Supported iridium catalysts

1. A method of converting at least one first alkane to a mixture of at least one lower molecular weight alkane and at least one higher molecular weight alkane, comprising:

reacting a first alkane in the presence of a dual catalyst system comprising: (i) a hydrogen transfer catalyst and (ii) a metathesis catalyst to produce said mixture of at least one low molecular weight alkane and at least one high molecular weight alkane, said reacting step carried out in the presence of a hydrogen acceptor, and wherein the molar ratio of said hydrogen acceptor to said hydrogen transfer catalyst is not greater than 10:1;

wherein said hydrogen transfer catalyst is an iridium pincer complex catalyst;

wherein said metathesis catalyst is selected from the group consisting of Schrock catalysts, molybdenum catalysts, tungsten oxide catalysts, rhenium oxide catalysts, and mixtures thereof;

wherein said reacting with a hydrogen transfer catalyst is carried out at a temperature of 120to 250° C.;

and wherein said reacting with a metathesis catalyst is carried out at a temperature of 30 to 100° C.

2. The method of claim 1 , wherein both said hydrogen transfer catalyst and said metathesis catalyst are heterogeneous catalysts.

3. The method of claim 1 , wherein said at least one higher molecular weight alkane is produced at a ratio of linear alkanes to branched alkanes of at least 500:1.

4. The method of claim 1 , wherein said hydrogen transfer catalyst is immobilized on a solid support, wherein said reaction is carried out in a solvent, and wherein said method further comprises the step of separating free hydrogen transfer catalyst from said solvent.

5. The method of claim 1 , wherein said at least one first alkane is linear.

6. The method of claim 1 , wherein said at least one first alkane is produced by: converting synthesis gas to said at least one first alkane by Fischer-Tropsch catalysis.

7. The method of claim 1 , further comprising the step of:

providing at least a portion of said high molecular weight alkane to a liquid hydrocarbon fuel synthesis process to produce liquid hydrocarbon fuel.

8. The method of claim 1 , further comprising the step of:

providing at least a portion of said high molecular weight alkane to a gasoline synthesis process to produce gasoline.

9. The method of claim 1 , further comprising the step of:

providing at least a portion of said high molecular weight alkane to a diesel fuel synthesis process to produce diesel fuel.

10. In a method of making a liquid hydrocarbon fuel from a synthesis gas by the Fischer Tropsch reaction, wherein said fuel comprises at least one high molecular weigh alkane, and wherein at least a portion of the product of said Fischer Tropsch reaction comprises at least one low molecular weight alkane, the improvement comprising:

converting at least a portion of said low molecular weight alkane to said high molecular weight alkane by reacting said low molecular weight alkane in the presence of a dual catalyst system comprising: (i) a hydrogen transfer catalyst and (ii) a metathesis catalyst to produce said high molecular weight alkane, said reacting carried out in the presence of a hydrogen acceptor, and wherein the molar ratio of said hydrogen acceptor to said hydrogen transfer catalyst is not greater than 10:1;

wherein said hydrogen transfer catalyst is an iridium pincer complex catalyst;

wherein said metathesis catalyst is selected from the group consisting of Schrock catalysts, molybdenum catalysts, tungsten oxide catalysts, rhenium oxide catalysts, and mixtures thereof;

wherein said reacting with a hydrogen transfer catalyst is carried out at a temperature of 120 to 250° C.;

and wherein said reacting with a metathesis catalyst is carried out at a temperature of 30 to 100° C.

11. The method of claim 10 , wherein said both said hydrogen transfer catalyst and said metathesis catalyst are heterogeneous catalysts.

12. The method of claim 10 , wherein said at least one higher molecular weight alkane is produced at a ratio of linear alkanes to branched alkanes of at least 500:1,

13. The method of claim 10 , wherein said hydrogen transfer catalyst is immobilized on a solid support, wherein said reaction is carried out in a solvent, and wherein said method further comprises the step of separating free hydrogen transfer catalyst from said solvent.

14. The method of claim 10 , wherein said fuel is diesel fuel or gasoline.

15. The method of claim 10 , wherein:

said at least one low molecular weight alkane is a compound of the formula C n H 2n+2 where n is 3-10, and

said at least one high molecular weight alkane is a compound of the formula C m H 2m+2 ,

where m is an integer of from 4 to 40.

16. In a method of making a liquid hydrocarbon fuel from a synthesis gas by the Fischer-Tropsch reaction, wherein said fuel comprises at least one high molecular weigh alkane, wherein at least a portion of the product of said Fischer Tropsch reaction comprises a wax, and wherein said wax is of still higher molecular weight than said high molecular weight alkane, the improvement comprising:

converting at least a portion of said wax to said at least one high molecular weight alkane by reacting said wax in the presence of a dual catalyst system comprising: (i) a hydrogen transfer catalyst and (ii) a metathesis catalyst to produce said at least one higher molecular weight alkane;

wherein said reacting is carried out in the presence of a hydrogen acceptor, and wherein the molar ratio of said hydrogen acceptor to said hydrogen transfer catalyst is not greater than 10:1;

wherein said hydrogen transfer catalyst is an iridium pincer complex catalyst;

wherein said metathesis catalyst is selected from the group consisting of Schrock catalysts, molybdenum catalysts, tungsten oxide catalysts, rhenium oxide catalysts, and mixtures thereof;

wherein said reacting with a hydrogen transfer catalyst is carried out at a temperature of 120 to 250° C.;

and wherein said reacting with a metathesis catalyst is carried out at a temperature of 30 to 100° C.

17. The method of claim 16 , wherein said both said hydrogen transfer catalyst and said metathesis catalyst are heterogeneous catalysts.

18. The method of claim 16 , wherein said at least one higher molecular weight alkane is produced at a ratio of linear alkanes to branched alkanes of at least 500:1.

19. The method of claim 16 , wherein said fuel is diesel fuel or gasoline.

20. The method of claim 16 , wherein:

said at least one higher molecular weight alkane is a compound of the formula C m H 2m+2 , where m is an integer of from 4 to 40;

said wax comprises a compound of the formula C p H 2p+2 where p is 18 to 200.

21. The method of claim 1 , wherein said reacting step is carried out at atmospheric pressure at a temperature not greater than 200° C.

22. The method of claim 1 , wherein said hydrogen transfer catalyst is a homogeneous catalyst;

wherein said alkane is provided as a mixed composition comprising both alkanes and alkenes, with the weight ratio of alkanes to alkenes being at least 50:1;

and wherein the at least one higher molecular weigh alkane produced by the reaction comprises a mixture of linear alkanes to branched alkanes at a molar ratio of at least 1000:1.

23. The method of claim 10 , wherein said reacting step is carried out at atmospheric pressure at a temperature not greater than 200° C.

24. The method of claim 10 , wherein said hydrogen transfer catalyst is a homogeneous catalyst;

wherein said alkane is provided as a mixed composition comprising both alkanes and alkenes, with the weight ratio of alkanes to alkenes being at least 50:1;

and wherein the at least one higher molecular weigh alkane produced by the reaction comprises a mixture of linear alkanes to branched alkanes at a molar ratio of at least 1000:1.

25. The method of claim 16 , wherein said reacting step is carried out at atmospheric pressure at a temperature not greater than 200° C.

26. The method of claim 16 , wherein said hydrogen transfer catalyst is a homogeneous catalyst;

wherein said alkane is provided as a mixed composition comprising both alkanes and alkenes, with the weight ratio of alkanes to alkenes being at least 50:1;

and wherein the at least one higher molecular weigh alkane produced by the reaction comprises a mixture of linear alkanes to branched alkanes at a molar ratio of at least 1000:1.