Method and system for regenerating an amine-containing scrubbing solution obtained during gas purification
A method for regenerating an amine-containing scrubbing solution which is obtained during gas purification and in which CO 2 and sulfur compounds are chemically bonded, as well as a system that is suitable for carrying out the method. The contaminated scrubbing solution is heated, compressed, and expanded in several stages such that CO 2 and sulfur compounds are separated. The expanded scrubbing solution is subdivided into two partial streams, and one partial stream is recirculated into the process.
1. A method of regenerating an amine-containing scrubbing solution obtained during gas purification and having CO 2 and sulfur compounds chemically bound therein, the method which comprises:
a) heating a contaminated scrubbing solution to a temperature of at least 110° C. and compressing to a pressure of at least 4 bar, subsequently expanding the scrubbing solution in a first expansion stage, and removing a major proportion of CO 2 and sulfur compounds from the scrubbing solution as a gas stream to form a partially regenerated scrubbing solution;
b) heating the partially regenerated scrubbing solution obtained in step a) to a temperature of at least 130° C. and compressing to a pressure of at least 4 bar, and expanding the partially regenerated scrubbing solution in a second expansion stage to a pressure that is at least 0.5 bar higher than an expansion pressure of the first expansion stage, and removing a major proportion of the CO 2 and sulfur compounds still present from the partially regenerated scrubbing solution as a gas stream;
c) cooling the scrubbing solution removed in the second expansion stage to a temperature below 70° C. and expanding to standard pressure in a third expansion stage, and removing residual amounts of soluble CO 2 still present, and cooling to standard temperature as a completely purified scrubbing solution;
d) removing condensed water from the gas mixture (vapors) cooled to standard temperature, and mixing the condensed water at a dosed amount with the completely purified scrubbing solution; and
e) dividing the scrubbing solution removed after the first expansion stage or the second expansion stage into first and second partial streams, and returning the first partial stream in the circuit to the respective expansion stage and adjusting a temperature and a pressure thereof to conditions of the associated expansion stage, wherein residual amounts of sulfur compounds still present are removed from the first partial stream during the expansion and the second partial stream is further processed in accordance with step b) or step c).
2. The method according to claim 1 , which comprises using a gas mixture composed of CO 2 , water and sulfur compounds removed in the expansion stages as vapors in steps a) and b) as a heat carrier for heating the contaminated scrubbing solution and cooling the gas mixture to standard temperature.
3. The method according to claim 1 , which comprises compressing the contaminated scrubbing solution, prior to expansion, to a pressure of 6 to 12 bar and expanding during the expansion to a pressure of 1 to 8 bar.
4. The method according to claim 1 , which comprises carrying out a flash expansion in the expansion stages of steps a) and b).
5. The method according to claim 1 , which comprises using the purified scrubbing solution obtained in the second expansion stage as a heat carrier for heating the contaminated scrubbing solution.
6. The method according to claim 1 , which comprises desulfurizing a gas stream removed in the first and second expansion stage in a downstream desulfurization plant.
7. A method of regenerating an amine-containing scrubbing solution obtained during gas purification and having CO 2 and sulfur compounds chemically bound therein, the method which comprises:
a) heating a contaminated scrubbing solution to a temperature of at least 110° C. and compressing to a pressure of at least 4 bar, subsequently expanding the scrubbing solution in a first expansion stage, and removing a major proportion of CO 2 and sulfur compounds from the scrubbing solution as a gas stream to form a partially regenerated scrubbing solution;
b) heating the partially regenerated scrubbing solution obtained in step a) to a temperature of at least 130° C. and compressing to a pressure of at least 4 bar, and expanding the partially regenerated scrubbing solution in a second expansion stage to a pressure that is at least 0.5 bar higher than an expansion pressure of the first expansion stage, and removing a major proportion of the CO 2 and sulfur compounds still present from the partially regenerated scrubbing solution as a gas stream;
c) cooling the scrubbing solution removed in the second expansion stage to a temperature below 70° C. and expanding to standard pressure in a third expansion stage, and removing residual amounts of soluble CO 2 still present, and cooling to standard temperature as a completely purified scrubbing solution; and
d) dividing the scrubbing solution removed after the first expansion stage or the second expansion stage into first and second partial streams, and returning the first partial stream in the circuit to the respective expansion stage and adjusting a temperature and a pressure thereof to conditions of the associated expansion stage, wherein residual amounts of sulfur compounds still present are removed from the first partial stream during the expansion and the second partial stream is further processed in accordance with step b) or step c); and
subjecting the scrubbing solution to ultrasonic treatment during the first expansion stage.
8. A method of regenerating an amine-containing scrubbing solution obtained during gas purification and having CO 2 and sulfur compounds chemically bound therein, the method which comprises:
a) heating a contaminated scrubbing solution to a temperature of at least 110° C. and compressing to a pressure of at least 4 bar, subsequently expanding the scrubbing solution in a first expansion stage, and removing a major proportion of CO 2 and sulfur compounds from the scrubbing solution as a gas stream to form a partially regenerated scrubbing solution;
b) heating the partially regenerated scrubbing solution obtained in step a) to a temperature of at least 130° C. and compressing to a pressure of at least 4 bar, and expanding the partially regenerated scrubbing solution in a second expansion stage to a pressure that is at least 0.5 bar higher than an expansion pressure of the first expansion stage, and removing a major proportion of the CO 2 and sulfur compounds still present from the partially regenerated scrubbing solution as a gas stream;
c) cooling the scrubbing solution removed in the second expansion stage to a temperature below 70° C. and expanding to standard pressure in a third expansion stage and removing residual amounts of soluble CO 2 still present, and cooling to standard temperature as a completely purified scrubbing solution; and
d) dividing the scrubbing solution removed after the first expansion stage or the second expansion stage into first and second partial streams, and returning the first partial stream in the circuit to the respective expansion stage and adjusting a temperature and a pressure thereof to conditions of the associated expansion stage, wherein residual amounts of sulfur compounds still present are removed from the first partial stream during the expansion and the second partial stream is further processed in accordance with step b) or step c); and
measuring a pH of the purified scrubbing solution and utilizing the measured pH as a control variable for adjusting a temperature of the contaminated scrubbing solution in the expansion stages.
9. The method according to claim 1 , which comprises, in an expansion stage the ratio of the partial stream removed from the circuit to the amount fed in of contaminated scrubbing solution is 0.2 to 5.