IP Library Granted Patent US 8,377,521
Granted Patent B2
US 8,377,521 · App. 11/478,167 · Granted Feb 19, 2013

Ink jet recording material

Inventors: Gerhard Stork (Flensburg, DE); Karsten Lerius (Munkbrarup, DE)
Assignee: Mitsubishi HiTec Paper Flensburgh GmbH
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Quick Facts
Patent No.
US 8,377,521
App. No.
11/478,167
Granted
Feb 19, 2013
Kind
B2
Abstract

An ink-jet recording paper with a paper substrate that has a coating on at least one side, wherein the coating contains binder and inorganic pigment, and wherein: (a) the substrate has a density in the range of 0.6 to 1.0 g/cm 3 and a Cobb 60 value in the range of 19-25 g/m 2 ; (b) the coating consists solely of a single layer formed as a recording layer, which is applied directly to the substrate; (c) the pigment present in the recording layer consists of colloidal synthetic boehmite with a mean crystal size in the range of 10-50 nm; and (d) the binder present in the recording material consists of silanized polyvinyl alcohol to the extent of 80-100 wt. %.

Claims (24)

1. Ink-jet recording material with a paper substrate that has a single coating on at least one side, wherein the coating contains binder and inorganic pigment, wherein:

(a) the substrate has a density in a range of 0.6 to 1.0 g/cm 3 and a Cobb 60 value in a range of 19-25 g/m 2 ;

(b) said single coating consists solely of a single layer formed as a recording layer, which is applied directly to the substrate;

(c) the pigment present in the recording layer consists of colloidal synthetic boehmite with a mean crystal size in a range of 10-50 nm; and

(d) the binder present in the recording layer consists of silanized polyvinyl alcohol to an extent of 80-100 wt. %.

2. Ink jet recording material in accordance with claim 1 , wherein pulp stock used to produce the paper has a Schopper Riegler (SR) freeness of 25-30°.

3. Ink jet recording material in accordance with claim 2 , wherein the pulp stock consists of eucalyptus pulp to an extent of 75-100 wt. % (absolutely dry).

4. Ink-jet recording material in accordance with claim 1 , wherein the pulp stock consists of eucalyptus pulp.

5. Ink jet recording material in accordance with claim 1 , wherein a coating is applied to both sides of the substrate, with the coating on each side containing binder and inorganic pigment, and:

(a) each of the two coatings consists of only a single layer formed as a recording layer, which is applied directly to the substrate;

(b) the pigment present in each of the two recording layers consists of colloidal synthetic boehmite with a mean crystal size in the range of 10-50 nm; and

(c) the binder present in each of the two recording layers consists of a silanized polyvinyl alcohol to the extent of 80-100 wt. %.

6. Ink jet recording material in accordance with claim 1 , wherein the recording layer applied directly to one or both sides of the substrate has a mass per unit area of 7-12 g/m 2 and contains the boehmite in an amount of 6 to 8.5 g/m 2 .

7. Ink-jet recording material in accordance with claim 1 , wherein the boehmite has a mean crystal size in the range of 18-22 nm.

8. Ink jet recording material in accordance with claim 7 , wherein the boehmite has a mean pore radius of 85-110 Å or 8.5 to 11 nm.

9. Ink-jet recording material in accordance with claim 7 , wherein the boehmite has a mean specific surface in a range of 135-165 m 2 /g.

10. Ink-jet recording material in accordance with claim 1 , wherein the boehmite has a mean crystal size in the range of 34-43 nm.

11. Ink-jet recording material in accordance with claim 10 , wherein the boehmite has a mean pore radius of 180-220 Å or 18-22 nm.

12. Ink-jet recording material in accordance with claim 10 , wherein the boehmite has a mean specific surface in a range of 85-115 m 2 /g.

13. Ink-jet recording material in accordance with claim 1 , wherein the silanized polyvinyl alcohol is present in the recording layer applied directly to one or both sides of the substrate in an amount of 0.6 to 0.85 g/m 2 .

14. Ink-jet recording material in accordance with claim 1 , wherein the recording layer applied directly to one or both sides of the substrate contains an antioxidant.

15. Ink-jet recording material in accordance with claim 14 , wherein the antioxidant is hexamethylenebis(dimethylcarbazide).

16. Ink-jet recording material in accordance with claim 1 , wherein the recording layer applied directly to one or both sides of the substrate has a Bekk smoothness of 60-150 sec.

17. Ink-jet recording material in accordance with claim 1 , wherein the recording layer applied directly to one or both sides of the substrate has a glossiness in a range of 10-40%, as measured by TAPPI 450 or ISO 2813 at an angle of reflection of 75°.

Assignments (2)
CHANGE OF NAME Recorded Nov 1, 2018
From: MITSUBISHI HITEC PAPER FLENSBURG GMBH
To: MITSUBISHI HITEC PAPER EUROPE GMBH
Reel/Frame 047887/0983 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 29, 2006
From: STORK, GERHARD; LERIUS, KARSTEN
To: MITSUBISHI HITEC PAPER FLENSBURGH GMBH
Reel/Frame 018066/0586 →
Priority Claims (1)
EP 05014012 · Jun 29, 2005 · regional
Continuity (1)
Related Publication 20070002120A1 · Jan 4, 2007