Storage materials for hydrogen and other small molecules
This invention relates to adsorbents useful for storing hydrogen and other small molecules, and to methods for preparing such adsorbents. The adsorbents are produced by heating carbonaceous materials to a temperature of at least 900° C. in an atmosphere of hydrogen.
1. Carbon nanostructures made by a process comprising heating a carbonaceous material in the presence of H 2 to a temperature of at least 900° C., wherein the carbon nanostructures comprise turbostratic and amorphous regions, and wherein the carbon nanostructures have a total BET surface area of at least about 1,560 m 2 /g, and essentially no micropore volume.
2. A composition comprising a carbon nanostructures characterized by having:
(a) amorphous regions;
(b) turbostratic regions containing turbostratic graphite fragments;
(c) a total BET surface area of at least about 1560 m 2 /g; and
(d) total pore volume of at least 0.5 cc/g.
3. The composition of claim 2 , further comprising adsorbed small molecules selected from the group consisting of hydrogen, oxygen, nitrogen, methane, and carbon dioxide.
4. The composition of claim 3 , wherein the small molecule is hydrogen.
5. The composition of claim 4 , wherein the adsorbed H 2 comprises at least 1 wt % of the composition at 10 bar and −160° C. to −180° C.
6. The composition of claim 2 , wherein the total pore volume is 0.5-5.5 cc/g.
7. A process for storing small molecules selected from the group consisting of hydrogen, methane, oxygen, nitrogen and carbon dioxide, the process comprising,
(a) providing carbon nanostructures prepared by heating a carbonaceous material in the presence of H 2 to a temperature of at least 900° C., wherein the carbon nanostructures comprise amorphous and turbostratic regions wherein the carbon nanostructures have a total BET surface area of at least 1,560 m 2 /g, and essentially no micropore volume; and
(b) introducing the small molecules into a storage vessel containing the carbon nanostructures.
8. The process of claim 7 , wherein the carbonaceous material is selected from the group consisting of polysaccharides, carbohydrates, natural polymers, synthetic polymers and activated carbons.
9. The process of claim 8 , wherein the natural polymer is selected from the group consisting of chitosan, chitin and cellulose.
10. The process of claim 7 , wherein the carbonaceous material is heated to a temperature of 900-1600° C.
11. The process of claim 10 , wherein the carbonaceous material is heated to a temperature of 1000-1200° C. for 2-48 hr.
12. The process of claim 7 , wherein the small molecule is hydrogen.
13. The process of claim 12 , wherein the hydrogen is introduced at pressures between 0.1-10 atm and the temperature is between −160° C. and −180° C.
14. The process of claim 12 , wherein the hydrogen is introduced at pressures between 1-2,000 atm and at temperatures between −100° C. and 100° C.
15. A process for separating mixtures of gases, comprising:
(a) introducing a mixture of gases into a storage vessel containing carbon nanostructures produced by a process comprising heating a carbonaceous material in the presence of H 2 to a temperature of at least 900° C., wherein the carbon nanostructures comprise amorphous and turbostratic regions and wherein the carbon nanostructures have a total BET surface area of at least 1,560 m 2 /g, and essentially no micropore volume;
(b) allowing the gases to at least partially equilibrate at elevated pressure to form adsorbed and non-adsorbed gases; and
(c) reducing the pressure and removing at least a portion of the non-adsorbed gases.
16. The process of claim 15 , further comprising (d) further reducing the pressure and/or heating the carbon nanostructures to remove any additional non-adsorbed gases and at least a portion of the adsorbed gases.