Method of manufacturing via electrode
Provided is a method of manufacturing a via electrode by which productivity and production yield can be augmented or maximized. The method of the present invention includes: forming a via hole at a substrate; forming a catalyst layer at a sidewall and a bottom of the via hole; and forming a graphene layer in the via hole by exposing the catalyst layer to a solution mixed with graphene particles.
1. A method of manufacturing a via electrode, comprising:
forming a via hole in a substrate;
forming a catalyst layer over a sidewall and a bottom of the via hole; and
forming a graphene layer in the via hole by exposing the catalyst layer to a solution mixed with graphene particles.
2. The method of claim 1 , wherein the formation of the graphene layer comprises:
immersing the substrate in a solvent; and
forming the graphene layer on the catalyst layer by supplying the solution into the solvent.
3. The method of claim 2 , further comprising removing an air bubble in the via hole by making external pressure of the solvent lower than atmospheric pressure after the substrate is immersed in the solvent.
4. The method of claim 2 , wherein the graphene particles comprise at least one of graphene flakes, graphene powder, magnetic graphene nanoparticles, and graphene-coated metal particles.
5. The method of claim 4 , wherein the formation of the graphene layer comprises applying a magnetic field to a lower portion of the substrate.
6. The method of claim 2 , wherein the solvent comprises deionized water, alcohol, or iodic acid.
7. The method of claim 2 , where the formation of the graphene layer further comprises:
removing the graphene layer evenly so that an upper surface of the substrate is exposed after the substrate is discharged out of the solvent; and
hardening the graphene layer through a heat treatment process.
8. The method of claim 7 , further comprising forming a wiring layer on the graphene layer.
9. The method of claim 1 , further comprising forming an insulation film between the catalyst layer and the via hole.
10. A via electrode, comprising:
a semiconductor substrate;
a via hole provided in the semiconductor substrate;
a catalyst layer disposed over a bottom and a sidewall of the via hole; and
a graphene layer disposed on the catalyst layer,
wherein an upper surface of the graphene layer is lower than an upper surface of the semiconductor substrate.
11. The via electrode of claim 10 , further comprising an insulation film disposed between the catalyst layer and the bottom and the sidewall of the via hole.
12. The via electrode of claim 10 , further comprising a wiring layer disposed over the graphene layer.
13. The via electrode of claim 10 , wherein the graphene layer comprises at least one of graphene flakes, graphene powder, magnetic graphene nanoparticles, and graphene-coated metal particles.
14. A via electrode, comprising:
a semiconductor substrate;
a via hole provided in the semiconductor substrate;
an insulation layer coated over a bottom surface and sidewalls of the via hole;
a catalyst layer coated over the bottom surface and the sidewalls of the via hole and disposed over the insulation layer;
a graphene layer filling in a portion of the via hole and disposed over the catalyst layer; and
a wiring layer disposed in an upper portion of the via hole and over the graphene layer,
wherein an upper surface of the graphene layer is lower than an upper surface of the semiconductor substrate.