Electrolyte membrane using polybenzoxazine based compound
An electrolyte membrane includes a cross-linked reaction product of a benzoxazine monomer and a cross-linkable compound. The electrolyte membrane is impregnated with 300 to 600 parts by weight of phosphoric acid based on 100 parts by weight of the electrolyte membrane, and has a yield strain 0.5% or less, and a yield stress 0.3 MPa or less. The cross-linked material has a strong acid trapping ability with respect to the benzoxazine compound and excellent mechanical properties due to a cross-linkage. Also, the solubility of the cross-linked material in polyphosphoric acid is low, thereby showing excellent chemical stability. Accordingly, when the cross-linked material is used, an electrolyte membrane having an excellent liquid supplementing ability and excellent mechanical and chemical stability at a high temperature can be obtained. The cross-linked material can be obtained by a simple polymerization process by combining a benzoxazine monomer and a crosslinkable compound and by using heat instead of using a polymerization initiator or a cross-linking agent.
1. An electrolyte membrane, comprising:
a cross-linked reaction product of a benzoxazine monomer with a cross-linkable compound, the electrolyte membrane being impregnated with 300 to 600 parts by weight of phosphoric acid based on 100 parts by weight of the electrolyte membrane, and wherein the electrolyte membrane has a yield strain of 0.5% or less and a yield stress of 0.3 MPa or less.
2. A cross-linked material, comprising:
a reaction product of a benzoxazine monomer and a cross-linkable compound, wherein:
the cross-linked material is formed under conditions wherein the benzoxazine monomer polymerizes to form a polybenzoxazine that cross-links with the cross-linkable compound, and
the cross-linkable compound is a compound selected from the group of polybenzimidazole, polybenzothiazole, and polybenzoxazole.