Two-dimensional radial-ejection ion trap operable as a quadrupole mass filter
A two-dimensional radial-ejection ion trap is constructed from four apertured electrodes having inwardly facing hyperbolic surfaces, with each electrode being spaced from the centerline by a distance r that is greater than the hyperbolic radius r 0 defined by the hyperbolic surfaces. This geometry produces a balanced symmetrical trapping field that has a negligible octopole field component and a relatively large dodecapole or icosapolar field component. In one specific implementation, the ion trap is selectably operable as a quadrupole mass filter by applying a filtering DC voltage to the electrodes.
1. A multipole structure selectively operable in a mass filter mode or an analytical ion trap mode, comprising:
four elongated rod electrodes arranged around a centerline of the multipole structure and extending between an inlet end and an outlet end, at least two of the four electrodes each being adapted with an aperture permitting the ejection of ions therethrough;
at least one detector located proximate to a corresponding one of the apertures; and
a controller, coupled to an RF voltage source, a DC voltage source and an oscillatory resonant excitation voltage source, configured to switch the operation of the multipole structure between the mass filter mode, wherein the RF voltage source applies a filtering DC component to allow selective transmission of ions within a predetermined range of mass-to-charge ratios from the inlet end to the outlet end, and an analytical ion trap mode, wherein the DC voltage source applies DC offsets to axial trapping electrodes or to at least some of the rod electrodes to axially confine ions within the interior of the multipole structure and the resonant excitation source applies a resonant excitation voltage to eject ions through at least one aperture to the corresponding detector in order of their mass-to-charge ratios.
2. The multipole structure of claim 1 , wherein each of the elongated rod electrodes has a hyperbolic shaped surface facing the centerline.
3. The multipole structure of claim 1 , wherein each of the four rod electrodes is adapted with an aperture.
4. The multipole structure of claim 1 , wherein each rod electrode of a first opposed pair of rod electrodes is adapted with an aperture, and each rod electrode of a second opposed pair of rod electrodes is adapted with a recess that does not extend through the full thickness of the rod electrodes.
5. The multipole structure of claim 1 , wherein each rod electrode comprises a central segment interposed between first and second end segments, and wherein the controller is configured to apply DC offsets to the first and second end segments when the multipole structure is operated in analytical ion trap mode.
6. A mass spectrometer, comprising:
an ion source for generating ions from a sample to be analyzed; and
a multipole structure selectively operable in a mass filter mode or an analytical ion trap mode, comprising:
four elongated rod electrodes arranged around a centerline of the multipole and extending between an inlet end and an outlet end, at least two of the four electrodes each being adapted with an aperture permitting the ejection of ions therethrough;
a first detector located proximate to a corresponding one of the apertures;
a controller, coupled to an RF voltage source, a DC voltage source and an oscillatory resonant excitation voltage source, configured to switch the operation of the multipole structure between the mass filter mode, wherein the RF voltage source applies a filtering DC component to allow selective transmission of ions within a predetermined range of mass-to-charge ratios from the inlet end to the outlet end, and an analytical ion trap mode, wherein the DC voltage source applies DC offsets to axial trapping electrodes or to at least some of the rod electrodes to axially confine ions within the interior of the multipole structure and the resonant excitation source applies a resonant excitation voltage to eject ions through at least one aperture to the corresponding detector in order of their mass-to-charge ratios; and
a second detector located adjacent to the outlet end of the multipole structure.
7. The mass spectrometer of claim 6 , wherein each of the elongated rod electrodes has a hyperbolic shaped surface facing the centerline.
8. The mass spectrometer of claim 6 , wherein each of the four rod electrodes is adapted with an aperture.
9. The mass spectrometer of claim 6 , wherein each rod electrode of a first opposed pair of rod electrodes is adapted with an aperture, and each rod electrode of a second opposed pair of rod electrodes is adapted with a recess that does not extend through the full thickness of the rod electrodes.
10. The mass spectrometer of claim 6 , wherein each rod electrode comprises a central segment interposed between first and second end segments, and wherein the controller is configured to apply DC offsets to the first and second end segments when the multipole structure is operated in analytical ion trap mode.
11. The mass spectrometer of claim 6 , further comprising:
a quadrupole mass filter located upstream in the ion path from the multipole structure; and
a collision/reaction cell interposed in the ion path between the quadrupole mass filter and the multipole structure.