Heat resistant polypropylene film
A heat resistant film that comprises at least one layer that comprises a high crystallinity propylene polymer having a melt flow rate of from 0.5 g/10 min. to 15 g/10 min. and a xylene solubles of less than 3.5%. The propylene polymer may have a melting point above 158° C. The heat resistant film may further comprise at least a second layer, which may be a heterophasic random copolymer. The heat resistant film may be, for example, a blown film, a cast film, or an oriented film, and may be used in such articles of manufacture as construction films, retort packaging, and laminated articles.
1. A multi-layer heat resistant film comprising a first layer, said first layer consisting essentially of a polymer, the polymer comprising a high crystallinity propylene polymer having a melt flow rate of from 0.5 g/10 min. to 15 g/10 min., a xylene solubles of less than 3.5% and a second layer, said second layer comprising a heterophasic random copolymer, wherein the multi-layer film has a secant modulus in the transverse draw direction of from 150 kpsi to 250 kpsi.
2. The film of claim 1 wherein said propylene polymer has a melting point above 158° C.
3. The film of claim 1 wherein said heterophasic random copolymer is the core layer of said film.
4. The film of claim 1 wherein said heterophasic random copolymer has a melt flow rate of from 5 g/10 min. to 15 g/10 min. and a melting point of from 158° C. to about 180° C.
5. The film of claim 1 having a tear resistance in the transverse draw direction of greater than 500 grams.
6. The film of claim 1 having a tear resistance in the machine draw direction of greater than 10 grams.
7. The film of claim 1 having a puncture resistance of greater than 3.5 lbf.
8. The film of claim 1 having a secant modulus in the machine draw direction of greater than 200 kpsi.
9. The film of claim 1 having a heat of fusion above 90 cal/g.
10. The film of claim 1 having a degree of crystallinity between 0.5 to 0.85.
11. The film of claim 1 wherein said propylene polymer is isotactic.
12. The film of claim 1 wherein said film is blown, cast, or oriented.
13. An article of manufacture comprising the film of claim 1 .
14. The article of manufacture of claim 13 wherein said article is a construction film, a retort package, or laminated article.
15. A process of producing a multi-layer heat resistant film comprising co-extruding a first polyolefin polymer having a melt flow rate of from 0.5 g/10 min. to 15 g/10 min. and a melting point of from 158° C. to 180° C. and a second polyolefin polymer have a melt flow rate of from 0.5 g/10 min. to 20 g/10 min., a melting point of from 158° C. to 180° C., wherein the multi-layer film has a secant modulus in the transverse draw direction of from 150 kpsi to 250 kpsi.
16. The film of claim 1 , wherein second layer comprises 15 wt % or less impact copolymer.
17. The film of claim 1 , wherein the high crystallinity propylene polymer is metallocene-based.
18. The film of claim 1 , wherein the first layer is between 0.125 and 1.25 mil. in thickness.
19. The film of claim 18 , wherein the second layer is between 0.25 and 2.5 mil. in thickness.
20. The film of claim 19 , wherein the total thickness of the film is between 1 and 2 mil. in thickness.