method of claim 1 ,

wherein the second heat treatment is performed at 700 to 1000° C.

5. The method of claim 1 ,

wherein the amount of carbon on the surface of the positive active material prior to fabrication of a positive electrode is less than 0.1 wt % of the total weight of the positive active material.

6. The method of claim 5 ,

wherein the amount of the carbon is between 0.05 wt % to 0.07 wt % of the total weight of the positive active material.

7. The method of claim 6 ,

wherein the amount of the carbon is between 0.05 wt % to 0.06 wt % of the total weight of the positive active material.

8. The method of claim 1 ,

wherein the lithium/nickel-based compound has an X-ray diffraction intensity ratio I(003)/I(104) in an X-ray diffraction pattern using CuKα ranging from 1.04 to 1.15, and a full width at half maximum ranging from 0.14 to 0.16.

9. The method of claim 1 ,

wherein the positive active material is represented by at least one of the following formulas (1) to (4):

Li x Ni 1−y Co y O 2−z A z   (1)

Li x Ni 1−y−z Co y M z A 2   (2)

Li x Ni 1−y−z Co y Mn z O 2−α A α   (3)

Li x Ni 1−y−z Co y Mn z O 2−α A α   (4)

wherein x, y, z, w, and a are given by 0.94≦x≦1.1, 0≦y≦0.5, 0≦z≦0.5, 0≦w≦0.5, 0≦α≦2,

wherein M is at least one element selected from the group consisting of Al, Cr, Fe, Mg, Sr, V, and rare earth elements,

wherein A is at least one element selected from the group consisting of O, F, S, and P.