Composite material for positive electrode of lithium battery
The present invention provides a composite material for positive electrodes of lithium batteries, which provides a lithium battery having excellent high rate electrical discharge characteristics, has a sufficiently secured diffusion passage for Li, and has high conductivity, a process for producing the same, as well as a positive electrode and a battery using the composite material for positive electrodes of lithium batteries. The present invention relates to a composite material for positive electrodes of lithium batteries, comprising composite particles containing positive electrode active material particles and fibrous carbons, wherein the composite particles have a form in which the positive electrode active material particles are supported by the fibrous carbons.
1. A process for producing a composite material for positive electrodes of lithium batteries, which comprises composite particles containing positive electrode active material particles and fibrous carbons, the process including:
Step 1 of obtaining a slurry containing a solvent, and the positive electrode active material particles and the fibrous carbons contained in a dispersed state in the solvent; and
Step 2 of subjecting the slurry obtained in Step 1 to spray granulation to obtain granules containing the positive electrode active material particles and the fibrous carbons,
wherein the slurry further contains a dispersing agent in Step 1,
the positive electrode active material particles are supported by the fibrous carbons in the granules obtained in Step 2, and
further comprising Step 3 of removing the dispersing agent from the granules in or after Step 2 to obtain composite particles,
wherein Step 3 is a step of washing the granules with a solvent capable of dissolving the dispersing agent to remove the dispersing agent, thereby obtaining composite particles.
2. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein an average aggregated particle diameter of the positive electrode active material is 0.1 to 10 μm.
3. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein a fiber diameter of the fibrous carbon is 1 to 1,000 nm.
4. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein the fibrous carbon is a carbon nanotube.
5. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein the dispersing agent has a functional group containing an aromatic ring and/or an aliphatic ring.
6. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein an ultrasonic wave type disperser is used in Step 1.
7. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein in Step 1, the dispersed state, where the positive electrode active material particles and the fibrous carbons arc, dispersed, means a state where a ratio calculated by dividing the volume median particle diameter (D 50 ) of the slurry by particle size distribution measurement by the average aggregated particle diameter of the positive electrode active material and multiplying the obtained value by 100 is within 130%.
8. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein an aspect ratio of the fibrous carbon 200 to 2000.
9. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein the fiber length of the fibrous carbon is 1 to 10 μm.
10. The process for producing a composite material for positive electrodes of lithium batteries according to claim 1 , wherein in Step 1, the blending amount of the dispersing agent is 10 to 200 parts by weight based on 100 parts by weight of the fibrous carbon.