Flame retardant composition
View Patent ↗The invention relates to a flame retardant composition, particularly designed for fire fighting with aerial means. The retardant composition comprises a liquid ammonium polyphosphate of chain length with a value of n between 2 and 3, n being the number of condensation groups, and an ammonium polyphosphate in powder form in suspension, with a chain length with a value of n between 100 and 1500. In addition to the above, the flame retardant composition comprises corrosion inhibitors, in particular zinc orthophosphate dihydrate, and at least one surfactant agent as wetting agent or dispensing agent, an organic or inorganic thickening agent and at least one coloring agent.
1. A flame retardant composition for aerial fire fighting, comprising a liquid ammonium polyphosphate and ammonium polyphosphate in powder form in suspension; wherein:
the liquid ammonium polyphosphate has a chain length with a value of n, where n is 1 to 5, n being the number of condensation groups;
the ammonium polyphosphate in powder form has a chain length with a value of n, where n is 900 to 1500, n being the number of condensation groups;
the composition comprises at least one metal salt of the orthophosphoric acid as a corrosion inhibitor for alloys of aluminium, steel, bronze and magnesium, wherein the metal salt comprises a zinc orthophosphate salt; wherein the liquid ammonium polyphosphate content is 70% to 95% by weight of the total weight of the flame retardant composition; the ammonium polyphosphate in powder form is 5% to 13% by weight of the total weight of the flame retardant composition and the zinc orthophosphate salt is 0.01% to 5% by weight of the total weight of the flame retardant composition.
2. The flame retardant composition according to claim 1 , wherein the zinc orthophosphate salt is an anhydrous or a hydrated zinc salt.
3. The flame retardant composition according to claim 2 , wherein the zinc orthophosphate salt is a zinc orthophosphate dihydrate.
4. The flame retardant composition according to claim 3 , wherein the proportion of the zinc orthophosphate dihydrate is 0.2% to 0.5% by weight of the total weight of the flame retardant composition.
5. The flame retardant composition according to claim 1 , wherein the liquid ammonium polyphosphate has an ammonia content, expressed as nitrogen, that is 7% to 12% by weight of the total weight of the liquid ammonium polyphosphate.
6. The flame retardant composition according to claim 3 , wherein the liquid ammonium polyphosphate has an ammonia content, expressed as nitrogen, that is 7% to 12% by weight of the total weight of the liquid ammonium polyphosphate.
7. The flame retardant composition according to claim 1 , wherein the liquid ammonium polyphosphate has a phosphorous content, expressed as phosphoric anhydride, that is 20% to 37% by weight of the total weight of the liquid ammonium polyphosphate.
8. The flame retardant composition according to claim 6 , wherein the liquid ammonium polyphosphate has a phosphorous content, expressed as phosphoric anhydride, that is 20% to 37% by weight of the total weight of the liquid ammonium polyphosphate.
9. The flame retardant composition according to claim 1 , wherein the ammonium polyphosphate in powder form has an ammonia content, expressed in the form of nitrogen, that is 10% to 20% by weight of the total weight of the ammonium polyphosphate in powder form.
10. The flame retardant composition according to claim 1 , wherein the ammonium polyphosphate in powder form has a phosphorous content, expressed in the form of phosphoric anhydride, that is 60% to 75% by weight of the total weight of the ammonium polyphosphate in powder form.
11. The flame retardant composition according to claim 9 , wherein the ammonium polyphosphate in powder form has a phosphorous content, expressed in the form of phosphoric anhydride, that is 60% to 75% by weight of the total weight of the ammonium polyphosphate in powder form.
12. The flame retardant composition according to claim 1 , wherein the ammonium polyphosphate in powder form has a granulometry expressed in mean particle size of 1 to 20 microns, and 100% of said particles have a size lower than 40 microns.
13. The flame retardant composition according to claim 9 , wherein the ammonium polyphosphate in powder form has a granulometry expressed in mean particle size between 1 and 20 microns, and 100% of said particles have a size lower than 40 microns.
14. The flame retardant composition according to claim 10 , wherein the ammonium polyphosphate in powder form has a granulometry expressed in mean particle size of 1 to 20 microns, and 100% of said particles have a size lower than 40 microns.
15. The flame retardant composition according to claim 11 , wherein the ammonium polyphosphate in powder form has a granulometry expressed in mean particle size of 1 to 20 microns, and 100% of said particles have a size lower than 40 microns.
16. The flame retardant composition according to claim 1 , wherein the ammonia content of the flame retardant composition expressed as nitrogen is 6% to 12% by weight of the total weight of the flame retardant composition.
17. The flame retardant composition according to claim 14 , wherein the ammonia content of the flame retardant composition expressed as nitrogen is 6% to 12% by weight of the total weight of the flame retardant composition.
18. The flame retardant composition according to claim 1 , wherein the phosphorous content of the flame retardant composition expressed as phosphoric anhydride is 30% to 40% by weight of the total weight of the flame retardant composition.
19. The flame retardant composition according to claim 17 , wherein the phosphorous content of the flame retardant composition expressed as phosphoric anhydride is 30% to 40% by weight of the total weight of the flame retardant composition.