Lithium-ion battery using phosphorated composite
A lithium-ion battery includes an anode, a cathode, and an electrolyte. The anode includes a phosphorated composite including a conductive matrix and a red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%.
1. A lithium-ion battery comprising:
an anode, a cathode, and an electrolyte;
wherein the anode comprises a phosphorated composite comprising:
a conductive matrix, the conductive matrix comprises a material being selected from the group consisting of conductive polymer and conductive carbonaceous material, and a weight percentage of the conductive matrix in the phosphorated composite ranging from about 10% to about 85%; and
a red phosphorus, and a weight percentage of the red phosphorus in the phosphorated composite ranging from about 15% to about 90%.
2. The lithium-ion battery of claim 1 , wherein the conductive polymer is conjugated conductive polymer.
3. The lithium-ion battery of claim 2 , wherein the conjugated conductive polymer is a production of a reaction of a polymer under catalysis of the red phosphorus; and the reaction is dehydration, de-amine, dehydrogenation or dehydrohalogenation.
4. The lithium-ion battery of claim 3 , wherein the polymer is selected from the group consisting of polypropylene, polyacrylonitrile, polystyrene, polyethylene oxide, polyvinyl alcohol, polyvinylidenechloride, polyvinylidene fluoride, polyvinyl fluoride, polyvinyl chloride, poly1,2-chloride ethylene, poly1,2-fluoride ethylene, polymethyl methacrylate, and phenolic resin.
5. The lithium-ion battery of claim 1 , wherein the conductive carbonaceous material is selected from the group consisting of active carbon, acetylene black, conductive graphite, and conductive amorphous carbon.
6. The lithium-ion battery of claim 5 , wherein the conductive amorphous carbon is made by dehydrogenation of sugar or cellulose.
7. The lithium-ion battery of claim 1 , wherein the conductive matrix is a pyrolytic polyacrylonitrile with a weight percentage of about 45%, and the weight percentage of the red phosphorus is about 55%.
8. The lithium-ion battery of claim 1 , wherein the conductive matrix is a pyrolytic polyvinylidene chloride with a weight percentage of about 60%, and the weight percentage of the red phosphorus is about 40%.
9. The lithium-ion battery of claim 1 , wherein the conductive matrix is an active carbon with a weight percentage of about 70%, and the weight percentage of the red phosphorus is about 30%.
10. The lithium-ion battery of claim 1 , wherein the conductive matrix is a conductive graphite with a weight percentage of about 85%, and the weight percentage of the red phosphorus is about 15%.