Phase separated curable compositions
A curable composition, suitable for underfill encapsulant, has two distinct phase domains after cure, a continuous phase and a discontinuous phase, in which one phase has a modulus value of 2 GPa or greater, and the second phase has a modulus value at least 1 Gpa less than the first phase, characterized in that the phases are generated in situ as the composition cures.
1. A curable composition, which upon curing generates two phases in situ, the first phase comprising cyanate ester resin or an epoxy resin or both, the first phase after cure having a modulus value of 2 GPa or greater and the second phase comprising an oligomeric material having a weight average molecular weight in the range of 500 to 5000, a maleimide, a cyanate ester resin, an epoxy resin, or both a cyanate ester resin and an epoxy resin, the second phase after cure having a modulus value at least 1 Gpa less than the modulus value of the first phase after cure.
2. A cured composition comprising two phases generated in situ, in which the first phase comprises cyanate ester resin or an epoxy resin or both and has a modulus value of 2 GPa or greater and the second phase comprises an oligomeric material having a weight average molecular weight in the range of 500 to 5000, a maleimide, a cyanate ester resin, an epoxy resin or both a cyanate ester resin and an epoxy resin and has a modulus value at least 1 GPa less than the modulus value of the first phase.
3. The cured composition according to claim 2 in which the phases are generated in situ by reaction induced phase separation or by crystallization induced phase separation.